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公开(公告)号:US11318451B2
公开(公告)日:2022-05-03
申请号:US16545464
申请日:2019-08-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Preeti Kamakoti , Scott J. Weigel , Karl G. Strohmaier , Helge Jaensch , Marc H. Anthonis , Martine Dictus , Brita Engels , Darryl D. Lacy , Sina Sartipi , Brandon J. O'Neill
Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
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公开(公告)号:US10226319B2
公开(公告)日:2019-03-12
申请号:US15882353
申请日:2018-01-29
Applicant: ExxonMobil Research and Engineering Company
Inventor: Allen W. Burton , Karl G. Strohmaier , Scott J. Weigel
IPC: C01B39/48 , B01J29/70 , A61F2/00 , C01B39/02 , B01J37/10 , B01J37/30 , B01D53/04 , B01D53/75 , B01D53/86 , F01N3/08 , C01B39/04 , B01D53/92 , B01D53/94 , A61B17/06 , A61B17/34 , B01J29/03 , A61B17/04 , A61B17/00 , A61B17/32
Abstract: A method for reducing the level of occluded alkali metal cations from an MSE-framework type molecular sieve comprises either (a) contacting the molecular sieve with a solution containing ammonium ions at a temperature of at least about 50° C. to ammonium-exchange at least part of the occluded potassium ions or (b) contacting the molecular sieve with steam at a temperature of at least about 300° C. and then subjecting the steamed molecular sieve to ammonium exchange.
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公开(公告)号:US10011780B2
公开(公告)日:2018-07-03
申请号:US15582825
申请日:2017-05-01
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Lei Zhang , Kiara M. Benitez , Himanshu Gupta , Darryl D. Lacy , Scott J. Weigel , Xiaochun Xu
IPC: C10G25/00
CPC classification number: C10G25/003 , C10G2300/202 , C10G2400/04
Abstract: Methods for reducing impurities and improving color in liquid hydrocarbon products (e.g., diesel fuel) are provided herein.
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公开(公告)号:US20220401922A1
公开(公告)日:2022-12-22
申请号:US17349986
申请日:2021-06-17
Applicant: ExxonMobil Research and Engineering Company
Inventor: Scott J. Weigel , Megan E. Witzke , Wesley Sattler , Brandon M. Carcuffe , Jihad M. Dakka , Ryan S. Dugan
Abstract: Tungstated zirconium catalysts for paraffin isomerization may comprise: a mixed metal oxide that is at least partially crystalline and comprises tungsten, zirconium, and a variable oxidation state metal selected from Fe, Mn, Co, Cu, Ce, Ni, and any combination thereof. The mixed metal oxide comprises about 5 wt. % to about 25 wt. % tungsten, about 40 wt. % to about 70 wt. % zirconium, and about 0.01 wt. % to about 5 wt. % variable oxidation state metal, each based on a total mass of the mixed metal oxide. The mixed metal oxide has a total surface area of about 50 m2/g or greater as measured according to ISO 9277, and at least one of the following: an ammonia uptake of about 0.05 to about 0.3 mmol/g as measured by temperature programmed adsorption/desorption, or a collidine uptake of about 100 μmol/g or greater as measured gravimetrically.
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公开(公告)号:US10717069B2
公开(公告)日:2020-07-21
申请号:US15831594
申请日:2017-12-05
Applicant: ExxonMobil Research and Engineering Company
Inventor: Brian M. Weiss , Gerardo J. Majano , Tilman W. Beutel , Karl G. Strohmaier , John F. Brody , Samia Ilias , Scott J. Weigel , Shamel Merchant , Eugine Choi , Robert J. Colby , Walter Weissman
IPC: B01J23/46 , F02M26/35 , C10L3/08 , C01B3/40 , B01J23/08 , B01J23/06 , B01J23/60 , B01J29/70 , B01J29/85 , B01J23/10 , B01J29/74 , B01J35/00 , C10G63/08 , B01J29/78 , C10G47/20 , B01J37/28 , B01J29/46 , B01J37/04 , B01J29/48 , C10G47/14 , C10G2/00 , B01J29/76 , B01J29/44 , C10G47/04 , C10G47/18 , B01J29/80 , C10G35/09 , C10G35/095 , B01J23/00 , B01J37/08 , B01J23/63 , B01J37/03 , B01J37/02 , B01J23/62 , B01D53/92
Abstract: Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.
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公开(公告)号:US20200061593A1
公开(公告)日:2020-02-27
申请号:US16545464
申请日:2019-08-20
Applicant: ExxonMobil Research and Engineering Company
Inventor: Preeti Kamakoti , Scott J. Weigel , Karl G. Strohmaier , Helge Jaensch , Marc H. Anthonis , Martine Dictus , Brita Engels , Darryl D. Lacy , Sina Sartipi , Brandon J. O'Neill
Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
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公开(公告)号:US10195600B2
公开(公告)日:2019-02-05
申请号:US15179032
申请日:2016-06-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Paul Podsiadlo , Quanchang Li , David C. Calabro , Kiara M. Benitez , Machteld M. W. Mertens , Scott J. Weigel , Doron Levin , Randall D. Partridge
IPC: B01J31/26 , B01J29/70 , B01J31/12 , B01J35/00 , B01J37/00 , C10G45/54 , C10G45/64 , C10G47/16 , B01J29/40 , B01J29/44 , B01J29/74 , C07C5/10
Abstract: Catalysts including at least one microporous material (e.g., zeolite), an organosilica material binder, and at least one catalyst metal are provided herein. Methods of making the catalysts, preferably without surfactants and processes of using the catalysts, e.g., for aromatic hydrogenation, are also provided herein.
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公开(公告)号:US20180161139A1
公开(公告)日:2018-06-14
申请号:US15882353
申请日:2018-01-29
Applicant: ExxonMobil Research and Engineering Company
Inventor: Allen W. Burton , Karl G. Strohmaier , Scott J. Weigel
CPC classification number: A61F2/0045 , A61B17/0482 , A61B17/06109 , A61B17/3403 , A61B17/3468 , A61B2017/00805 , A61B2017/320056 , B01D53/04 , B01D53/75 , B01D53/86 , B01D53/864 , B01D53/927 , B01D53/9486 , B01D2253/10 , B01D2253/1085 , B01D2253/112 , B01D2253/116 , B01D2257/702 , B01J29/0308 , B01J29/70 , B01J37/10 , B01J37/30 , B01J2229/186 , B01J2229/24 , B01J2229/36 , B01J2229/38 , C01B39/026 , C01B39/04 , C01B39/48 , F01N3/0807 , F01N3/0814 , F01N3/0835 , Y02T10/22
Abstract: A method for reducing the level of occluded alkali metal cations from an MSE-framework type molecular sieve comprises either (a) contacting the molecular sieve with a solution containing ammonium ions at a temperature of at least about 50° C. to ammonium-exchange at least part of the occluded potassium ions or (b) contacting the molecular sieve with steam at a temperature of at least about 300° C. and then subjecting the steamed molecular sieve to ammonium exchange.
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公开(公告)号:US20210300842A1
公开(公告)日:2021-09-30
申请号:US17177081
申请日:2021-02-16
Applicant: ExxonMobil Research and Engineering Company
Inventor: Brandon J. O'Neill , Joe M. Falkowski , Allen W. Burton , Scott J. Weigel , Randall J. Meyer , Ajit B. Dandekar
Abstract: Zeolitic and molecular organic framework materials as catalysts suitable for generating branched olefins from linear olefins, thereby increasing the octane of a composition comprising the linear olefins. In particular, catalyst may exhibit selectivity for methyl-shift isomerization over cracking, alkylation, and oligomerization.
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公开(公告)号:US10995286B2
公开(公告)日:2021-05-04
申请号:US16709205
申请日:2019-12-10
Applicant: ExxonMobil Research and Engineering Company
Inventor: Joseph E. Gatt , William W. Lonergan , Scott J. Weigel , Ivy D. Johnson , Karl G. Strohmaier , Simon C. Weston
Abstract: In a process for improving the cold flow properties of a hydrocarbon feedstock, the feedstock is contacted with a catalyst composition comprising an EMM-17 molecular sieve and a hydrogenation component under dewaxing conditions effective to produce a dewaxed product having a cloud point and/or pour point that is reduced relative to the cloud point and/or pour point of the feedstock by at least 5° C.
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