摘要:
The invention relates to polysiloxane block copolymers of the formula A[LB(S)Q]m, where A is a polysiloxane block, L is a divalent organic linker, B is a polymer block composed of radically polymerizable monomers, S is a sulfur atom and Q is a monovalent organic radical and m is an integer from 1 to 50, to a method for their production, and to their use in cosmetics or personal care.
摘要:
An enzymatic process for preparing ethers is disclosed which includes reacting one or more alcohols with an ether in the presence of at least one enzyme.
摘要:
The invention relates to a process for the preparation of fatty acid partial esters of polyols, the fatty acid partial esters thus obtainable, and their use. The fatty acid partial esters (I) of polyols having at least 4 C atoms, at least one primary and at least one secondary alcohol group of the starting polyols are obtained in a process, where in a first process step the polyols are reacted with a fatty acid or a fatty acid derivative to give a fatty acid partial ester (II) and in a second process step the fatty acid partial esters (II) obtained are subjected to a selective enzymatic cleavage of primary ester groups.
摘要:
The present invention describes condensation products of polyether-modified and optionally hydrophobically modified monoesters and/or -amides of &agr;, &bgr;-unsaturated dicarboxylic acids and ammonia, their preparation and use. The condensation products contain polyoxyalkylene chains bonded via ester and/or amide bonds and prepared from monoesters and/or monoamides of monoethylenically unsaturated dicarboxylic acids and ammonia or prepared from the ammonium salts of said acids, and the mixtures thereof, optionally in the presence of cocondensable compounds.
摘要:
The present invention provides a process for enzymatic preparation of acrylic esters and/or methacrylic esters of polyoxyalkylenes, and to the use thereof. The acryloyl and/or methacryloyl compounds of polyoxyalkylenes are obtainable by a process for esterifying or transesterifying acrylic and/or methacrylic acid or acrylic and/or methacrylic esters with a polyoxyalkylene of the general formula (I) wherein R1, R2, R3 and a-e are as defined in claim 1 and wherein at least one OH group is present per molecule and the sequence of the polyoxyalkylene segments (C2H4-aR2aO)b and (CcH2cO)d is arbitrary, in the presence of an enzyme which catalyzes the esterification or transesterification.
摘要翻译:本发明提供了一种用于酶制备聚氧化烯的丙烯酸酯和/或甲基丙烯酸酯的方法及其用途。 聚氧化烯的丙烯酰基和/或甲基丙烯酰基化合物可通过丙烯酸和/或甲基丙烯酸或丙烯酸和/或甲基丙烯酸酯与通式(I)的聚氧化烯酯化或酯交换的方法获得,其中R1,R2,R3和ae为 如在权利要求1中所定义的,并且其中每个分子存在至少一个OH基团,并且在催化酯化或酯交换的酶的存在下,聚氧化烯链段(C 2 H 4 -a R 2a)b和(C 1 H 8 C 10)d的序列是任意的。
摘要:
The invention relates to a method for separating alkyl glycoside mixtures or alcohol-containing alkyl glycoside mixtures by extraction, which is characterized in that the extraction is carried out with an extraction agent, which is close to or below the critical point at a reduced temperature ranging from 0.9 to 1.2, and at pressures, which are selected so that the density of the extraction agent is at least 180 kg/m.sup.3.
摘要翻译:本发明涉及一种通过提取分离烷基糖苷混合物或含醇烷基糖苷混合物的方法,其特征在于用提取剂进行萃取,该提取剂在降低的温度范围内接近或低于临界点 0.9至1.2,并且在压力下,其选择使得提取剂的密度为至少180kg / m 3。
摘要:
An organic phase which comprises a water-insoluble material to be encapsulated, a capsule-forming or matrix-forming monomer or prepolymer and, should this be desirable, a solvent, is dispersed in droplet form in an aqueous phase. The capsule-forming or matrix-forming monomer or prepolymer forms a sheath around the material to be encapsulated. As a capsule-forming or matrix-forming monomer, an organosilicon compound of the general formula ##STR1## is used, wherein R.sup.1 is a linear or branched, saturated or unsaturated, n-functional hydrocarbon moiety, which may be interrupted by groups containing oxygen, nitrogen or sulfur; R.sup.2 and R.sup.3 are the same or different and represent a hydrocarbon moiety with 1 to 6 carbon atoms or X; X is a hydroxyl group or a hydrolyzable group and n is a whole number greater than or equal to 1, with the proviso that, when n=1, R.sup.1 has at least 12 carbon atoms and R.sup.2 and R.sup.3 represent X or a prepolymer hereof. The method can be carried out easily and requires only one compound to form the capsules or micromatrix bodies. In the implementation of the method, no foam occurs and the method results in end products with an acceptable shelf life.
摘要:
The invention relates to the use of compounds of the general formula (I) wherein R, R′=H, C1-5-hydrocarbon radical, —O—C1-5-oxyhydrocarbon radical and are identical or different, R1, R2, R3=H, C1-5-hydrocarbon radical and are identical or different, X, Y=—O—; —O—C(O)—; —(O)C—O— and are identical or different, A=Aα=—O—C(O)—O—; Aβ=R4—CH2C(CH2—)3, Aγ=—C(H)-isopropyl, R4=R4δ=—CH3; R4ε=—[CH2—CH(R1)]e—(Y)d—(CH2)c-Ph(R)a, a, b=1 to 5 and are identical or different, c, k=0 to 5 and are identical or different, d, h=0 or 1 and are identical or different, e, g=0 or 1 and are identical or different, f=0 or 1, m=1 to 3, n=0 or 1, as solubilizing agents/solvents for dissolving organic UV filters.
摘要:
The invention relates to a process for preparing alkylpolyglycosides from monomeric glycosides, oligo- or polyglycosides and alcohols according to the general scheme (Glyc-O)zH+R1—OH→(Glyc-O)z′R1 where z≧1 z′≦z, preferably from 1 to 10, (Glyc-O)— is a glycoside radical, R1 is a hydrocarbon radical which optionally contains multiple bonds and/or heteroatoms, which comprises carrying out the reaction under supercritical conditions with regard to the alcohol, preferably at pressures and temperatures which are at least 5% above the critical parameters, the alcohols serving both as the solvent and as reactants.
摘要:
The invention relates to a process for the enzymatic preparation of regioselective fatty acid esters of ascorbic acid and selected fatty acid alkyl esters.Ascorbic acid and fatty acid alkyl esters are reacted in a solvent or suspending agent at reduced pressure in relation to the atmosphere and temperatures above the boiling point of the resulting alcohol of reaction.