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公开(公告)号:US20240360291A1
公开(公告)日:2024-10-31
申请号:US18646185
申请日:2024-04-25
IPC分类号: C08J9/32 , C08F220/14 , C08F220/44 , C08J9/14 , C08J9/20
CPC分类号: C08J9/32 , C08F220/14 , C08F220/44 , C08J9/141 , C08J9/20 , C08J2203/14 , C08J2203/22 , C08J2300/22
摘要: Thermoplastic thermally expandable microspheres comprise a polymer shell and a propellant, wherein the polymer shell is formed from ethylenically unsaturated monomers and encapsulates the propellant, and wherein the ethylenically unsaturated monomers comprise acrylonitrile in an amount from 45 to 80 weight %, methacrylonitrile in an amount of from 10 to 45 weight %, and methyl acrylate and/or methyl methacrylate in an amount of 5 to 35 weight %, each based on the total weight of ethylenically unsaturated monomers, and wherein the thermoplastic thermally expandable microspheres comprise the propellant in an amount of 5 to 17 weight %, based on the total weight of the thermoplastic thermally expandable microspheres. The thermoplastic thermally expandable microspheres are formed in a process of the disclosure and may be present in an aqueous slurry.
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公开(公告)号:US11993671B2
公开(公告)日:2024-05-28
申请号:US17291347
申请日:2019-11-06
IPC分类号: C08F236/18 , C08F220/44 , B29C35/02
CPC分类号: C08F236/18 , C08F220/44 , B29C35/02 , B29K2011/00
摘要: A chloroprene-unsaturated nitrile copolymer having 3 to 20% by mass of a structural unit derived from an unsaturated nitrile monomer, in which the chloroprene-unsaturated nitrile copolymer has a peak at 5.80 to 6.00 ppm in a 1H-NMR spectrum as measured in a deuterochloroform solvent, and a ratio (A/B) of a peak area (A) at 5.80 to 6.00 ppm and a peak area (B) at 4.05 to 6.20 ppm is 0.6/100 to 1.1/100.
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公开(公告)号:US11897979B2
公开(公告)日:2024-02-13
申请号:US17811301
申请日:2022-07-07
发明人: Zhongyu Fu , Huijie Yan , Huixuan Zhang
IPC分类号: C08F20/44 , C08F220/44 , C08F2/38 , C08F2/44
摘要: Some embodiments of the disclosure provides polyacrylonitrile (PAN) and a preparation method and use thereof. The method includes the following steps. Mixing raw materials for polymerization to obtain a suspension comprising the PAN. The raw materials include an acrylonitrile monomer, a first auxiliary monomer, a second auxiliary monomer, a polymerization medium, an initiator, a chain transfer agent, and a settling agent. Removing unreacted monomers and unreacted polymerization medium in the suspension to obtain the PAN. After subsequent removal of monomers, removal of a polymerization medium, washing, and drying, a PAN powder is obtained. In some embodiments, the preparation method of the PAN has a wide adjustable range of a PAN copolymerization composition, a low viscosity of a polymerization system, a high concentration of a polymerized monomer, and a strong anti-scaling ability.
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公开(公告)号:US20230399503A1
公开(公告)日:2023-12-14
申请号:US18034253
申请日:2022-07-19
申请人: LG CHEM, LTD.
发明人: Jeong Su CHOI , Won Seok LEE , Roo Da LEE , Sang Hoo PARK , Jong Ju LEE
IPC分类号: C08L51/04 , C08L9/06 , C08F212/08 , C08F220/14 , C08F220/44
CPC分类号: C08L51/04 , C08L9/06 , C08F212/08 , C08F220/14 , C08F220/44 , C08L2207/53
摘要: The present disclosure relates to a thermoplastic resin composition which includes: a graft polymer including a rubber polymer having a gel content of 0 to 10 wt % and including an aromatic vinyl-based monomer unit and a diene-based monomer unit; and a shell including a (meth)acrylate-based monomer unit and an aromatic vinyl-based monomer unit which are grafted to the rubber polymer; and a non-grafted polymer including 90 wt % or more of a (meth)acrylate-based monomer unit.
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公开(公告)号:US20230087173A1
公开(公告)日:2023-03-23
申请号:US17957459
申请日:2022-09-30
申请人: TECHNO-UMG CO., LTD.
发明人: Shinji FUJII , Naruki TANAKA
IPC分类号: C08L55/02 , C08F255/04 , C08F212/08 , C08F220/44 , C08G64/04 , C08F236/06 , C08L53/00 , C08F236/08 , C08F8/04 , C08J5/18
摘要: A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.
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公开(公告)号:US20230081156A1
公开(公告)日:2023-03-16
申请号:US17823900
申请日:2022-08-31
发明人: Doo Han HA , Soo Wan KIM , Sung Wook HA
IPC分类号: C08F265/04 , C08K5/3415 , C08K5/1515 , C08K5/42 , C08F12/08 , C08F220/44 , B29C48/00 , B29C48/40 , C08J5/18
摘要: Provided are a matting polymer composition having excellent weather resistance and impact resistance, and a matte sheet including the same. The matting polymer composition according to the present disclosure includes two kinds of styrene-acrylonitrile copolymers having different acrylonitrile contents, and a matting agent, and thus, a molded article manufactured by an extrusion or injection process has mechanical properties such as excellent weather resistance and impact resistance, and also may show an effective matting effect and excellent appearance quality.
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公开(公告)号:US20230064044A1
公开(公告)日:2023-03-02
申请号:US17982698
申请日:2022-11-08
发明人: Wolfgang FISCHER , Peter ITTEMANN , Florian PATCAS , Michael RUF
IPC分类号: C08F2/01 , C08F2/06 , C08F2/34 , C08F212/10 , C08F220/14 , C08F220/44
摘要: A method for producing a polymer from a first component and a second component using a reactor (50) offers technical advantages, wherein reaction heat produced in the reactor (50) is discharged via a boiling cooler (40) by supplying gaseous vapors produced in the reactor (50) to the boiling cooler (40). A product flow containing condensed vapors is returned to the reactor (50) from the boiling cooler (40) via a separation vessel (60), and an aqueous phase is separated from the product flow in the separation vessel (60). A system is provided for producing a polymer from a first component and a second component, comprising a reactor (50) and a boiling cooler (40) for discharging reaction heat produced in the reactor (50). A separation vessel (60) is arranged between the boiling cooler (40) and the reactor (50) such that a product flow containing condensed vapors is returned to the reactor (50) from the boiling cooler (40) via the separation vessel (60).
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公开(公告)号:US20230036829A1
公开(公告)日:2023-02-02
申请号:US17787392
申请日:2021-01-04
发明人: Oguz Türünç , David A. Babb , Florian Puschman , Sven Claessens , Antoon De Smet
IPC分类号: C08G18/63 , C08G18/48 , C08G18/10 , C08G18/08 , C08F212/08 , C08F220/44 , C08F216/14 , C08G65/26 , C08G65/331
摘要: Polyether polyols are prepared by polymerizing unsaturated monomers in a continuous phase of a base polyol. A macromer or polymerization produce of such a macromer is present during the polymerization to stabilize the polymer particles as they form. The macromer is a polyether capped with certain unsaturated epoxide compounds.
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公开(公告)号:US20230020924A1
公开(公告)日:2023-01-19
申请号:US17783682
申请日:2021-11-25
申请人: LG CHEM, LTD.
发明人: Sung Won HONG , Hyung Sub LEE , Dae Woo LEE , Min Cheol JU , Seong Jae SHIN , Min Seung SHIN , In Soo KIM
IPC分类号: C08F212/12 , C08F212/10 , C08F2/18 , C08F212/08 , C08F220/44
摘要: The present invention relates to a method of preparing a polymer, which includes: adding a first reaction solution including an aqueous solvent and a monomer mixture including an alkyl-substituted aromatic vinyl-based monomer, an alkyl-unsubstituted aromatic vinyl-based monomer, and a vinyl cyanide-based monomer to a reactor and initiating polymerization; and performing polymerization by continuously adding an alkyl-substituted aromatic vinyl-based monomer to the reactor, wherein the first reaction solution satisfies Expression 1 (see the description of the invention).
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公开(公告)号:US20220348760A1
公开(公告)日:2022-11-03
申请号:US17774231
申请日:2021-07-19
申请人: LG CHEM, LTD.
发明人: Suk Jo CHOI , Hyun Jun RYU , Tae Hoon KIM
IPC分类号: C08L51/00 , C08F120/14 , C08F212/08 , C08F220/14 , C08F220/44
摘要: Disclosed are a thermoplastic resin composition, a method of preparing the same, and a molded article manufactured using the same. The thermoplastic resin composition includes 3 to 22% by weight of a graft copolymer (A-1) including an acrylate-based rubber having an average particle diameter of 200 to 400 nm, an aromatic vinyl compound, and a vinyl cyanide compound; 17 to 40% by weight of a graft copolymer (A-2) including an acrylate-based rubber having an average particle diameter of 50 to 199 nm, an aromatic vinyl compound, and a vinyl cyanide compound; 30 to 57% by weight of a copolymer (B) including a (meth)acrylic acid alkyl ester compound, an α-methyl styrene-based compound, and a vinyl cyanide compound; and 6 to 30% by weight of a polymethacrylate resin (C) (except for α-methyl styrene), wherein an average multi-axial impact strength is 22 J/mm or more.
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