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    6'-C-ALKYL-3-DEAZANEPLANOCIN A DERIVATIVE, ITS PRODUCTION AND USE
    5.
    发明专利
    6'-C-ALKYL-3-DEAZANEPLANOCIN A DERIVATIVE, ITS PRODUCTION AND USE 失效

    公开(公告)号：JPH04327587A

    公开(公告)日：1992-11-17

    申请号：JP12282091

    申请日：1991-04-26

    申请人： ASAHI CHEMICAL IND

    发明人： OHARA TAKUMI ,  SHUTO SATOSHI ,  TORIYA MINORU ,  FUJIWARA TATSURO

    IPC分类号： A61K31/52 ,  A61P31/12 ,  C07C43/172 ,  C07C309/66 ,  C07C309/71 ,  C07D471/04 ,  C07F7/18

    摘要： PURPOSE:To obtain a novel compound having high chemotherapeutic coefficient and high safety and useful as an antiviral agent by reacting a cyclopentene derivative with a 3-deazaadenine derivative in an inert solvent and eliminating protecting group from the reaction product. CONSTITUTION:A compound of formula I (Y is lower alkyl; R1' to R3' are OH-protecting group; X is electron-attracting eliminable group) is made to react with a compound of formula II (R4 is H or amino-protecting group) in an inert solvent (e.g. THF) in the presence of 2-5 equivalent of a base (e.g. sodium hydride) and 1-2 equivalent of a crown ether (based on the compound of formula I) e.g. at room temperature to obtain the objective compound of formula III (R1 to R3 are same as R1' to R3'), e.g. 6'-C-methyl-3-deazaneplanocin A derivative.

    Cyclohexane compound and liquid-crystalline composition containing the compound
    6.
    发明专利
    Cyclohexane compound and liquid-crystalline composition containing the compound 审中-公开
    含有化合物的环己酮化合物和液晶组合物

    公开(公告)号：JP2012180284A

    公开(公告)日：2012-09-20

    申请号：JP2010162348

    申请日：2010-07-17

    申请人： Chiracol Co Ltd ,  Organo Science Co Ltd ,  オルガノサイエンス株式会社 ,  株式会社 Chiracol

    发明人： SHIBATA TOSHIHIRO ,  OKAMOTO KAZUO

    IPC分类号： C07C22/00 ,  C07C43/12 ,  C07C43/172 ,  C07C49/417 ,  C07C49/517 ,  C09K19/30 ,  G02F1/13

    摘要： PROBLEM TO BE SOLVED: To provide a new cyclohexane compound that can form a liquid-crystalline composition with improved response speed, by blending the compound with a nematic liquid crystal or the like.SOLUTION: The new cyclohexane compound represented by general formula (1) and a liquid-crystalline composition containing the compound are synthesized, thereby improving the response speed of the stable liquid-crystalline composition, (where in the formula: Rand Rrepresent the same or different R, ROCO or RCOO, R indicates an alkyl group, and the alkyl group may have an unsaturated bond; -CH-, -O-, -CO- or -COO- may substitute in the group; also part or all hydrogen atom(s) may be replaced with a halogen atom or a cyano group), X and Y each independently represent a halogen atom or a hydrogen atom, provided that both are not hydrogen atoms at the same time or/and X represents an oxygen atom and Y represents direct bond to the oxygen atom.

    摘要翻译： 待解决的问题：通过将化合物与向列型液晶等混合，提供能够形成具有改善的响应速度的液晶组合物的新型环己烷化合物。 解决方案：合成由通式（1）表示的新的环己烷化合物和含有该化合物的液晶组合物，从而提高稳定液晶组合物的响应速度（式中，R 1 ，R 2 表示相同或不同的R，ROCO或RCOO，R表示烷基，烷基可具有 不饱和键; -O - ， - CO-或-COO-可以在基团中代替;也可以将部分或全部氢原子替换为 卤素原子或氰基），X和Y各自独立地表示卤素原子或氢原子，条件是同时不是氢原子或/和X表示氧原子，Y表示与氧的直接键合 原子。 版权所有（C）2012，JPO＆INPIT