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公开(公告)号:US10982134B2
公开(公告)日:2021-04-20
申请号:US16070300
申请日:2017-02-20
Inventor: Jessica Ye Huang , Zhifeng Bai , Liang Chen , Jake Joo , Ing-Feng Hu , James C. Taylor
IPC: C09K11/02 , C08F222/10 , C09D133/12 , C09K11/08 , C08K3/013
Abstract: A polymer composite comprising quantum dots; said polymer composite comprising: (a) quantum dots; (b) polymerized units of a first compound having at least one readily polymerizable vinyl group, a molecular weight from 300 to 20,000 and at least one continuous acyclic hydrocarbyl chain of at least five carbon atoms; and (c) polymerized units of a second compound having at least one readily polymerizable vinyl group and a molecular weight from 100 to 750; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring, and the molecular weight of the first compound minus the molecular weight of the second compound is at least 100.
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公开(公告)号:US20180230377A1
公开(公告)日:2018-08-16
申请号:US15880879
申请日:2018-01-26
Inventor: Liang Chen , Leslie E. O'Leary , Zhifeng Bai , Yuming Lai , Jake Joo
IPC: C09K11/02 , C09K11/88 , C09K11/70 , C08F220/16 , C09D5/22 , C09D5/24 , C09D133/06 , B01D15/08
Abstract: The present invention provides methods for making polymerizable monomer compositions comprising purifying a (b) monomer mixture of (i) one or more monomers having at least two polymerizable vinyl groups and (ii) one or more monomers having a single polymerizable vinyl group as part of a (meth)acrylate ester group by any one or more of treating the monomer mixture in an activated porous alumina or silica column, sieve drying the monomer mixture in a vacuum followed by drying over dried molecular sieves having average pore sizes of from 2 to 20 Angstroms, freeze-pump-thaw (FPT) treating by freezing the monomer mixture in a vessel or container to a temperature below −75° C., degassing the monomer mixture by application of vacuum in the range of 102 to 10−2 Pa, sealing the vessel or container under vacuum, and thawing the composition to room temperature; and, combining in an inert gas atmosphere the resulting monomer mixture (b) with a composition (a) of quantum dots in dry form or organic solvent solution.
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公开(公告)号:US10894916B2
公开(公告)日:2021-01-19
申请号:US16078778
申请日:2017-03-31
Inventor: Liang Chen , Jake Joo , Yuming Lai , Zhifeng Bai , Jessica Ye Huang , James C. Taylor
IPC: C09K11/02 , C09K11/06 , C09K11/88 , C09K11/77 , C09K11/89 , C09D4/06 , C08F220/20 , C09D133/06 , C08L33/14 , C08L35/02 , C08F222/10 , B82Y20/00 , B82Y40/00
Abstract: A polymer composite comprising quantum dots. The polymer composite comprises: (a) quantum dots; (b) a first polymer having a molecular weight from 1,000 to 100,000 and a solubility parameter from 12 to 17 (J/cm3)1/2; (c) a second polymer comprising polymerized units of a first compound comprising at least one readily polymerizable vinyl group and having a molecular weight from 72 to 500, wherein the second polymer has a solubility parameter from 16.5 to 20 (J/cm3)1/2; and (d) a third polymer comprising polymerized units of a second compound comprising at least two readily polymerizable vinyl groups and having a molecular weight from 72 to 2000; wherein the first polymer encapsulates the quantum dots; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring.
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公开(公告)号:US10510924B2
公开(公告)日:2019-12-17
申请号:US14599181
申请日:2015-01-16
Applicant: The Board of Trustees of the University of Illinois , Rohm and Haas Electronic Materials LLC , Dow Global Technologies LLC
Inventor: Moonsub Shim , Nuri Oh , You Zhai , Sooji Nam , Peter Trefonas, III , Kishori Deshpande , Jake Joo
IPC: H01L29/06 , H01L29/12 , H01L33/06 , B82Y10/00 , B82Y30/00 , B82Y40/00 , H01L31/0296 , H01L31/0352 , H01L33/18 , H01L21/02 , H01L51/50 , H01L29/225 , H01L31/18 , H01L33/00 , H01L33/28 , H01L33/50 , H01L51/00 , B82Y20/00
Abstract: Disclosed herein is a semiconducting nanoparticle comprising a one-dimensional semiconducting nanoparticle having a first end and a second end; where the second end is opposed to the first end; and two first endcaps, one of which contacts the first end and the other of which contacts the second end respectively of the one-dimensional semiconducting nanoparticle; where the first endcap that contacts the first end comprises a first semiconductor and where the first endcap extends from the first end of the one-dimensional semiconducting nanoparticle to form a first nanocrystal heterojunction; where the first endcap that contacts the second end comprises a second semiconductor; where the first endcap extends from the second end of the one-dimensional semiconducting nanoparticle to form a second nanocrystal heterojunction; and where the first semiconductor and the second semiconductor are chemically different from each other.
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公开(公告)号:US20190085112A1
公开(公告)日:2019-03-21
申请号:US16078878
申请日:2017-05-12
Inventor: Zhifeng Bai , Jake Joo , James C. Taylor , Liang Chen , Valerity V. Ginzburg , Jessica Ye Huang , Christopher J. Tucker
IPC: C08F287/00 , C08F292/00
Abstract: A polymer resin comprising: (a) quantum dots, (b) a compound of formula (I) (I) wherein R1 is hydrogen or methyl and R2 is a C6-C20 aliphatic polycyclic substituent, and (c) a block or graft copolymer having Mn from 50,000 to 400,000 and comprising from 10 to 100 wt % polymerized units of styrene and from 0 to 90 wt % of a non-styrene block; wherein the non-styrene block has a van Krevelen solubility parameter from 15.0 to 17.5 (J/cm3)1/2.
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公开(公告)号:US10889675B2
公开(公告)日:2021-01-12
申请号:US16078878
申请日:2017-05-12
Inventor: Zhifeng Bai , Jake Joo , James C. Taylor , Liang Chen , Valeriy V. Ginzburg , Jessica Ye Huang , Christopher J. Tucker
IPC: B82Y20/00 , B82Y40/00 , C08F287/00 , C08F292/00 , C09K11/02 , C08K5/10 , C08K3/08 , B82Y30/00
Abstract: A polymer resin comprising: (a) quantum dots, (b) a compound of formula (I) (I) wherein R1 is hydrogen or methyl and R2 is a C6-C20 aliphatic polycyclic substituent, and (c) a block or graft copolymer having Mn from 50,000 to 400,000 and comprising from 10 to 100 wt % polymerized units of styrene and from 0 to 90 wt % of a non-styrene block; wherein the non-styrene block has a van Krevelen solubility parameter from 15.0 to 17.5 (J/cm3)1/2.
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公开(公告)号:US20200299573A1
公开(公告)日:2020-09-24
申请号:US16086108
申请日:2016-03-30
Applicant: Dow Global Technologies LLC
Inventor: Bo Lv , Xiuyan Wang , Yan Huang , Xiaofan Ren , Jake Joo , Ping Zhu
Abstract: A method of preparing a semiconductor nanocrystal-silicate composite without significantly reducing the quantum yield of the semiconductor nanocrystal, a composite prepared from the method, and a film and an electronic device comprising the composite.
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公开(公告)号:US20190062626A1
公开(公告)日:2019-02-28
申请号:US16070300
申请日:2017-02-20
Inventor: Jessica Ye Huang , Zhifeng BAI , Liang Chen , Jake Joo , Ing-Feng Hu , James C. Taylor
IPC: C09K11/02 , C08F222/10 , C08K3/013
Abstract: A polymer composite comprising quantum dots; said polymer composite comprising: (a) quantum dots; (b) polymerized units of a first compound having at least one readily polymerizable vinyl group, a molecular weight from 300 to 20,000 and at least one continuous acyclic hydrocarbyl chain of at least five carbon atoms; and (c) polymerized units of a second compound having at least one readily polymerizable vinyl group and a molecular weight from 100 to 750; wherein a readily polymerizable vinyl group is part of a (meth)acrylate ester group or is attached directly to an aromatic ring, and the molecular weight of the first compound minus the molecular weight of the second compound is at least 100.
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公开(公告)号:US20190048257A1
公开(公告)日:2019-02-14
申请号:US16078815
申请日:2017-04-03
Inventor: Jake Joo , Kathleen M. O'Connell , Liang Chen , Daniel L. Dermody , Zhifeng Bai , James C. Taylor
IPC: C09K11/02
Abstract: A method for encapsulating quantum dots. The method comprises steps of: (a) mixing quantum dots with a polymer having a molecular weight from 1,000 to 200,000 and a solubility parameter from 14 to 18.75 (J/cm3)1/2 and a solvent to form a mixture; and (b) spray drying the mixture to produce an encapsulated quantum dot powder.
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公开(公告)号:US10472563B2
公开(公告)日:2019-11-12
申请号:US15880879
申请日:2018-01-26
Inventor: Liang Chen , Leslie E. O'Leary , Zhifeng Bai , Yuming Lai , Jake Joo
IPC: C07C27/26 , C07C67/48 , C09K11/02 , C09K11/54 , C09K11/62 , C09K11/70 , B01D15/08 , C08F220/16 , C09D5/22 , C09D5/24 , C09D133/06 , C09K11/88 , C08F220/18 , B82Y20/00 , B82Y40/00 , C08K3/30 , C08K3/32 , C08K9/02 , B82Y30/00
Abstract: The present invention provides methods for making polymerizable monomer compositions comprising purifying a (b) monomer mixture of (i) one or more monomers having at least two polymerizable vinyl groups and (ii) one or more monomers having a single polymerizable vinyl group as part of a (meth)acrylate ester group by any one or more of treating the monomer mixture in an activated porous alumina or silica column, sieve drying the monomer mixture in a vacuum followed by drying over dried molecular sieves having average pore sizes of from 2 to 20 Angstroms, freeze-pump-thaw (FPT) treating by freezing the monomer mixture in a vessel or container to a temperature below −75° C., degassing the monomer mixture by application of vacuum in the range of 102 to 10−2 Pa, sealing the vessel or container under vacuum, and thawing the composition to room temperature; and, combining in an inert gas atmosphere the resulting monomer mixture (b) with a composition (a) of quantum dots in dry form or organic solvent solution.
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