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公开(公告)号：US10196414B2
公开(公告)日：2019-02-05
申请号：US15103556
申请日：2015-01-22
申请人： GIVAUDAN SA
IPC分类号： C07D307/02 , C07C29/14 , C07C27/04 , C07C29/00 , C07C27/00 , C07C209/00 , C07F15/00 , C07B41/02 , C07C29/149 , C07C29/17 , C07C67/303 , C07D307/79 , C07C33/025 , C07C33/20 , C07C35/36 , C07C69/612
摘要： A process for the hydrogenation of a substrate comprising a carbon heteroatom double bond in the presence of a transition metal complex comprising a tridentate or bisdentate-ligand containing a nitrogen, sulphur and phosphorus atom, of which at least the N- and P- and optionally also the S-atom coordinates with the transition metal.
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公开(公告)号：US09404027B2
公开(公告)日：2016-08-02
申请号：US14058653
申请日：2013-10-21
发明人： Galen J. Suppes
CPC分类号： C09K3/185 , C07C27/04 , C07C29/145 , C07C29/60 , C07C45/52 , C09K5/10 , C09K5/20 , Y02P20/52 , C07C49/17 , C07C31/202 , C07C31/205 , C07C31/225
摘要： A reactive-separation process converts glycerin into lower alcohols, having boiling points less than 200° C., at high yields. Conversion of natural glycerin to propylene glycol through an acetol intermediate is achieved at temperatures from 150° to 250° C. at pressures from 1 and 25 bar. The preferred applications of the propylene glycol are as an antifreeze, deicing compound, or anti-icing compound. The preferred catalyst for this process in a copper-chromium.
摘要翻译： 反应分离方法以高产率将甘油转化成沸点低于200℃的低级醇。 通过丙酮醇中间体将天然甘油转化为丙二醇在1和25巴的压力下，在150〜250℃的温度下进行。 丙二醇的优选应用是防冻剂，除冰化合物或防冰化合物。 铜 - 铬中该方法的优选催化剂。
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公开(公告)号：US09353034B2
公开(公告)日：2016-05-31
申请号：US13368146
申请日：2012-02-07
申请人： Radmila Jevtic , Victor J. Johnston , David Lee , Heiko Weiner , Zhenhua Zhou
发明人： Radmila Jevtic , Victor J. Johnston , David Lee , Heiko Weiner , Zhenhua Zhou
IPC分类号： C07C27/04 , C07C29/149 , C07C51/44
CPC分类号： C07C29/149 , C07C51/44 , C07C31/08
摘要： The present invention is directed to the separation of ethanol from a crude ethanol product obtained from the vaporization and hydrogenation of acetic acid using reduced residence time for the vapor phase reactants between exiting the vaporizer and entering the reactor. The crude ethanol product is separated in at least one column to recover an ethanol product.
摘要翻译： 本发明涉及从蒸发和氢化乙酸获得的粗乙醇产物中分离出乙醇，其中使用蒸气器排出并进入反应器之前的气相反应物的停留时间减少。 将粗乙醇产物在至少一个塔中分离以回收乙醇产物。
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公开(公告)号：US09283537B2
公开(公告)日：2016-03-15
申请号：US14919221
申请日：2015-10-21
申请人： XYLECO, INC.
发明人： Marshall Medoff
CPC分类号： B01J19/085 , B01J19/081 , B01J19/121 , B01J19/123 , B01J19/126 , B01J2219/00006 , B01J2219/08 , B01J2219/0869 , B01J2219/0871 , B01J2219/0879 , B01J2219/089 , B02C23/18 , C07C27/00 , C07C27/04 , C07C27/24 , C08B1/00 , C12M45/00 , C12P7/10 , C12P19/00 , C12P19/02 , C12P19/14 , C12P2201/00 , C13K1/02 , D21B1/02 , D21B1/063 , G21K5/00 , H01J37/3002 , Y02E50/16 , Y02E50/17
摘要： Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy or sugary materials, to produce ethanol and/or butanol, e.g., by fermentation.
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公开(公告)号：US20160024545A1
公开(公告)日：2016-01-28
申请号：US14776161
申请日：2014-03-14
CPC分类号： C12P19/14 , C07C1/20 , C07C1/22 , C07C27/00 , C07C27/04 , C07H3/02 , C10G3/42 , C10G3/50 , C10G2300/1011 , C12P19/02 , C12P2201/00 , C13K1/02 , Y02E50/343 , Y02P30/20 , C07C15/02 , C07C15/24
摘要： Method for creating valuable products from lignocellulosic biomass comprising sequential pretreatment of lignocellulosic biomass with ionic liquid followed by hydrothermal processing of the lignin.
摘要翻译： 从木质纤维素生物质生产有价值产品的方法包括用离子液体连续预处理木质纤维素生物质，然后进行木质素的水热处理。
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公开(公告)号：US09187769B1
公开(公告)日：2015-11-17
申请号：US14810158
申请日：2015-07-27
申请人： XYLECO, INC.
发明人： Marshall Medoff
CPC分类号： B01J19/085 , B01J19/081 , B01J19/121 , B01J19/123 , B01J19/126 , B01J2219/00006 , B01J2219/08 , B01J2219/0869 , B01J2219/0871 , B01J2219/0879 , B01J2219/089 , B02C23/18 , C07C27/00 , C07C27/04 , C07C27/24 , C08B1/00 , C12M45/00 , C12P7/10 , C12P19/00 , C12P19/02 , C12P19/14 , C12P2201/00 , C13K1/02 , D21B1/02 , D21B1/063 , G21K5/00 , H01J37/3002 , Y02E50/16 , Y02E50/17
摘要： Biomass (e.g., plant biomass, animal biomass, and municipal waste biomass) is processed to produce useful products, such as fuels. For example, systems can use feedstock materials, such as cellulosic and/or lignocellulosic materials and/or starchy or sugary materials, to produce ethanol and/or butanol, e.g., by fermentation.
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公开(公告)号：US09187389B2
公开(公告)日：2015-11-17
申请号：US14417576
申请日：2013-08-13
IPC分类号： C07C27/04 , C07C27/00 , C07C29/149
CPC分类号： C07C29/149 , C07C31/08 , C07C31/10 , C07C31/125
摘要： A method of producing an alcohol compound from an organic acid compound including the step of heating a solution of the organic acid compound in the presence of a heterogeneous catalyst including transition metal supported upon a cross-linked functional polymer.
摘要翻译： 一种从有机酸化合物制备醇化合物的方法，包括在包含负载在交联官能聚合物上的过渡金属的多相催化剂存在下加热有机酸化合物溶液的步骤。
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公开(公告)号：US09018426B1
公开(公告)日：2015-04-28
申请号：US14134333
申请日：2013-12-19
发明人： Claudio Ribeiro , Andrew Shuff , Tianshu Pan
摘要： In one embodiment, the invention is to a process for producing multi-carbon alcohols, including butanol and/or hexanol. The process comprises the step of reacting ethanol in a reactor to form a crude product comprising butanol, ethanol, and water. The process further comprises the step of separating at least a portion of the crude product in a first distillation zone to form a first distillate comprising ethanol and a first residue comprising butanol, and water. The process further comprises the step of separating at least a portion of the first residue in a second distillation zone to form a second distillate and a second residue comprising butanol.
摘要翻译： 在一个实施方案中，本发明涉及生产多元醇（包括丁醇和/或己醇）的方法。 该方法包括使乙醇在反应器中反应以形成包含丁醇，乙醇和水的粗产物的步骤。 该方法还包括在第一蒸馏区中分离至少一部分粗产物以形成包含乙醇的第一馏出物和包含丁醇和水的第一残余物的步骤。 该方法还包括在第二蒸馏区中分离至少一部分第一残余物以形成第二馏出物和包含丁醇的第二残余物的步骤。
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9.发明授权Conversion of carbon dioxide into useful organic products by using plasma technology 有权通过使用等离子体技术将二氧化碳转化为有用的有机产物公开(公告)号：US09011648B2
公开(公告)日：2015-04-21
申请号：US13749075
申请日：2013-01-24
CPC分类号： B01J19/087 , B01D53/32 , B01D53/62 , B01D53/92 , B01D2251/208 , B01D2257/504 , B01D2258/01 , B01D2258/0283 , B01D2259/818 , B01J19/088 , B01J19/126 , B01J19/129 , B01J2219/0809 , B01J2219/083 , B01J2219/0835 , B01J2219/0869 , B01J2219/0875 , C07C27/04 , C10G2/40 , C10G2/50 , C10G2300/4012 , C10G2400/02 , C10G2400/04 , Y02C10/04 , Y02P20/152
摘要： The present invention relates to a method of conversion of carbon dioxide into organic products using plasma technology comprising the steps of (a) providing a reaction chamber; (b) introducing a counterpart molecule and carbon dioxide into the reaction chamber; (c) initiating a plasma in the reaction chamber; and (d) converting the carbon dioxide into organic products, wherein the organic products do not contain formic acid and formaldehyde, and wherein the counterpart molecule consists of water molecule.
摘要翻译： 本发明涉及使用等离子体技术将二氧化碳转化为有机产物的方法，包括以下步骤：（a）提供反应室; （b）将对应物分子和二氧化碳引入反应室中; （c）在反应室中引发等离子体; 和（d）将二氧化碳转化为有机产物，其中有机产物不含甲酸和甲醛，并且其中对应物分子由水分子组成。
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10.发明授权公开(公告)号：US08927788B2
公开(公告)日：2015-01-06
申请号：US13457280
申请日：2012-04-26
申请人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
发明人： David Lee , Adam Orosco , Claudio Ribeiro , R. Jay Warner , Robert Alan Deck , Emily Duff , Victor J. Johnston
CPC分类号： C07C29/149 , C07C29/76 , C07C29/80 , C07C29/84 , C07C51/12 , C07C67/08 , C07C67/54 , C10L1/02 , C10L2200/04 , C10L2290/543 , C10L2290/548 , C07C31/08 , C07C53/08 , C07C69/14
摘要： A process for recovering ethanol obtained from the hydrogenation of acetic acid. The crude ethanol product is separated in a column to produce a distillate stream comprising acetaldehyde and ethyl acetate and a residue stream comprising ethanol, acetic acid, ethyl acetate and water. The ethanol product is recovered from the residue stream.
摘要翻译： 一种从乙酸氢化中回收乙醇的方法。 将粗乙醇产物在柱中分离以产生包含乙醛和乙酸乙酯的馏出物流和包含乙醇，乙酸，乙酸乙酯和水的残余物流。 从残余物流中回收乙醇产物。
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