摘要:
The present invention relates to a hybrid prepreg having reinforcing carbon fibers and foreign fibers. The carbon fibers have a diameter ranging from 5-30 microns and are unidirectionally arranged. The foreign fibers are composed either of single monofilaments having a diameter ranging from between about 50-150 microns or of strands formed by bundling together a plurality of single monofilaments having a diameter ranging from between about 5-50 microns. If strands are employed, they have a conversion diameter (D.sub.0) which is less than about 500 microns. The conversion diameter (D.sub.0) is represented by the following equation: ##EQU1## wherein n is the number of monofilaments used in forming the strand, and wherein d is the diameter of these monofilaments. Examples of foreign fibers which can be used when practicing this invention include boron fibers, metal fibers and organic fibers. These foreign fibers are spaced at fixed intervals, arranged in the same direction as the direction of the reinforcing carbon fibers, and positioned approximately at or near the center of the resulting prepreg. The prepreg prepared in accordance with the present invention also includes a thermosetting matrix resin in which the reinforcing carbon fibers and the foreign fibers are impregnated.
摘要:
The present invention relates to a hybrid prepreg having reinforcing carbon fibers and foreign fibers. The carbon fibers have a diameter ranging from 5-30 microns and are unidirectionally arranged. The foreign fibers are composed either of single monofilaments having a diameter ranging from between about 50-150 microns or of strands formed by bundling together a plurality of single monofilaments having a diameter ranging from between about 5-50 microns. If strands are employed, they have a conversion diameter (D.sub.0) which is less than about 500 microns. The conversion diameter (D.sub.0) is represented by the following equation: ##EQU1## wherein n is the number of monofilaments used in forming the strand, and wherein d is the diameter of these monofilaments. Examples of foreign fibers which can be used when practicing this invention include boron fibers, metal fibers and organic fibers. These foreign fibers are spaced at fixed intervals, arranged in the same direction as the direction of the reinforcing carbon fibers, and positioned approximately at or near the center of the resulting prepreg. The prepreg prepared in accordance with the present invention also includes a thermosetting matrix resin in which the reinforcing carbon fibers and the foreign fibers are impregnated.
摘要:
A hybrid laminated prepreg is disclosed, which comprises a resin layer, a decorative layer laminated thereon and having a pattern, and a transparent prepreg layer laminated on the decorative layer. In manufacturing a fiber reinforced composite resin material molding, the hybrid prepreg is laminated in a couple of layers on the outermost one of laminated layers of usual prepreg. Thus, it is possible to easily decorate the obtainable molding to readily provide an aesthetic sense to the appearance of the molding and also dispense with time-consuming operation of coating or the like. Further, unlike the coating or the like, it is possible to stably hold the aesthetic sense of the appearance for long time. The hybrid laminated prepreg can be suitably used for fiber reinforced composite resin material moldings, for instance such sport articles as golf club shafts, tennis rackets, ski pole shafts and fishing rods, fancy articles, briefcases such as attache cases, pipes such as bicycle frames and panels such as fair-faced wall panels.
摘要:
This invention relates to fiber-reinforced composite resin pultrusion products of circular and noncircular cross-sectional contours, manufactured by impregnating fiber tows or rovings with a resin, drawing them into a die, and forming them into an article of predetermined size and shape, and then curing it, and relates also to a method for manufacturing the same.
摘要:
An epoxy resin composition useful as a matrix for fiber-reinforced composites is disclosed which includes a mixture containing 30-95% by weight of a tetrafunctional epoxy resin, 3-40% by weight of an admixture of trifunctional epoxy resin oligomers and 2-50% by weight of a bisphenol A epoxy resin having a number average molecular weight of 450-1,300 and such a weight average molecular weight as to provide a ratio of the weight average molecular weight to the number average molecular weight of 1.3-3.0.
摘要:
A new thermosetting resin composition is disclosed which comprises a Bisphenol A-type epoxy resin having a number average molecular weight of smaller than 650 but not smaller than 450 and a ratio of the weight average molecular weight thereof to the number average molecular weight thereof of in the range of 1.3-3.0; and a curing agent capable of cross-linking the epoxy resin. The curing agent is preferably a compound represented by the following general formula: ##STR1## wherein X is --CR.sub.1 R.sub.2 --, --CO--, --COO--, --SO.sub.2 --, --SO--, --S--, --O--, --NR.sub.1 --, --SiR.sub.1 R.sub.2 -- or --POR.sub.1 -- where R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4, or a mixture thereof with a primary amine, a phenolic compound or an acid anhydride.
摘要翻译:公开了一种新的热固性树脂组合物,其包含数均分子量小于650但不小于450的双酚A型环氧树脂,其重均分子量与其数均分子量的比例 范围1.3-3.0; 和能够交联环氧树脂的固化剂。 固化剂优选为由以下通式表示的化合物:其中X为-CR 1 R 2 - , - CO - , - COO - , - SO 2 - , - SO - , - S - , - O - , - NR 1 - ,-SiR1R2-或-POR1-,其中R1和R2各自表示氢,低级烷基或苯基; Y和Y'各自代表氢,低级烷基或吸电子基团; R是低级烷基; m和n各自为1-4的整数,或其与伯胺,酚类化合物或酸酐的混合物。
摘要:
A new thermocurable composition is disclosed which comprises a Bisphenol A-type epoxy resin having a number average molecular weight of 650-1300, 10-40% by weight of the Bisphenol A-type epoxy resin having an epoxy equivalent of 180-195; and a curing agent capable of cross-linking the epoxy resin. The curing agent is preferably a compound represented by the following general formula: ##STR1## wherein X is --CR.sub.1 R.sub.2 --, --CO--, --COO--, --SO.sub.2 --, --SO--, --S--, --O--, --NR.sub.1 --, --SiR.sub.1 R.sub.2 -- or --POR.sub.1 -- where R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attractive group; R is a lower alkyl; and m and n each is an integer of 1-4, or a mixture thereof with a primary amine, a phenolic compound or an acid anhydride.
摘要翻译:公开了一种新的耐热组合物,其包含数均分子量为650-1300的双酚A型环氧树脂,10-40重量%的环氧当量为180-195的双酚A型环氧树脂; 和能够交联环氧树脂的固化剂。 固化剂优选为由以下通式表示的化合物:其中X为-CR 1 R 2 - , - CO - , - COO - , - SO 2 - , - SO - , - S - , - O - , - NR 1 - ,-SiR1R2-或-POR1-,其中R1和R2各自表示氢,低级烷基或苯基; Y和Y'各自代表氢,低级烷基或吸电子基团; R是低级烷基; m和n各自为1-4的整数,或其与伯胺,酚类化合物或酸酐的混合物。
摘要:
A two component-type curing agent composition is disclosed which comprises a first curing agent which is capable of cross-linking an epoxy resin and which is at least one member selected from primary amines, phenolic compounds and acid anhydrides, and a second curing agent which is at least one compounds represented by the following general formula: ##STR1## wherein X is --CR.sub.1 R.sub.2 --, --CO--, --COO--, --SO.sub.2 --, --SO--, --S--, --O--, --NR.sub.1 --, --SiR.sub.1 R.sub.2 -- or --POR.sub.1 -- where R.sub.1 and R.sub.2 each stands for hydrogen, a lower alkyl or a phenyl; Y and Y' each stands for hydrogen, a lower alkyl or an electron attracting group; R is a lower alkyl; and m and n each is an integer of 1-4.
摘要:
A reinforcing fiber sheet is provided which includes a support sheet and reinforcing fibers. The fibers are arranged in one direction on at least one surface of the support sheet and attached thereto through an adhesive layer. There is also provided a method of reinforcing a structure, which includes arranging bundles of the reinforcing fibers in one direction on at least one surface of a support sheet in parallel apart from each other or close to each other, wherein the surface of the support sheet is coated with an adhesive layer. Thereafter, pressing the bundles against the support sheet such that the reinforcing fibers are adhered through the adhesive layer to the support sheet in one direction in a slightly unfastened state to thereby produce the reinforcing fiber sheet.
摘要:
A reinforcing fiber sheet is provided which includes a support sheet and reinforcing fibers. The fibers are arranged in one direction on at least one surface of the support sheet and attached thereto through an adhesive layer. There is also provided a method of reinforcing a structure, which includes impregnating reinforcing fibers of the fiber sheets with a room temperature-settable resin, attaching the resin-impregnated fiber sheets to a surface of the structure, and thereafter setting the room temperature-settable resin.