摘要:
The invention provides a process for producing methanol. The process comprises contacting a gas phase with a solid catalyst, wherein the gas phase comprises (a) H 2 and (b) C0 2 , CO or a mixture of C0 2 and CO, and the catalyst comprises heterometallic particles comprising palladium and zinc. The invention also provides a catalyst which comprises heterometallic particles of palladium and zinc and a support material comprising zinc oxide. Also provided is a process for producing such a catalyst, the process comprising reducing a composition comprising palladium and zinc oxide. A catalyst obtainable by this process is also provided. The invention also relates to uses of the described catalysts for the hydrogenation of C0 2 , CO, or a mixture of C0 2 and CO, to produce methanol, and, more particularly, for the hydrogenation of C0 2 to produce methanol. The invention also provides a composition which comprises palladium, zinc oxide and a compound suitable for promoting the reduction by hydrogen gas of zinc oxide to zinc metal.
摘要:
Systems having at least one photonic antenna molecule and at least one catalyst for degrading a sugar to degradation products using light energy are disclosed. Also disclosed are the devices and methods that use the systems for photocatalytically degrading a sugar into degradation products.
摘要:
A zoned catalysed substrate monolith comprises a first zone and a second zone, wherein the first zone and the second zone are arranged axially in series, wherein the first zone comprises a platinum group metal loaded in a support and a first base metal oxide selected from the group consisting of iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, and mixtures thereof or a first base metal selected from the group consisting of iron, manganese, copper, zinc, nickel, and mixtures thereof loaded on an inorganic oxide and the second zone comprises copper or iron loaded on a zeolite and a second base metal oxide selected from the group consisting of iron oxide, manganese oxide, copper oxide, zinc oxide, nickel oxide, and mixtures thereof or a second base metal selected from the group consisting of iron, manganese, copper, zinc, nickel, and mixtures thereof loaded on an inorganic oxide, wherein the second base metal is different from the first base metal.
摘要:
The present invention relates to a device for treatment of material transported through the device comprising at least one porous element consisting of specific solid metallic structure which allows cross-flow of the material through the porous element and wherein the porous element is coated by a non-acidic metal oxide which is impregnated by palladium (Pd).
摘要:
The present invention is related to a new metal powder catalytic system (catalyst) comprising a cobalt/chrome-alloy as a carrier, its production and its use in hydrogenation processes.
摘要:
A nanocrystalline photocatalyst for water splitting and a method for fabricating a nanocrystalline photocatalyst for water splitting. The photocatalyst comprises a structure having a specific surface area and a volume fraction of atoms located both on the surface and at the grain boundaries adapted for enhancement of a photocatalytic reaction.
摘要:
A method for purification of ethylene-containing feed streams from steam crackers or fluid catalytic crackers (FCC), wherein the feed streams further comprises hydrogen, carbon monoxide, acetylenes, oxygen, nitrogen oxides, is disclosed. The method comprises contacting an ethylene-comprising gas stream with a Ru-based catalyst at reaction temperatures of at least 120°C. The process results in an ethylene- containing feed stream wherein the ethylene is essentially free of acetylenes, nitrogen oxides and oxygen. The purifying of the feed stream occurs with minimal loss of ethylene.
摘要:
Novel catalytic materials and methods for producing the same are shown and described. The present disclosure provides catalytic materials formed from producing an alloy of an oxophilic metal and a metal having electro-oxidative activity using spray pyrolysis. The present disclosure further provides methods and mechanisms for both detecting and removing hydrazine from a system.
摘要:
Catalyst comprising palladium, gold and alkali metal acetate as catalytically active components on an abrasion-resistant support, which is mechanically and thermally stable, shaped bodies that are produced from synthetically pure and mixed metal oxides which may be also modified by means of aluminum, calcium, cerium, iron, lanthanum, magnesium, molybdenum, titanium, yttrium and/or zirconium or oxides thereof. It can be used for preparing vinyl acetate monomer.