摘要:
Spheroidal shaped, hollow microcapsules of thermoplastic polymeric resins have been prepared which have an average diameter of from 0.1 Mu to 1.0 Mu . Each of the microcapsules are filled with air and have an average wall thickness of from about 3 percent to 30 percent of the diameter of the microcapsules. These microcapsules are obtained from an emulsion comprising water and microcapsules of the polymeric resin containing a nonsolvent for the resin. The microcapsules are suspended in the water and the non-solvent is present inside the microcapsules. Either one of these products, i.e. the microcapsules themselves or the water emulsion containing the microcapsules described above, may be used as an opacifier in paint or other systems.
摘要:
SYNTHETIC LATEXES AND AQUEOUS COLLOIDAL DISPERSIONS, FREE OF ADDED EXTERNAL SURFACTANTS AND EMULSIFIERS, ARE MADE FROM NORMALLY SOLIDS, WATER- AND ALKALI-INSOLUBLE THERMOPLASTIC ORGANIC ADDITION POLYMERS CONTAINING PLURALITY OF ACID GROUPS IN THE POLYMER STRUCTURE AND WHICH ARE IN NON-COLLOIDAL MASSIVE FORM BY DIGESTING THE POLYMER IN ADMIXTURE WITH AN EVELOPING ALKALINE AQEOUS LIQUID MEDIUM UNTIL THE POLYMER SPONTANEOUSLY CONVERTS INTO COLLOIDAL PARTICLES IN THE AQUEOUS MEDIUM. IN AN EXAMPLE, A SOLID THERMOPLASTIC TERNARY COPOLYMER OF ETHYLENE, 11.2% BY WEIGHT ETHYL ACRYLATE, AND 11% BY WEIGHT ACRYLIC ACID, IN THE FORM OF MOLDING GRANULES, WAS CONVERTED TO LATEX FORM BY DIGESTION IN AQUEOUS AMMONIA OR IN AQUEOUS POTASSIUM HYDROXDE. THE RESULTING DISPERSIONS ARE USEFUL IN IMPREGNATING, COATING AND ADHESIVE COMPOSITIONS.
摘要:
AQUEOUS COLLOIDAL DISPERSIONS HAVING IMPROVED STABILITY ARE PREPARED BY ADSORBING A POLYMERIZABLE SURFACTANT, SUCH AS SODIUM ALLYL A-SULFOPALMITATE, ON THE SURFACE OF PARTICLES DISPERSED IN AQUEOUS MEDIA, SUCH AS IN A PREFORMED LATEX, AND POLYMERIZING IN PLACE THE ADSORBED SURFACTANT. ORDINARILY AN AMOUNT OF POLYMERIZABLE SURFACTANT TO PROVIDE FROM ABOUT 50 PERCENT TO ABOUT 100 PERCENT COVERAGE OF THE PARTICLES IS USED.
摘要:
A PROCESS FOR PREPARING DISPERSIONS OF POLYTETRAFLUOROETHYLENE IN ORGANIC LIQUIDS WHICH COMPRISES MIXING PARTICULATE POLYTETRAFLUOROETHYLENE AND AN ORGANIC LIQUID HAVING A SURFACE TENSION BELOW ABOUT 25 DYNES PER CENTIMETER AND THEN MILLING THE MIXTURE.
摘要:
IN WHICH R1, R2, R4 AND R5 MAY BE THE SAME OR DIFFERENT AND ARE HYDROGEN OR A METHYL GROUP AND R3 IS AN ALKYL GROUP CONTAINING FROM 1 TO 8 CARBON ATOMS.
R4-CH=C(-R5)-COO-R3
AND FROM 5 TO 60 MOLE PERCENT OF MOIETIES OF AN UNSATURATED CARBOXYLIC ACID ESTER OF THE FORMULA:
R1-CH=C(-R2)-COOH
1. IN AQUEOUS EMULSION GLOSS PAINT WHICH COMPRISES A BLEND OF A BINDER LATEX A PIGMENT DISPERSION CONTAINING, AS DISPERSING AGENT, FROM 0.01 TO 1%, BASES ON THE WEIGHT OF PIGMENT, OF A POLYMER HAVING AN AVERAGE MOLECULAR WEIGHT BELOW 5,000 AND WHICH IS AN AMMONIUM OR ALKALI METAL SALT OF A COPOLYMER CONTAINING FROM 40 TO 95 MOLE PERCENT OF MOIETIES OF AN UNSATURATED MONOCARBOXYTIC ACID OF THE FORMULA:
摘要:
A PROCESS FOR PREPARING A STABLE SPINNING COMPOSITION COMPRISING AN ACRYLONITRILE POLYMER DISSOLVED IN A CONCENTRATED INORGANIC SOLVENT SOLUTION THEREFOR AND A SURFACE ACTIVE AGENT INSOLUBLE IN SAID SOLUTION IS DISCOLSED WHICH COMPRISES DISPERSING SAID SURFACE ACTIVE AGENT IN SAID SOLUTION, MAINTAINING SAID DISPERSION AS A FILM UNDER RETION, AND DEFOAMING SAID DISPERSION AS A FILM UNDER REDUCED PRESSURE AT A TEMPERATURE WHICH IS AT LEAST EQUAL TO THE BOILING POINT OF SAID COMPOSITION AT THE REDUCED PRESSURE EMPLOYED.
摘要:
AN IMPROVED PROCESS FOR THE PREPARATION OF OLEFIN POLYMER DISPERSIONS, SUCH AS ETHYLENE/VINYL ACETATE COPOLYMER DISPERSIONS, IS PROVIDED. THE IMPROVEMENT COMPRISES ADDING VEGETABLE OILS OR REFINED SOLID OR LIQUID HYDROCARBONS DERIVED FRO PETROLEUM SUCH AS PARAFFIN WAXES OR LIGHT AND HEAVY MINERAL OILS TO SUPPRESS FOAM AT A SPECIFIC TIME DURING SOLVENT EVAPORATION.