公开(公告)号：US09121295B2

公开(公告)日：2015-09-01

申请号：US13634420

申请日：2011-03-11

申请人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

发明人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

IPC分类号： B32B27/32 ,  B32B9/00 ,  B32B19/00 ,  F01D5/28 ,  C23C18/12

CPC分类号： F01D5/288 ,  C23C18/1216 ,  C23C18/1245 ,  C23C18/1254 ,  Y10T428/12479 ,  Y10T428/12549

摘要： The invention relates to a method for manufacturing a thermal barrier protection covering a superalloy metal substrate and comprising at least one metal sublayer (13) and a ceramic layer (14) based on zirconia stabilized with yttrium having a column structure defining pores.The following steps are applied: impregnation of a portion of the pores of the ceramic layer (14) with a sol based on zirconia is achieved via a sol-gel route and this in order to form an anchoring sublayer (22), on said ceramic layer topped with said anchoring sub-layer (22), a continuous protective layer (20) based on oxide, is formed via a sol-gel route, and a heat treatment is carried out, whereby an outer protection layer is formed against the attack of the thermal barrier (11) by CMASes. Application to the protection of aeronautical protection parts.

摘要翻译： 本发明涉及一种用于制造覆盖超合金金属基底的热障保护的方法，该方法包括至少一个金属子层（13）和陶瓷层（14），所述金属子层（13）和陶瓷层（14）基于用具有限定孔的柱结构的用钇稳定的氧化锆。 应用以下步骤：通过溶胶 - 凝胶途径实现用基于氧化锆的溶胶浸渍陶瓷层（14）的一部分孔隙，以便在所述陶瓷上形成锚定子层（22） 通过溶胶 - 凝胶途径形成基于氧化物的连续保护层（20），并且进行热处理，从而形成抵抗攻击的外部保护层 的热障（11）。 适用于航空保护部件的保护。

公开(公告)号：US20130071610A1

公开(公告)日：2013-03-21

申请号：US13638133

申请日：2011-04-01

申请人： Sylvain Deville ,  Celine Viazzi ,  Jérôme Leloup

发明人： Sylvain Deville ,  Celine Viazzi ,  Jérôme Leloup

IPC分类号： C04B41/00

CPC分类号： C04B41/0018 ,  B01J21/066 ,  B01J35/04 ,  B01J35/1076 ,  C04B35/111 ,  C04B35/462 ,  C04B35/47 ,  C04B35/486 ,  C04B35/565 ,  C04B35/6263 ,  C04B35/63416 ,  C04B35/63488 ,  C04B35/638 ,  C04B38/0022 ,  C04B2111/00853 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3244 ,  C04B2235/3246 ,  C04B2235/3262 ,  C04B2235/3281 ,  C04B2235/3286 ,  C04B2235/449 ,  C04B2235/5436 ,  C04B2235/6027 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/787 ,  C04B2235/96 ,  H01M4/8605 ,  H01M4/8621 ,  H01M8/0215 ,  H01M8/0217 ,  H01M8/0236 ,  H01M8/1016 ,  H01M8/124 ,  H01M8/1246 ,  H01M8/1253 ,  H01M8/126 ,  Y02E60/525 ,  Y02P70/56 ,  Y10T428/24165 ,  C04B35/00 ,  C04B38/0054 ,  C04B38/0074 ,  C04B38/0605 ,  C04B38/061

摘要： Product formed from a ceramic material, at least part of the product not being formed from amorphous silica, having pores and satisfying the following criteria: (a′) at least 70% by number of the pores are tubular pores extending substantially parallel to each other in a longitudinal direction; (b′) in at least one cross-section plane, at least 30% by number of the pores have a section of convex hexagonal shape, these pores being known hereinbelow as “hexagonal pores”, at least 80% by number of the hexagonal pores having a roundness index of greater than 0.70, the roundness index being equal to the ratio SA/LA of the lengths of the small and long axes of the ellipse in which the section is inscribed; the mean size of the cross sections of the pores is greater than 0.15 μm and less than 25 μm.

摘要翻译： 由陶瓷材料形成的产品，至少部分产品不是由无定形二氧化硅形成，具有孔隙并且满足以下标准：（a'）至少70个数量的孔是基本平行延伸的管状孔 沿纵向; （b'）在至少一个横截面中，至少30％数量的孔具有凸起的六边形形状，这些孔在下文中称为六角形孔，至少80％的六方孔具有 圆度指数大于0.70，圆度指数等于部分刻有椭圆的长轴和长轴长度的比率SA / LA; 孔的横截面的平均尺寸大于0.15μm且小于25μm。

公开(公告)号：US09556075B2

公开(公告)日：2017-01-31

申请号：US13638454

申请日：2011-04-01

申请人： Sylvain Deville ,  Celine Viazzi

发明人： Sylvain Deville ,  Celine Viazzi

IPC分类号： C04B38/00 ,  H01M4/36 ,  H01M8/10 ,  B01D39/20 ,  B01J21/06 ,  B01J35/04 ,  B01J35/10 ,  C04B35/111 ,  C04B35/462 ,  C04B35/47 ,  C04B35/486 ,  C04B35/565 ,  C04B35/626 ,  C04B35/634 ,  C04B35/638 ,  H01M4/86 ,  H01M4/90 ,  H01M8/12 ,  H01M10/0562 ,  C04B111/00

CPC分类号： C04B38/0054 ,  B01D39/2068 ,  B01J21/066 ,  B01J35/04 ,  B01J35/1076 ,  C04B35/111 ,  C04B35/462 ,  C04B35/47 ,  C04B35/486 ,  C04B35/565 ,  C04B35/6263 ,  C04B35/63416 ,  C04B35/63488 ,  C04B35/638 ,  C04B38/0022 ,  C04B38/0605 ,  C04B38/061 ,  C04B2111/00853 ,  C04B2235/3201 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3244 ,  C04B2235/3246 ,  C04B2235/3262 ,  C04B2235/3281 ,  C04B2235/3286 ,  C04B2235/3427 ,  C04B2235/449 ,  C04B2235/5436 ,  C04B2235/6027 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/787 ,  C04B2235/96 ,  H01M4/36 ,  H01M4/8621 ,  H01M4/90 ,  H01M4/9033 ,  H01M8/1016 ,  H01M8/1246 ,  H01M10/0562 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56 ,  Y10T428/24273 ,  Y10T428/249921 ,  C04B35/00 ,  C04B38/0074 ,  C04B38/0003

摘要： Product formed from a ceramic material, at least part of the said product not being formed from amorphous silica and including pores and satisfying the following criteria (a), (b) and (c): (a) at least 70% by number of the said pores are frustoconical tubular pores extending substantially parallel to each other in a longitudinal direction; (b) in at least one cross-section plane, the mean size of the cross sections of the said pores is greater than 0.15 μm and less than 300 μm; (c) in at least one cross-section plane, at least 50% by number of the pores have a convexity index Ic of greater than 87%, the convexity index of a pore being equal to the ratio Sp/Sc of the surfaces Sp and Sc delimited by the perimeter and by the convex envelope of the said pore, respectively.

摘要翻译： 由陶瓷材料形成的产品，所述产品的至少一部分不是由无定形二氧化硅形成并且包括孔并且满足以下标准（a），（b）和（c））：（a）至少70％ 所述孔是在纵向上彼此基本平行延伸的截头圆锥形管状孔; （b）在至少一个横截面中，所述孔的横截面的平均尺寸大于0.15μm且小于300μm; （c）在至少一个横截面中，至少50％数量的孔具有大于87％的凸度指数Ic，孔的凸度等于表面Sp的Sp / Sc比 和Sc分别由所述孔的周长和凸包围分隔开。

公开(公告)号：US20130130052A1

公开(公告)日：2013-05-23

申请号：US13634420

申请日：2011-03-11

申请人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

发明人： Justine Menuey ,  Florence Ansart ,  Jean-Pierre Bonino ,  Justine Fenech ,  Celine Viazzi

IPC分类号： F01D5/28

CPC分类号： F01D5/288 ,  C23C18/1216 ,  C23C18/1245 ,  C23C18/1254 ,  Y10T428/12479 ,  Y10T428/12549

摘要： The invention relates to a method for manufacturing a thermal barrier protection covering a superalloy metal substrate and comprising at least one metal sublayer (13) and a ceramic layer (14) based on zirconia stabilized with yttrium having a column structure defining pores.The following steps are applied: impregnation of a portion of the pores of the ceramic layer (14) with a sol based on zirconia is achieved via a sol-gel route and this in order to form an anchoring sublayer (22), on said ceramic layer topped with said anchoring sub-layer (22), a continuous protective layer (20) based on oxide, is formed via a sol-gel route, and a heat treatment is carried out, whereby an outer protection layer is formed against the attack of the thermal barrier (11) by CMASes. Application to the protection of aeronautical protection parts.

摘要翻译： 本发明涉及一种用于制造覆盖超合金金属基底的热障保护的方法，该方法包括至少一个金属子层（13）和陶瓷层（14），所述金属子层（13）和陶瓷层（14）基于用具有限定孔的柱结构的用钇稳定的氧化锆。 应用以下步骤：通过溶胶 - 凝胶途径实现用基于氧化锆的溶胶浸渍陶瓷层（14）的一部分孔隙，以便在所述陶瓷上形成锚定子层（22） 通过溶胶 - 凝胶途径形成基于氧化物的连续保护层（20），并且进行热处理，从而形成抵抗攻击的外部保护层 的热障（11）。 适用于航空保护部件的保护。

公开(公告)号：US20130105386A1

公开(公告)日：2013-05-02

申请号：US13638454

申请日：2011-04-01

申请人： Sylvain Deville ,  Celine Viazzi

发明人： Sylvain Deville ,  Celine Viazzi

IPC分类号： C04B38/00 ,  H01M4/36 ,  H01M8/10 ,  H01M10/0562 ,  B01D39/20 ,  H01M4/90

CPC分类号： C04B38/0054 ,  B01D39/2068 ,  B01J21/066 ,  B01J35/04 ,  B01J35/1076 ,  C04B35/111 ,  C04B35/462 ,  C04B35/47 ,  C04B35/486 ,  C04B35/565 ,  C04B35/6263 ,  C04B35/63416 ,  C04B35/63488 ,  C04B35/638 ,  C04B38/0022 ,  C04B38/0605 ,  C04B38/061 ,  C04B2111/00853 ,  C04B2235/3201 ,  C04B2235/3208 ,  C04B2235/3225 ,  C04B2235/3227 ,  C04B2235/3244 ,  C04B2235/3246 ,  C04B2235/3262 ,  C04B2235/3281 ,  C04B2235/3286 ,  C04B2235/3427 ,  C04B2235/449 ,  C04B2235/5436 ,  C04B2235/6027 ,  C04B2235/606 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/787 ,  C04B2235/96 ,  H01M4/36 ,  H01M4/8621 ,  H01M4/90 ,  H01M4/9033 ,  H01M8/1016 ,  H01M8/1246 ,  H01M10/0562 ,  Y02E60/521 ,  Y02E60/525 ,  Y02P70/56 ,  Y10T428/24273 ,  Y10T428/249921 ,  C04B35/00 ,  C04B38/0074 ,  C04B38/0003

摘要： Product formed from a ceramic material, at least part of the said product not being formed from amorphous silica and including pores and satisfying the following criteria (a), (b) and (c): (a) at least 70% by number of the said pores are frustoconical tubular pores extending substantially parallel to each other in a longitudinal direction; (b) in at least one cross-section plane, the mean size of the cross sections of the said pores is greater than 0.15 μm and less than 300 μm; (c) in at least one cross-section plane, at least 50% by number of the pores have a convexity index Ic of greater than 87%, the convexity index of a pore being equal to the ratio Sp/Sc of the surfaces Sp and Sc delimited by the perimeter and by the convex envelope of the said pore, respectively.

摘要翻译： 由陶瓷材料形成的产品，所述产品的至少一部分不是由无定形二氧化硅形成并且包括孔并且满足以下标准（a），（b）和（c））：（a）至少70％ 所述孔是在纵向上彼此基本平行延伸的截头圆锥形管状孔; （b）在至少一个横截面中，所述孔的横截面的平均尺寸大于0.15μm和小于300μm; （c）在至少一个横截面中，至少50％数量的孔具有大于87％的凸度指数Ic，孔的凸度等于表面Sp的Sp / Sc比 和Sc分别由所述孔的周长和凸包围分隔开。