-
1.
公开(公告)号:US20240167172A1
公开(公告)日:2024-05-23
申请号:US18138116
申请日:2023-04-23
申请人: Dioxycle
发明人: Sarah Lamaison , Jonathan Maistrello , Ruperto G Mariano , Bastien Faure , David Wakerley , Lindsay Leveen
IPC分类号: C25B3/25 , C01B32/942 , C07C1/32 , C21B13/12
CPC分类号: C25B3/25 , C01B32/942 , C07C1/325 , C21B13/12 , C01B2210/0006 , C21B2100/40 , C21B2100/80
摘要: Methods and systems for the valorization of carbon monoxide emissions from electric arc furnaces into highly valuable low-carbon footprint chemicals using carbon monoxide electrolysis are disclosed herein are disclosed. A disclosed method includes operating an electric arc furnace, generating, via operation of the electric arc furnace, a volume of carbon monoxide, supplying the volume of carbon monoxide to a cathode area of a carbon monoxide electrolyzer to be used as a reduction substrate, and generating, using the carbon monoxide electrolyzer, the reduction substrate, and an oxidation substrate, a volume of generated chemicals. The volume of generated chemicals is at least one of: a volume of hydrocarbons, a volume of organic acids, a volume of alcohol, a volume of olefins and a volume of N-rich organic compounds.
-
公开(公告)号:US11884606B2
公开(公告)日:2024-01-30
申请号:US17988544
申请日:2022-11-16
申请人: ENTEGRIS, INC.
摘要: The disclosure provides methodology for the synthesis of mono-alkylated cyclopentadiene structures, which can be obtained via fulvene intermediates. In one embodiment, the cyclopentadiene ring is substituted with a trialkylsilyl moiety, which enables the further reaction with certain metal halides to form metal adducts. For example, the monoalkyl cyclopentadienes substituted with a trimethylsilyl group can be reacted with TiCl4 to provide R*CpTiCl3 complexes, wherein R* is a group of the formula
wherein R1 and R2 are as defined herein.-
3.
公开(公告)号:US20240025925A1
公开(公告)日:2024-01-25
申请号:US18224207
申请日:2023-07-20
摘要: Systems and methods for formation of highly reactive alkali dendrites are provided. For example, in some embodiments alkali metals are dissolved in ammonia to form metal electrides after which the ammonia is removed via vacuum to reveal highly activated metal surfaces in the form of crystalline alkali dendrites. The alkali dendrites can mimic powders but have the advantage of being freshly prepared from inexpensive and readily available metal sources. These uniquely activated metals exhibit enhanced reactivity comparatively to similar off the shelf sources of the corresponding metals. For example, the dendrites can have about 100 times greater surface area than conventional metal sources and/or be about 19 times more reactive than powders that serve as the industry standard for the preparation of organometallic compounds. After surface activation, these metals can be used to prepare various organometallic reagents.
-
公开(公告)号:US20220017434A1
公开(公告)日:2022-01-20
申请号:US17374247
申请日:2021-07-13
IPC分类号: C07C1/32 , C01B3/26 , C01B32/75 , C07C319/06 , B01J23/42 , B01J21/04 , B01J23/04 , B01J23/883 , B01J29/40 , B01J19/24 , B01J19/00 , B01D3/14 , B01D3/00
摘要: The present disclosure is generally directed to a new and innovative system, process and method that utilize a new “non-oxygen type of oxidizers” process for methane (CH4) upgrading to value-added products such as olefins and aromatics (i.e., benzene, toluene and xylene (BTX)) etc. and further removing toxic impurities such as sulphur-containing compounds (i.e. H2S) by using the sulphur as a source of radical.
-
5.
公开(公告)号:US20210114953A1
公开(公告)日:2021-04-22
申请号:US16972291
申请日:2019-06-07
申请人: Amyris, Inc.
IPC分类号: C07C1/32 , C12P5/02 , C07C209/60 , C07C17/093 , C07C67/10 , C07C29/128 , C07C315/00 , C07C315/04 , A61K39/39
摘要: The present disclosure provides methods for preparing polyunsaturated hydrocarbons, such as E,E-farnesol, farnesyl acetate and squalene, by base catalyzed addition of a dialkylamine to a 3-methylene-1-alkene, such as farnesene. The present disclosure also provides compositions including one more farnesene derivatives prepared using the disclosed methods.
-
公开(公告)号:US10745424B2
公开(公告)日:2020-08-18
申请号:US16327735
申请日:2017-08-30
IPC分类号: C07F9/117 , C07C1/32 , C07C2/42 , C07C13/62 , C07C29/17 , C07C45/69 , C07C53/136 , C07C1/30 , C07C29/09 , C07C41/20 , C07C45/68 , C07C51/16 , C07C41/18 , C07C69/608 , A61K9/127 , C07C31/137 , C07C49/693 , C07F5/02
摘要: Methods for preparing a variety of ladderane precursors, ladderane compounds and ladderane lipids are provided. Also provided are methods of preparing a liposome from the ladderane lipids disclosed herein, and compositions thereof. Aspects of the invention include encapsulated one or more cargo moieties in the liposome or compositions thereof and use of the subject liposome compositions as vehicles in drug delivery, imaging, diagnostics and other medical applications. Aspects of the methods disclosed herein include administering a liposomal composition comprising a pharmaceutical agent to a subject under conditions sufficient to deliver the composition to a site of interest in the subject, and release the pharmaceutical agent from the liposomal composition.
-
公开(公告)号:US10246393B2
公开(公告)日:2019-04-02
申请号:US15797568
申请日:2017-10-30
发明人: Hisao Eguchi , Takanori Miyazaki , Yoshiaki Nakao
IPC分类号: C07D213/06 , C07C41/30 , C07C1/32 , C07C17/263 , C07C45/61 , C07C67/28 , C07C303/30 , C07D213/16 , C07D213/64 , C07D215/06 , C07D217/04 , C07D295/033 , C07D409/04 , C07C67/343 , C07C41/18 , C07B37/04 , C07C315/04 , C07C45/45 , C07C45/49 , C07C45/59
摘要: In a cross coupling reaction, in a case where a halogen atom is selected as the leaving group of the raw material compound, a harmful halogen waste forms as a by-product after the reaction, and disposal of the waste liquid is complicated and environmental burden is high. In a carbon-hydrogen activation cross coupling reaction which requires no halogen atom as the leaving group, although no halogen waste forms as a by-product, the reaction substrate is considerably restricted, and the reaction remains a limited molecular construction method.A method for producing an aromatic compound, which comprises subjecting an aromatic nitro compound and a boronic acid compound to a cross coupling reaction in the presence of a metal catalyst.
-
公开(公告)号:US10246382B2
公开(公告)日:2019-04-02
申请号:US15128448
申请日:2015-04-17
申请人: Siemens Energy, Inc.
IPC分类号: C02F1/66 , C02F1/72 , C07C1/32 , C08L33/26 , C10L3/10 , C02F11/08 , C02F101/32 , C02F101/36 , C02F103/28 , C02F103/36 , C02F101/38 , C02F103/10 , C02F103/32
摘要: Catalytic systems and methods for treating process streams are disclosed. Catalytic wet oxidation and hydrolysis techniques may be used to treat one or more undesirable constituents such as HPAM and KHI. Methane may be produced in connection with at least some embodiments.
-
公开(公告)号:US20180334414A1
公开(公告)日:2018-11-22
申请号:US15580838
申请日:2016-06-01
IPC分类号: C07C1/32 , C07C41/30 , C07C17/263 , C07C67/343 , C07C201/12 , C07F7/18 , C07D309/18 , C07D333/08 , C07D307/79 , C07D231/56 , C07D213/61 , C07D209/08 , C07D211/70
摘要: Processes of forming Csp2—Csp3 bonds at the allylic carbon of a cyclic allylic compound starting material are disclosed, in which a racemic mixture of a cyclic allylic compound having a leaving group attached to the allylic carbon is reacted with a compound having a nucleophilic carbon atom in the presence of a Rh(I), Pd(II) or Cu(I) pre-catalyst and a chiral ligand. The reaction products containing the newly-formed Csp2—Csp3 bond are generated in high stereoisomeric excess, and may therefore serve as important organic building blocks in the preparation of new agrochemicals and pharmaceuticals.
-
公开(公告)号:US10118872B2
公开(公告)日:2018-11-06
申请号:US15684709
申请日:2017-08-23
IPC分类号: C07C1/26 , C07C1/32 , C07C4/06 , C07C2/06 , C07C1/22 , C07C7/04 , B01J29/85 , C01B39/02 , C10G3/00 , C07C1/20 , B01J29/40
摘要: The present invention is a phosphorous modified zeolite (A) made by a process comprising in that order: selecting a zeolite with low Si/Al ratio (advantageously lower than 30) among H+ or NH4+-form of MFI, MEL, FER, MOR, clinoptilolite, said zeolite having been made preferably without direct addition of organic template; steaming at a temperature ranging from 400 to 870° C. for 0.01-200h; leaching with an aqueous acid solution containing the source of P at conditions effective to remove a substantial part of Al from the zeolite and to introduce at least 0.3 wt % of P; separation of the solid from the liquid; an optional washing step or an optional drying step or an optional drying step followed by a washing step; a calcination step. The present invention also relates to a process (hereunder referred as “XTO process”) for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert at least a portion of the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent).The present invention also relates to a process (hereunder referred as “combined XTO and OCP process”) to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
-
-
-
-
-
-
-
-
-