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19 条记录 (耗时 0.016 秒)

    Crystalline modification of mixtures of a nickel-quencher and a benzophenone and process for its preparation
    1.
    发明授权
    Crystalline modification of mixtures of a nickel-quencher and a benzophenone and process for its preparation 失效
    镍猝灭剂和二苯甲酮的混合物的结晶改性及其制备方法

    公开(公告)号：US06620867B1

    公开(公告)日：2003-09-16

    申请号：US09673683

    申请日：2000-12-19

    申请人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    发明人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    IPC分类号： C08K546

    CPC分类号： C08J5/18 ,  C08J2323/02 ,  C08K5/005 ,  C08K5/0091 ,  C08L23/02

    摘要： Crystalline modification of mixtures comprising (a) a nickel-quencher corresponding to [2,2′-thio-bis(4-t-octylphenolate)-n-butylamine Nickel (II)] and (b) a 2-hydroxy-4-alkyloxybenzophenone corresponding to 2-hydroxy-4-n-octyloxybenzophenone wherein it has two diffraction lines at angles 2{acute over (ø)}=6.291 and 2{acute over (ø)}=6.888 in the X-Ray diffraction spectrum from powders. The said crystalline modification can be used as a light stabilizer for agricultural films based on polyolefins or polyolefinic copolymers.

    摘要翻译： 混合物的结晶改性，包括（a）对应于[2,2'-硫代 - 双（4-叔辛基苯酚） - 正丁胺镍（II）]的镍猝灭剂和（b）2-羟基-4- 对应于2-羟基-4-正辛氧基二苯甲酮的烷氧基二苯甲酮，其中它具有两个角度为2的衍射线（锐度超过（ø= 6.291和2）（在粉末的X射线衍射光谱中ø= 6.888） 改性剂可用作基于聚烯烃或聚烯烃共聚物的农用薄膜的光稳定剂。

    Process for preparing aryl- or heteroarylhexadienoic acids
    7.
    发明授权
    Process for preparing aryl- or heteroarylhexadienoic acids 失效
    制备芳基或杂芳基己二烯酸的方法

    公开(公告)号：US4355168A

    公开(公告)日：1982-10-19

    申请号：US212238

    申请日：1980-12-02

    申请人： Gian P. Chiusoli ,  William Giroldini ,  Luciano Pallini ,  Giuseppe Salerno

    发明人： Gian P. Chiusoli ,  William Giroldini ,  Luciano Pallini ,  Giuseppe Salerno

    IPC分类号： B01J31/00 ,  C07B31/00 ,  C07B37/02 ,  C07B61/00 ,  C07C51/00 ,  C07C51/353 ,  C07C57/42 ,  C07C59/64 ,  C07C67/00 ,  C07D333/24 ,  C07D213/55 ,  C07C51/347

    CPC分类号： C07D333/24 ,  C07C51/353

    摘要： There is disclosed and claimed a process for preparing aryl- and heteroarylhexadienoic acids which is characterized in that an aryl- or heteroarylacetylene having the formula: R--C.tbd.CH, wherein R is an aryl or heteroaryl group, optionally substituted and having in the aggregate up to 20 carbon atoms, is reacted with 3-butenoic acid CH.sub.2 .dbd.CH--CH.sub.2 --COOH, in an alcoholic medium, at temperatures maintained between 50.degree. C. and 120.degree. C., approximately, in the presence of a catalyst selected from among the phosphinic complexes of rhodium having the formulas: III, Rh(PR'.sub.3).sub.n L.sub.m X associated with alkaline salts of carboxylic acids having up to 4 carbon atoms, and IV, Rh(PR'.sub.3).sub.n L.sub.p.sup.+ Y.sup.-, wherein R' is a hydrocarbyl group having up to 12 carbon atoms; "L" is a linear or cyclic olefin selected from among the olefins having from 2 to 10 carbon atoms and the chelating olefins having from 6 to 8 carbon atoms, n is an integer from 1 to 3, m is an integer from 0 to 2 and such that n+m=2 or 3, and p is an integer from 0 to 3 and such that n+p=3 or 4; X is an anion selected from among the haloid anions, preferably the hydrochloric anion, and the anions of carboxylic acids having up to 4 carbon atoms and Y is a sparingly coordinating anion, preferably selected from PF.sub.6.sup.- and BF.sub.4.sup.-.The compounds obtained are used as intermediates for organic syntheses, with particular regard to the so-called "fine chemicals" such as, for example, additives for polymers and paints, plasticizers, and the like.

    摘要翻译： 公开并要求了一种制备芳基 - 和杂芳基己二烯酸的方法，其特征在于具有下式的芳基 - 或杂芳基乙炔：其中R是芳基或杂芳基，其中R是芳基或杂芳基， 20个碳原子与3-丁烯酸CH 2 = CH-CH 2 -COOH在醇的介质中在保持在50℃和120℃之间的温度下反应，大约在存在催化剂的情况下，选自 具有以下结构式的铑的次膦酸络合物：III，Rh（PR'3）nLmX与具有至多4个碳原子的羧酸的碱金属盐，以及IV，Rh（PR'3）nLp + Y-，其中R'为 具有至多12个碳原子的烃基; “L”是选自具有2至10个碳原子的烯烃和具有6至8个碳原子的螯合烯烃，n为1至3的整数的直链或环状烯烃，m为0至2的整数 并且使得n + m = 2或3，并且p是0至3的整数，并且使得n + p = 3或4; X是选自卤素阴离子，优选盐酸阴离子的阴离子和具有至多4个碳原子的羧酸阴离子，Y是一种微量配位阴离子，优选选自PF6-和BF4-。 所得化合物用作有机合成的中间体，特别涉及所谓的“精细化学品”，例如聚合物和油漆的添加剂，增塑剂等。

    Granular form of a mixture of a nickel-quencher and a benzophenone and process for its preparation
    8.
    发明授权
    Granular form of a mixture of a nickel-quencher and a benzophenone and process for its preparation 失效
    颗粒形式的镍猝灭剂和二苯甲酮的混合物及其制备方法

    公开(公告)号：US06403679B1

    公开(公告)日：2002-06-11

    申请号：US09622045

    申请日：2000-08-23

    申请人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    发明人： Carlo Neri ,  Luciano Pallini ,  Giovanni Sandre

    IPC分类号： C08K546

    CPC分类号： C08K5/132 ,  C08K5/005 ,  C08K5/0091 ,  C08L23/02

    摘要： Granular form of a mixture comprising: (a) a nickel-quencher corresponding to [2,2′-thio-bis(4-t-octyl-phenolate)-n-butylamine Nickel (II)]; (b) a 2-hydroxy-4-alkyloxybenzophenone corresponding to 2-hydroxy-4-n-octyloxybenzophenone; characterized in that it has two diffraction lines at angles 2&thgr;=17.593 and 2&thgr;=22.023 in the X-Ray diffraction spectrum from powders. The above granular form can be used as a light stabilizer for agricultural films based on polyolefins or olefinic copolymers.

    摘要翻译： 混合物的颗粒形式包括：（a）对应于[2,2'-硫代 - 双（4-叔辛基 - 苯酚） - 正丁胺镍（II）]的镍猝灭剂; （b）对应于2-羟基-4-正辛氧基二苯甲酮的2-羟基-4-烷氧基二苯甲酮; 其特征在于，在来自粉末的X射线衍射光谱中，它具有角度2θ= 17.593和2θ= 22.023的两条衍射线。 上述颗粒形式可用作基于聚烯烃或烯烃共聚物的农用薄膜的光稳定剂。