公开(公告)号：US20180362688A1

公开(公告)日：2018-12-20

申请号：US16061192

申请日：2016-12-09

Applicant: Arkema France

Inventor： Sylvain BOURRIGAUD ,  Pierre GERARD ,  Daniel CALLIN ,  Gilles MEUNIER ,  Sylvain C. LAMARRE ,  Sylvain D. QUERUEL

IPC: C08F220/14 ,  C08F220/06 ,  C08F2/02 ,  C08F6/10 ,  C08L33/12 ,  C08L33/02

Abstract: “The present invention relates to a polymeric composition comprising a polymer comprising monomers of methyl methacrylate and methacrylic acid. In particular the present invention relates to a process for making a polymeric composition suitable for moulded objects, said polymeric composition is comprising monomers of methyl methacrylate and methacrylic acid. The present invention concerns also process for making a moulded object comprising a polymer comprising monomers of methyl methacrylate and methacrylic acid. The present invention concerns also moulded object comprising a polymer comprising monomers of methyl methacrylate and methacrylic acid.”

公开(公告)号：US20180009968A1

公开(公告)日：2018-01-11

申请号：US15705713

申请日：2017-09-15

Applicant: Arkema France

Inventor： Pierre GERARD ,  Michel GLOTIN ,  Gilles HOCHSTETTER

IPC: C08K7/14 ,  C08K7/06 ,  C08F220/14 ,  B29C70/44 ,  C08F265/06 ,  C08L33/12 ,  C08J5/24 ,  B29K33/00

Abstract: The present invention relates to a composite material obtained by in situ polymerization of a thermoplastic resin with a fibrous material. More particularly the present invention relates to a polymeric composite material obtained by in-situ polymerization of a thermoplastic (meth)acrylic resin and a fibrous material containing long fibers and its use, a process for making such a composite material and manufactured mechanical or structured part or article comprising this polymeric composite material.

公开(公告)号：US20170361547A1

公开(公告)日：2017-12-21

申请号：US15532755

申请日：2015-12-03

Applicant: Arkema France ,  INSTITUT DE SOUDURE

Inventor： Jean-Pierre CAUCHOIS ,  Gilles FRANCOIS ,  Pierre GERARD ,  Henri PERRIN ,  Sébastien TAILLEMITE

IPC: B29C70/46 ,  B29C33/10 ,  B29C43/36 ,  B29C70/48

Abstract: The invention relates to a molding device (1) and a method for the manufacture of structured or semistructured composite components comprising a polymer resin (50) and a fibrous substrate (51). According to the invention, the device comprises a mold (2) comprising a bottom and a lateral surface, a part (10) that is movable along the lateral surface of the mold, comprising a compression surface (14) forming a cavity (7) with the bottom and the lateral surface (5) of said mold (2), characterized in that the movable part (10) comprises a vacuum-drawing channel (13, 23) opening into a chamber (25, 42) located above the cavity and communicating with said cavity (7).

公开(公告)号：US20160030896A1

公开(公告)日：2016-02-04

申请号：US14775239

申请日：2014-03-11

Applicant: POLYMEN ,  ARKEMA FRANCE ,  CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE ,  UNIVERSITE PAUL SABATIER TOULOUSE

Inventor： Olivier LORAIN ,  Jean-Michel ESPENAN ,  Jean-Christophe REMIGY ,  Jean-Francois LAHITTE ,  Jean-Christophe ROUCH ,  Thibaut SAVART ,  Pierre GERARD ,  Stephanie MAGNET

IPC: B01D71/80 ,  C08L53/00 ,  C02F1/44 ,  C08F293/00

CPC classification number: B01D71/80 ,  B01D67/0011 ,  B01D71/34 ,  B01D71/40 ,  C02F1/44 ,  C08F293/00 ,  C08F293/005 ,  C08F2438/02 ,  C08L53/00 ,  C08F220/14 ,  C08F2220/1825 ,  C08F220/20 ,  C08L27/16

Abstract: A copolymer having amphiphilic blocks includes at least one first hydrophilic block, obtainable from n-butyl acrylate and hydroxyethyl methacrylate monomers, and a second hydrophobic block likely to be obtained from a methyl methacrylate monomer. The copolymer is found to be particularly advantageous for use as an additive for manufacturing a polymer filtration membrane, particularly a PVDF membrane, particularly via a phase inversion method.

Abstract translation: 具有两亲性嵌段的共聚物包括至少一种可从丙烯酸正丁酯和甲基丙烯酸羟乙酯单体获得的第一亲水嵌段和可能由甲基丙烯酸甲酯单体获得的第二疏水嵌段。 发现该共聚物特别有利于用作制备聚合物过滤膜，特别是PVDF膜的添加剂，特别是通过相转化法。

公开(公告)号：US20160017138A1

公开(公告)日：2016-01-21

申请号：US14772847

申请日：2014-03-07

Applicant: ARKEMA FRANCE

Inventor： Pierre GERARD

IPC: C08L53/00 ,  B29C70/48 ,  C08L33/08

CPC classification number: C08L53/00 ,  B29C70/48 ,  B29K2033/08 ,  B29K2105/0809 ,  C08F220/14 ,  C08F2438/02 ,  C08J5/24 ,  C08J2333/12 ,  C08L25/14 ,  C08L33/08 ,  C08L33/12 ,  D06M13/203 ,  D06M15/263

Abstract: The invention relates to a liquid (meth)acrylic syrup for impregnating a fibrous substrate. The invention especially relates to a viscous liquid syrup mainly containing methacrylic or acrylic components. The invention also relates to a method for producing such a syrup. The invention relates further to a process for impregnating a fibrous substrate or long fibers with said viscous liquid syrup. The invention also relates to a fibrous substrate preimpregnated with said syrup, which is useful for the production of mechanical or structured parts or products. The invention also relates to a production method for producing mechanical or structured parts or items and to three-dimensional mechanical or structured parts produced by said method. The invention applies to the production of mechanical parts or structural elements made of impact-resistant thermoplastic composite material.

Abstract translation: 本发明涉及一种用于浸渍纤维基材的液体（甲基）丙烯酸浆液。 本发明特别涉及主要含有甲基丙烯酸或丙烯酸成分的粘稠液体糖浆。 本发明还涉及一种生产这种糖浆的方法。 本发明还涉及用所述粘性液体糖浆浸渍纤维基质或长纤维的方法。 本发明还涉及用所述糖浆预先浸渍的纤维基质，其可用于生产机械或结构化部件或产品。 本发明还涉及用于生产机械或结构化零件或物品的生产方法以及通过所述方法生产的三维机械或结构零件。 本发明适用于由耐冲击热塑性复合材料制成的机械部件或结构元件的生产。

公开(公告)号：US20210040305A1

公开(公告)日：2021-02-11

申请号：US17078144

申请日：2020-10-23

Applicant: Arkema France

Inventor： Raber INOUBLI ,  Philippe HAJJI ,  Rosangela PIRRI ,  Pierre GERARD

IPC: C08L33/12 ,  C08F265/08 ,  C08F220/14 ,  C08L51/00 ,  C08J5/24

Abstract: The present invention relates to a liquid (meth)acrylic composition comprising a (meth)acrylic monomer, a (meth)acrylic polymer and a multistage polymer.
In particular the present invention it relates to liquid composition comprising a (meth)acrylic monomer, a (meth)acrylic polymer and a multistage polymer that can be used as a syrup and especially as a syrup for impregnation.

公开(公告)号：US20210009740A1

公开(公告)日：2021-01-14

申请号：US16977221

申请日：2019-03-05

Applicant: Arkema France

Inventor： Pierre GERARD

IPC: C08F265/06 ,  C08J5/24

Abstract: The present invention relates to a precursor composition for (meth) acrylic thermoplastic composites, its method of preparation and its use. In particular it relates to a semi-fabricated composition comprising a (meth) acrylic polymer, a monomer, a fibrous material and at least one initiator. More particularly the present invention relates to a precursor composition comprising a (meth) acrylic polymer, a monomer, a fibrous material and at least two initiators. The present invention relates also to a method of preparation of a composition comprising a (meth) acrylic polymer, a monomer, a fibrous material and at least two initiators.

公开(公告)号：US20190039029A1

公开(公告)日：2019-02-07

申请号：US16073855

申请日：2017-02-01

Applicant: Arkema France ,  Polymem

Inventor： Walter Phillip KOSAR ,  Olivier LORAIN ,  Sébastien MARCELLINO ,  François BEAUME ,  Pierre GERARD

IPC: B01D71/80 ,  B01D71/32 ,  B01D71/40 ,  B01D61/14 ,  C08F293/00 ,  C08F220/18 ,  C08F220/28

Abstract: Provided is a an amphiphilic diblock copolymer including from 40 to 60% by weight, relative to the weight of the copolymer, of a hydrophilic block including a unit derived from an n-butyl acrylate monomer and a derived from a hydroxyethyl methacrylate monomer. The copolymer also includes from 40 to 60% by weight, relative to the weight of the copolymer, of a hydrophobic block including at least one unit derived from a methyl methacrylate monomer. Also provided is a polymeric membrane that includes the block copolymer and a hydrophobic polymeric matrix. This membrane is useful for treating an effluent, for example, water.

公开(公告)号：US20190031875A1

公开(公告)日：2019-01-31

申请号：US16068993

申请日：2017-01-11

Applicant: Arkema France

Inventor： Raber Inoubli ,  Philippe HAJJI ,  Rosangela PIRRI ,  Pierre GERARD

IPC: C08L33/12 ,  C08J5/24

Abstract: The present invention relates to a liquid (meth) acrylic composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer. In particular the present invention it relates to liquid composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer that can be used as a syrup and especially as a syrup for impregnation. More particularly the present invention relates also to a process for preparing a liquid composition comprising a (meth) acrylic monomer, a (meth) acrylic polymer and a multistage polymer.

公开(公告)号：US20160009878A1

公开(公告)日：2016-01-14

申请号：US14772862

申请日：2014-03-07

Applicant: ARKEMA FRANCE

Inventor： Pierre GERARD

IPC: C08J5/10 ,  C08J5/24 ,  C08L33/12 ,  C08K3/00 ,  C08K7/28

CPC classification number: C08J5/10 ,  C03C25/285 ,  C08F220/14 ,  C08J5/24 ,  C08J2333/12 ,  C08J2433/12 ,  C08K3/013 ,  C08K3/36 ,  C08K7/28 ,  C08L33/12 ,  C08L33/14 ,  D06M13/203 ,  D06M15/263

Abstract: The invention relates to a liquid (meth)acrylic syrup for impregnating a fibrous substrate. The invention especially relates to a viscous liquid syrup mainly containing methacrylic or acrylic components. The invention also relates to a method for producing such a syrup. The invention relates further to a method for impregnating a fibrous substrate or long fibers with said viscous liquid syrup. The invention also relates to a fibrous substrate pre impregnated with said syrup, which is useful for the production of mechanical or structured parts or products. The invention also relates to a production method for producing mechanical or structured parts or items and to three-dimensional mechanical or structured parts produced by said method. The invention allows significant reduction of the exothermic peak during the polymerization of the syrup, reduction of the residual monomer content at the end of the polymerization, and production of parts in a composite material without defects or with few defects.

Abstract translation: 本发明涉及一种用于浸渍纤维基材的液体（甲基）丙烯酸浆液。 本发明特别涉及主要含有甲基丙烯酸或丙烯酸成分的粘稠液体糖浆。 本发明还涉及一种生产这种糖浆的方法。 本发明还涉及一种用所述粘性液体糖浆浸渍纤维基质或长纤维的方法。 本发明还涉及预浸渍有所述糖浆的纤维基材，其可用于生产机械或结构化部件或产品。 本发明还涉及用于生产机械或结构化零件或物品的生产方法以及通过所述方法生产的三维机械或结构零件。 本发明允许在糖浆聚合期间显着降低放热峰，聚合结束时残留单体含量的降低以及复合材料中没有缺陷或少量缺陷的部件的生产。