摘要:
PROBLEM TO BE SOLVED: To provide a chemically amplified resist composition, from which a pattern can be formed having high sensitivity, high resolution (for example, high resolving power, an excellent pattern profile and small line edge roughness (LER)), high stability with time, little production of scum and good dry etching durability, in particular, a chemically amplified resist composition, which shows a good balance between sensitivity and stability with time owing to an ester group included in an acid multiplication agent expressed by general formula (I), and which is excellent in improving sensitivity by generating a carboxylic acid when the acid multiplication agent is decomposed by an acid, and to provide a resist film, a resist coated mask blank, a method for forming a resist pattern and a photomask using the above composition.SOLUTION: The chemically amplified resist composition comprises (A) a compound expressed by general formula (I) and (B) a compound that generates an acid by irradiation with actinic rays or radiation. In general formula (I), Rto Reach represent a hydrogen atom or a substituent, and two or more in Rto Rmay be bonded to form a ring; Rrepresents a substituent; and A represents a monovalent organic group.
摘要:
PROBLEM TO BE SOLVED: To provide: a chemically amplified positive resist composition which can satisfy high sensitivity, high resolving power, a preferable pattern cross-sectional shape and a preferable roughness property in forming an isolated line pattern; and a resist film, a resist coated mask blank, a resist pattern formation method, and a photomask which use the composition.SOLUTION: Provided is a chemically amplified positive resist composition containing: (A) a compound represented by the specified general formula (1); and (B) a compound having a phenolic hydroxyl group and a group which has a group represented by the specified general formula (2) or (3) substituted for a hydrogen atom of a phenolic hydroxyl group. Also provided are a resist film, a resist coated mask blank, a resist pattern formation method, and a photomask which use the composition. In the specified general formula (1), Z represents a monovalent organic group. In the specified general formulas (2) and (3), Qand Qrepresent an alkyl group or an aryl group.
摘要:
PURPOSE:To obtain a new sulfonic acid derivative having excellent antitumor actions and useful as an anticancer agent. CONSTITUTION:This sulfonic acid ester derivative is expressed by formula I {R1 and R2 are each H, a halogen, lower alkyl, etc.; R3 and R4 are each H, a halogen, lower alkyl, etc.; R5 is H or a lower alkyl; A and B are each N atom or (lower alkyl-substituted)methine; Y is a (substituted)aryl, (CO)-R6 [R6 is a lower alkyl, (substituted)amino, etc.], etc.}, e.g. (2-phenylamino)-3-pyridyl 4-methoxybenzenesulfonate. The compound expressed by formula 1 is obtained by reacting, e.g. a sulfonic acid expressed by formula II or its reactive derivative with a compound expressed by formula III.