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公开(公告)号:US20060217263A1
公开(公告)日:2006-09-28
申请号:US11371000
申请日:2006-03-09
申请人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Hisaya Kawabata , Masahiko Shigetsu , Masaaki Akamine , Akihide Takami
发明人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Hisaya Kawabata , Masahiko Shigetsu , Masaaki Akamine , Akihide Takami
IPC分类号: B01J23/10
CPC分类号: B01J35/0006 , B01D53/945 , B01J23/04 , B01J23/10 , B01J23/63 , B01J37/0244 , B01J37/0248 , Y02T10/22
摘要: In an exhaust gas purification catalyst in which a catalytic coating containing plural kinds of aluminas and plural kinds of oxygen storage components each carrying a catalytic precious metal is coated on a honeycomb support, the catalytic coating is formed of an upper layer and a lower layer, palladium is carried on a first alumina and a Ce—Zr—La—Y-alumina compound having oxygen storage capacity in the lower layer, platinum is carried on a second alumina in the upper layer, and rhodium is carried on a third alumina and a Ce—Zr—Nd mixed oxide having oxygen storage capacity in the upper layer.
摘要翻译: 在其中将含有多种氧化铝的催化剂涂层和各种携带催化贵金属的多种储氧组分涂覆在蜂窝状载体上的废气净化催化剂中,催化涂层由上层和下层形成, 钯在第一氧化铝和具有储氧能力的Ce-Zr-La-Y-氧化铝化合物的下层中承载,铂在上层被承载在第二氧化铝上,铑承载在第三氧化铝上, 在上层具有储氧能力的Ce-Zr-Nd混合氧化物。
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公开(公告)号:US20070265160A1
公开(公告)日:2007-11-15
申请号:US11785461
申请日:2007-04-18
IPC分类号: B01J23/10
CPC分类号: B01D53/945 , B01D2255/1025 , B01D2255/206 , B01D2255/20715 , B01J23/10 , B01J23/464 , B01J23/63 , B01J37/0242 , B01J37/03 , F01N3/0864 , F01N3/103 , F01N3/2828 , F01N2510/06 , Y02T10/22
摘要: A catalyst component of Rh carried on a ZrLa mixed oxide coated on activated alumina particles and a catalyst component of Rh carried on an oxygen storage component coexist in a catalytic coating on a support.
摘要翻译: 负载在活性氧化铝颗粒上的ZrLa混合氧化物上的Rh的催化剂组分和携带在储氧组分上的Rh的催化剂组分共存于载体上的催化涂层中。
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公开(公告)号:US20070179054A1
公开(公告)日:2007-08-02
申请号:US11669998
申请日:2007-02-01
IPC分类号: B01D53/94
CPC分类号: B01J23/63 , B01D53/945 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01D2255/908 , B01J23/002 , B01J23/10 , B01J37/03 , B01J2523/00 , C01G25/006 , Y02T10/22 , B01J2523/36 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/31
摘要: A catalytic matter comprises alumina particles. A compound oxide is loaded on surfaces of the alumina particles. The compound oxide contains cerium, zirconium, and lanthanum, but not aluminum. A catalytic metal is loaded on the surfaces of the alumina particles. The catalytic matter may be manufactured by preparing a first acidic solution containing aluminum, adding a first basic solution to the first acidic solution, thereby obtaining a second basic solution and precipitating a first hydroxide in the second basic solution, preparing a second acidic solution containing cerium, zirconium and lanthanum, adding the second acidic solution to the first hydroxide, thereby precipitating a second hydroxide on the first hydroxide, drying the first and second hydroxides to obtain an oxide matter, and loading a catalytic metal on the oxide matter. By loading the compound oxide containing cerium as an oxygen storage material on the alumina particle surfaces, the amount of the oxygen storage material on the surfaces of alumina particles may be increased, and the catalytic metal may loaded on or in the proximity of the oxygen storage material. Therefore, the catalytic metal may be supplied with sufficient amount of active oxygen to purify the exhaust gas.
摘要翻译: 催化剂物质包括氧化铝颗粒。 复合氧化物负载在氧化铝颗粒的表面上。 复合氧化物含有铈,锆和镧,但不包括铝。 催化金属负载在氧化铝颗粒的表面上。 催化剂可以通过制备含有铝的第一酸性溶液,向第一酸性溶液中加入第一碱性溶液,从而获得第二碱性溶液并在第二碱性溶液中沉淀第一氢氧化物,制备含有铈的第二酸性溶液 ,锆和镧,将第二酸性溶液加入到第一氢氧化物中,由此在第一氢氧化物上沉淀第二氢氧化物,干燥第一和第二氢氧化物以获得氧化物,并将催化金属负载在氧化物上。 通过将含有铈作为储氧材料的复合氧化物负载在氧化铝颗粒表面上,可以增加氧化铝颗粒表面上的储氧材料的量,并且催化金属可以装载在氧储存器上或其附近 材料。 因此,催化金属可以被供给足量的活性氧来净化废气。
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公开(公告)号:US07235511B2
公开(公告)日:2007-06-26
申请号:US10933808
申请日:2004-09-03
申请人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Masahiko Shigetsu , Masaaki Akamine , Hisaya Kawabata , Hideharu Iwakuni , Akihide Takami
发明人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Masahiko Shigetsu , Masaaki Akamine , Hisaya Kawabata , Hideharu Iwakuni , Akihide Takami
CPC分类号: B01D53/945 , B01D2255/102 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01J23/464 , B01J23/63 , B01J37/0215 , B01J37/0244 , B01J37/0248 , Y02C20/10 , Y02T10/22
摘要: An exhaust gas purifying catalyst includes a carrier and a catalyst layer provided on the carrier. The catalyst layer includes active Al2O3 on which a noble metal is carried, an oxygen storage agent on which Rh is carried, Al2O3 coated with ZrO2 on which Rh is carried, and a binder material.
摘要翻译: 废气净化催化剂包括载体和设置在载体上的催化剂层。 催化剂层包括其上载有贵金属的活性Al 2 O 3 N 3,携带有Rh的储氧剂,Al 2 O 3, 在其上携带有Rh的ZrO 2 N 2上涂覆的O 3和粘合剂材料。
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公开(公告)号:US20050070428A1
公开(公告)日:2005-03-31
申请号:US10933808
申请日:2004-09-03
申请人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Masahiko Shigetsu , Masaaki Akamine , Hisaya Kawabata , Hideharu Iwakuni , Akihide Takami
发明人: Tomohiko Kawamoto , Katsuyuki Fujita , Tadashi Tokuyama , Masahiko Shigetsu , Masaaki Akamine , Hisaya Kawabata , Hideharu Iwakuni , Akihide Takami
IPC分类号: F01N3/10 , B01D53/94 , B01J23/46 , B01J23/56 , B01J23/58 , B01J23/63 , B01J37/02 , B01J37/04 , F01N3/28
CPC分类号: B01D53/945 , B01D2255/102 , B01D2255/206 , B01D2255/20715 , B01D2255/2092 , B01J23/464 , B01J23/63 , B01J37/0215 , B01J37/0244 , B01J37/0248 , Y02C20/10 , Y02T10/22
摘要: An exhaust gas purifying catalyst includes a carrier and a catalyst layer provided on the carrier. The catalyst layer includes active Al2O3 on which a noble metal is carried, an oxygen storage agent on which Rh is carried, Al2O3 coated with ZrO2 on which Rh is carried, and a binder material.
摘要翻译: 废气净化催化剂包括载体和设置在载体上的催化剂层。 催化剂层包括载有贵金属的活性Al 2 O 3,载有Rh的储氧剂,携带有Rh的ZrO 2涂覆的Al 2 O 3和粘合剂材料。
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公开(公告)号:US08912116B2
公开(公告)日:2014-12-16
申请号:US12846486
申请日:2010-07-29
申请人: Masaaki Akamine , Hideharu Iwakuni , Hisaya Kawabata , Yasuhiro Ochi , Yuki Murakami , Susumu Mineoi , Akihide Takami , Masahiko Shigetsu
发明人: Masaaki Akamine , Hideharu Iwakuni , Hisaya Kawabata , Yasuhiro Ochi , Yuki Murakami , Susumu Mineoi , Akihide Takami , Masahiko Shigetsu
IPC分类号: B01J23/10 , B01D53/94 , B01J23/00 , B01J37/00 , B01J23/63 , B01J35/02 , B01J37/02 , B01J35/00
CPC分类号: B01J23/63 , B01D53/945 , B01D2255/1025 , B01D2255/2061 , B01D2255/2068 , B01D2255/407 , B01D2255/9022 , B01D2255/9202 , B01D2258/014 , B01J23/002 , B01J35/0006 , B01J35/0013 , B01J35/002 , B01J35/023 , B01J37/0036 , B01J37/0244 , B01J37/0248 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/3725 , B01J2523/48 , B01J2523/822 , B01J2523/31 , B01J2523/3706
摘要: A catalyst layer includes: a first mixed oxide particle component 4 which contains Ce and Rh 8 and in which Rh is partially exposed at particle surfaces; and a second mixed oxide particle component 5 containing Ce, Zr, and a rare earth metal except Ce. The particle size distribution of the first mixed oxide particle component 4 has a peak in the particle size range from 100 nm to 300 nm, both inclusive. The particle size distribution of the second mixed oxide particle component 5 has a peak in a particle size range larger than the particle size range in which the first mixed oxide particle component 4 has the peak. At least part of particles of the first mixed oxide particle component 4 is attached to at least part of particles of the second mixed oxide particle component 5.
摘要翻译: 催化剂层包括:含有Ce和Rh 8的第一混合氧化物颗粒组分4,其中Rh在颗粒表面部分暴露; 以及含有Ce,Zr和Ce以外的稀土金属的第二混合氧化物粒子成分5。 第一混合氧化物粒子成分4的粒径分布在100nm〜300nm的粒径范围内具有峰值。 第二混合氧化物粒子成分5的粒径分布具有比第一混合氧化物粒子成分4具有峰值的粒径范围大的粒度范围的峰。 第一混合氧化物颗粒组分4的至少部分颗粒附着到第二混合氧化物颗粒组分5的至少一部分颗粒。
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公开(公告)号:US09415383B2
公开(公告)日:2016-08-16
申请号:US13115876
申请日:2011-05-25
申请人: Masaaki Akamine , Masahiko Shigetsu
发明人: Masaaki Akamine , Masahiko Shigetsu
IPC分类号: B01J23/10 , B01J35/00 , B01D53/94 , B01J23/46 , B01J23/63 , B01J35/02 , B01J37/03 , B01J21/06 , B01J21/04
CPC分类号: B01J35/0006 , B01D53/945 , B01D2255/1025 , B01D2255/2063 , B01D2255/2068 , B01D2255/20715 , B01D2255/2092 , B01D2255/407 , B01D2255/908 , B01D2255/9202 , B01D2258/012 , B01J21/04 , B01J21/066 , B01J23/464 , B01J23/63 , B01J35/023 , B01J37/038 , Y02T10/22
摘要: An exhaust gas purification catalyst includes a catalytic layer on a carrier, in which a particle component A and a particle component B are mixed. The particle component A is composed of catalytic-metal-doped CeZr-based mixed oxide powder, and has a particle size distribution with a peak in a particle size range of equal to or greater than 100 nm and equal to or less than 300 nm. A CeO2/(CeO2+ZrO2) mass ratio of CeZr-based mixed oxide is equal to or greater than 30% and equal to or less than 75%. The particle component B is composed of at least one selected from a group consisting of activated alumina powder, Zr-based-oxide-supported alumina powder, and catalytic-metal-undoped CeZr-based mixed oxide powder. At least a part of particles of the particle component B has a particle size larger than that of the particle component A.
摘要翻译: 废气净化催化剂包括载体上的催化剂层,其中颗粒组分A和颗粒组分B被混合。 颗粒组分A由催化金属掺杂的CeZr基混合氧化物粉末组成,并且具有在等于或大于100nm且等于或小于300nm的粒度范围内的峰值的粒度分布。 CeZr基混合氧化物的CeO 2 /(CeO 2 + ZrO 2)质量比等于或大于30%且等于或小于75%。 颗粒组分B由选自活性氧化铝粉末,Zr-氧化物负载的氧化铝粉末和催化金属未掺杂的CeZr基混合氧化物粉末中的至少一种组成。 颗粒组分B的颗粒的至少一部分具有比颗粒组分A的颗粒大的粒径。
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公开(公告)号:US08932982B2
公开(公告)日:2015-01-13
申请号:US13115890
申请日:2011-05-25
CPC分类号: B01J35/0006 , B01D53/9422 , B01D53/944 , B01D53/945 , B01D2255/20715 , B01D2255/2092 , B01D2255/407 , B01D2258/012 , B01D2258/014 , B01J23/63 , B01J35/023 , B01J37/0215 , B01J37/031 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/3725 , B01J2523/48
摘要: An exhaust gas purification catalyst includes a catalytic layer containing a particle component A-1 and a particle component A-2 with different catalytic metal contents, each of which is composed of catalytic-metal-doped CeZr-based mixed oxide powder. The particle component A-1 having the lower catalytic metal content is supported on a particle component B composed of Zr-based-oxide-supported alumina powder, and the particle component A-2 having the higher catalytic metal content is supported on a particle component C composed of CeZr-based mixed oxide powder in which catalytic metal is not solid-dissolved.
摘要翻译: 废气净化催化剂包括含有不同催化金属含量的颗粒组分A-1和颗粒组分A-2的催化层,每个催化剂层由催化金属掺杂的CeZr基混合氧化物粉末组成。 将具有较低催化金属含量的颗粒组分A-1负载在由Zr-氧化物负载的氧化铝粉末组成的颗粒组分B上,并且具有较高催化金属含量的颗粒组分A-2负载在颗粒组分 C由CeZr系混合氧化物粉末组成,其中催化金属不固溶。
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公开(公告)号:US08211824B2
公开(公告)日:2012-07-03
申请号:US13024095
申请日:2011-02-09
申请人: Masaaki Akamine , Masahiko Shigetsu
发明人: Masaaki Akamine , Masahiko Shigetsu
CPC分类号: B01D53/945 , B01D2255/1021 , B01D2255/1023 , B01D2255/1025 , B01D2255/206 , B01D2255/2061 , B01D2255/2063 , B01D2255/2065 , B01D2255/2068 , B01D2255/20715 , B01D2255/2092 , B01D2255/902 , B01D2255/9022 , B01D2255/908 , B01D2255/92 , B01J23/63 , B01J35/0006 , B01J35/0073 , B01J35/04 , B01J37/0244 , B01J37/0248 , B01J37/031 , B01J2523/00 , Y02T10/22 , B01J2523/3712 , B01J2523/3725 , B01J2523/48 , B01J2523/31 , B01J2523/3706
摘要: A catalytic metal 5 is supported on oxide particles 4, 6 in a first catalyst layer 2, and first binder particles 7 which are fine, and have oxygen ion conductivity are interposed among the oxide particles. A catalytic metal 11 is supported on oxide particles 8, 9, 12 in a second catalyst layer 3 provided on or above the first catalyst layer 2, and second binder particles 13 which are fine, and are capable of storing and releasing oxygen are interposed among the oxide particles.
摘要翻译: 催化金属5负载在第一催化剂层2中的氧化物颗粒4,6上,并且氧化物颗粒之间插入有细的氧离子传导性的第一粘结剂颗粒7。 在设置在第一催化剂层2上或第二催化剂层2上的第二催化剂层3中,催化金属11负载在氧化物颗粒8,9,12上,并且能够容纳和释放氧的第二粘合剂颗粒13介于 氧化物颗粒。
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公开(公告)号:US08713921B2
公开(公告)日:2014-05-06
申请号:US13353263
申请日:2012-01-18
申请人: Masaaki Akamine , Masahiko Shigetsu
发明人: Masaaki Akamine , Masahiko Shigetsu
IPC分类号: F01N3/10
CPC分类号: B01D53/9468 , B01D53/945 , B01D53/9472 , B01D2255/1025 , B01D2255/2063 , B01D2255/40 , B01D2255/407 , B01D2255/908 , B01J23/63 , B01J35/023 , B01J35/04 , B01J37/031 , B01J2523/00 , F01N13/009 , Y02T10/22 , B01J2523/3706 , B01J2523/3725 , B01J2523/48 , B01J2523/24 , B01J2523/31
摘要: An upper catalyst layer of an upstream catalyst 3 and a downstream catalyst 5 includes an oxygen storage/release material in/on which a catalytic metal is included or loaded. The content of the oxygen storage/release material per 1 L of a substrate in the catalyst layer of the upstream catalyst 3 is larger than that in the catalyst layer of the downstream catalyst 5. The oxygen release amount per a unit amount of the Rh is larger than that for the upper catalyst layer of the upstream catalyst 5. At least part of the oxygen storage/release material included in the downstream catalyst shows a particle size distribution having a peak particle size smaller than that in the upstream catalyst 5.
摘要翻译: 上游催化剂3和下游催化剂5的上催化剂层包括在其中包含催化金属或加载催化金属的储氧/释放材料。 上游催化剂3的催化剂层中每1L基板的氧气储存/释放材料的含量大于下游催化剂5的催化剂层的含量。每单位量的Rh的氧释放量为 大于上游催化剂5的上部催化剂层。下游催化剂中包含的至少一部分储氧/释放材料表现出具有比上游催化剂5中的峰值粒度小的粒度分布。
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