公开(公告)号：US08865938B2

公开(公告)日：2014-10-21

申请号：US13877595

申请日：2011-10-05

申请人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

发明人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

IPC分类号： C07C209/00 ,  C07C209/48 ,  C07C253/22

CPC分类号： C07C209/48 ,  C07C253/22 ,  C07C2601/14 ,  C07C255/46 ,  C07C211/18

摘要： A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.

摘要翻译： 制备双（氨基甲基）环己烷的方法包括核氢化步骤，其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物，所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸，邻苯二甲酸酯， 和邻苯二甲酸酰胺; 氰化步骤，用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物，从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤，从而产生双（氨基甲基）环己烷。 在氰化步骤中，使用金属氧化物作为催化剂，所得到的二氰基环己烷的金属含量为3000ppm以下。

公开(公告)号：US20130197270A1

公开(公告)日：2013-08-01

申请号：US13878090

申请日：2011-10-05

申请人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

发明人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

IPC分类号： C07C209/48

CPC分类号： C07C209/48 ,  B01J23/44 ,  B01J25/00 ,  B01J25/02 ,  C07B2200/09 ,  C07C253/22 ,  C07C253/34 ,  C07C2601/14 ,  C07C255/46 ,  C07C211/18

摘要： A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane.Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.

摘要翻译： 反式-1,4-双（氨基甲基）环己烷的制造方法包括通过对苯二甲酸或对苯二甲酸衍生物的核氢化制造氢化对苯二甲酸或对苯二甲酸衍生物的核氢化工序，对苯二甲酸或对苯二甲酸衍生物为 选自对苯二甲酸，对苯二甲酸酯和对苯二甲酸酰胺中的至少一种; 用氨处理氢化对苯二甲酸或对苯二甲酸衍生物的氰化步骤，从而得到1,4-二氰基环己烷，由所得的1,4-二氰基环己烷生产反式-1,4-二氰基环己烷; 和用氢处理反式-1,4-二氰基环己烷的氨基甲基化步骤，从而产生反式-1,4-双（氨基甲基）环己烷。 在氰化步骤中使用金属氧化物作为催化剂，得到的反式-1,4-二氰基环己烷的金属含量为3000ppm以下。

公开(公告)号：US08865939B2

公开(公告)日：2014-10-21

申请号：US13878090

申请日：2011-10-05

申请人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

发明人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

IPC分类号： C07C209/00 ,  C07C253/34 ,  C07C209/48 ,  C07C253/22 ,  B01J23/44 ,  B01J25/00 ,  B01J25/02

CPC分类号： C07C209/48 ,  B01J23/44 ,  B01J25/00 ,  B01J25/02 ,  C07B2200/09 ,  C07C253/22 ,  C07C253/34 ,  C07C2601/14 ,  C07C255/46 ,  C07C211/18

摘要： A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trans-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane. Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.

摘要翻译： 反式-1,4-双（氨基甲基）环己烷的制造方法包括通过对苯二甲酸或对苯二甲酸衍生物的核氢化制造氢化对苯二甲酸或对苯二甲酸衍生物的核氢化工序，对苯二甲酸或对苯二甲酸衍生物为 选自对苯二甲酸，对苯二甲酸酯和对苯二甲酸酰胺中的至少一种; 用氨处理氢化对苯二甲酸或对苯二甲酸衍生物的氰化步骤，从而得到1,4-二氰基环己烷，由所得1,4-二氰基环己烷生产反式-1,4-二氰基环己烷; 和用氢处理反式-1,4-二氰基环己烷的氨基甲基化步骤，从而产生反式-1,4-双（氨基甲基）环己烷。 在氰化步骤中使用金属氧化物作为催化剂，得到的反式-1,4-二氰基环己烷的金属含量为3000ppm以下。

公开(公告)号：US20130197269A1

公开(公告)日：2013-08-01

申请号：US13877595

申请日：2011-10-05

申请人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

发明人： Naritoshi Yoshimura ,  Shinji Kiyono ,  Tetsuya Hamada ,  Eiji Watanabe ,  Saiko Sawada

IPC分类号： C07C209/48

CPC分类号： C07C209/48 ,  C07C253/22 ,  C07C2601/14 ,  C07C255/46 ,  C07C211/18

摘要： A method for producing bis(aminomethyl)cyclohexanes includes a nuclear hydrogenation step of producing hydrogenated phthalic acids or phthalic acid derivatives by nuclear hydrogenation of phthalic acids or phthalic acid derivatives of at least one selected from the group consisting of phthalic acids, phthalic acid esters, and phthalic acid amides; a cyanation step of treating the hydrogenated phthalic acids or phthalic acid derivatives obtained in the nuclear hydrogenation step with ammonia, thereby producing dicyanocyclohexanes; and an aminomethylation step of treating the dicyanocyclohexanes obtained in the cyanation step with hydrogen, thereby producing bis(aminomethyl)cyclohexanes. In the cyanation step, metal oxide is used as a catalyst, and the obtained dicyanocyclohexanes have a metal content of 3000 ppm or less.

摘要翻译： 制备双（氨基甲基）环己烷的方法包括核氢化步骤，其通过邻苯二甲酸或邻苯二甲酸衍生物的核氢化制备氢化邻苯二甲酸或邻苯二甲酸衍生物，所述邻苯二甲酸或邻苯二甲酸衍生物选自邻苯二甲酸，邻苯二甲酸酯， 和邻苯二甲酸酰胺; 氰化步骤，用氨处理在核氢化步骤中得到的氢化邻苯二甲酸或邻苯二甲酸衍生物，从而产生二氰基环己烷; 和在氰化步骤中用氢处理二氰基环己烷的氨基甲基化步骤，从而产生双（氨基甲基）环己烷。 在氰化步骤中，使用金属氧化物作为催化剂，所得到的二氰基环己烷的金属含量为3000ppm以下。

公开(公告)号：US08420522B2

公开(公告)日：2013-04-16

申请号：US12213819

申请日：2008-06-25

申请人： Masamitsu Ikumo ,  Hiroyuki Yoda ,  Eiji Watanabe

发明人： Masamitsu Ikumo ,  Hiroyuki Yoda ,  Eiji Watanabe

IPC分类号： H01L21/44

CPC分类号： H01L24/12 ,  H01L23/3171 ,  H01L24/11 ,  H01L24/16 ,  H01L2224/0381 ,  H01L2224/03912 ,  H01L2224/0401 ,  H01L2224/05124 ,  H01L2224/05147 ,  H01L2224/05166 ,  H01L2224/1132 ,  H01L2224/114 ,  H01L2224/1147 ,  H01L2224/116 ,  H01L2224/131 ,  H01L2224/73253 ,  H01L2224/83102 ,  H01L2224/92125 ,  H01L2924/00013 ,  H01L2924/01005 ,  H01L2924/01006 ,  H01L2924/01013 ,  H01L2924/01015 ,  H01L2924/01018 ,  H01L2924/01022 ,  H01L2924/01029 ,  H01L2924/01033 ,  H01L2924/01047 ,  H01L2924/01074 ,  H01L2924/01078 ,  H01L2924/01082 ,  H01L2924/014 ,  H01L2924/12044 ,  H01L2924/19041 ,  H01L2924/19043 ,  H01L2924/19105 ,  H01L2224/13099 ,  H01L2924/00014

摘要： A semiconductor device includes a plurality of electrode layers provided at designated positions of a semiconductor substrate, an organic insulation film formed on the semiconductor substrate by selectively exposing designated areas of the electrode layers, and projection electrodes for outside connection, the projection electrodes being formed on the designated areas of the electrode layers. Thickness of the organic insulation film situated in the vicinity of the periphery of the projection electrodes is greater than thickness of the organic insulation film situated between the projection electrodes.

摘要翻译： 半导体器件包括设置在半导体衬底的指定位置处的多个电极层，通过选择性地暴露电极层的指定区域和用于外部连接的突出电极而形成在半导体衬底上的有机绝缘膜，所述突起电极形成在 电极层的指定区域。 位于突出电极周围附近的有机绝缘膜的厚度大于位于突出电极之间的有机绝缘膜的厚度。

公开(公告)号：US20120006298A1

公开(公告)日：2012-01-12

申请号：US13256347

申请日：2010-03-24

申请人： Eiji Watanabe

发明人： Eiji Watanabe

IPC分类号： F02M55/02 ,  B21D19/00 ,  B21D53/84

CPC分类号： F02M55/005 ,  F16L19/0286 ,  Y10T29/49231

摘要： To provide a high-pressure fuel injection pipe preventing like a generation crack of a pocket portion during formation of a connection head portion, and being robust against fatigue, wherein the connection head portion is configured such that cylindrical face has contours in a section along the axial direction of the pipe from an end portion of a fillet portion of an annular flange portion toward the seat face formed such that an opening angle θ to an axis of the pipe in the section in the axial direction of the pipe satisfies 0°

摘要翻译： 为了提供一种高压燃料喷射管，其在形成连接头部分期间防止凹陷部分的产生裂纹，并且抵抗疲劳是鲁棒的，其中连接头部分被构造成使得圆柱形表面沿着沿着 从环形凸缘部分的圆角部分的端部朝向座面的管的轴向方向形成为开口角度; 在管的轴向截面中的管的轴线满足0°<＆amp;＆nbsp;＆nlE; 20°，并且圆柱面在管的轴向方向上的长度h与从长度H的比例 连接头部的端部到圆筒部侧的圆筒面的端部满足0.33＆nlE; h / H＆nlE; 0.85。

公开(公告)号：US07915538B2

公开(公告)日：2011-03-29

申请号：US12021548

申请日：2008-01-29

申请人： Masamitsu Ikumo ,  Tadahiro Okamoto ,  Eiji Watanabe

发明人： Masamitsu Ikumo ,  Tadahiro Okamoto ,  Eiji Watanabe

IPC分类号： H05K1/03

CPC分类号： H01L23/5385 ,  H01L21/481 ,  H01L21/4857 ,  H01L21/6835 ,  H01L23/13 ,  H01L2224/16 ,  H01L2224/16235 ,  H01L2924/00011 ,  H01L2924/00014 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/15311 ,  H05K3/0052 ,  H05K3/007 ,  H05K3/20 ,  H05K3/28 ,  H05K3/4682 ,  H05K2201/0187 ,  H05K2201/09036 ,  H05K2201/09518 ,  H05K2203/016 ,  Y10T29/49126 ,  Y10T428/24802 ,  Y10T428/24917 ,  H01L2224/0401

摘要： A multilayer wiring board having a plurality of wiring boards in which wiring layers and resin layers in each wiring board are alternately arranged in a laminated formation. In the multilayer wiring board, all the resin layers and the wiring layers, except a resin layer in the plurality of wiring boards, are separated in a same position between the plurality of wiring boards and the resin layer is continuous in the same position.

摘要翻译： 具有多个配线基板的多层布线基板，其中布线层和每个布线板中的树脂层交替地布置在层叠结构中。 在多层布线基板中，除了多个布线基板中的树脂层以外的所有树脂层和布线层在多个布线基板之间的相同位置分离，并且树脂层在相同位置连续。

公开(公告)号：US20100019782A1

公开(公告)日：2010-01-28

申请号：US11916947

申请日：2006-06-28

申请人： Eiji Watanabe ,  Akira Higuchi ,  Masaya Nakatani

发明人： Eiji Watanabe ,  Akira Higuchi ,  Masaya Nakatani

IPC分类号： G01R27/08

CPC分类号： G01N33/48728

摘要： The present invention provides a cellular potential measurement container that can measure a cellular potential with high accuracy while suppressing noise even when the number of the cells to be subjected to the measurement is increased. The cellular potential measurement container includes a first solution reservoir 14, a second solution reservoir 15, a partition substrate 18, a first electrode 27a, a second electrode 27b, a first measurement terminal 13a, and a second measurement terminal 13b. The first solution reservoir 14 and the second solution reservoir 15 are partitioned with the partition substrate 18, and the partition substrate 18 has a through hole 19. A first end of the through hole 19 is open toward the first solution reservoir 14 while a second end of the through hole 19 is open toward the second solution reservoir 15. The opening at the first end of the through hole 19 can hold a cell. The first electrode 27a is arranged so that a first solution can come into contact with the first electrode, and the second electrode 27b is arranged so that a second solution can come into contact with the second electrode. In the cellular potential measurement container with the above configuration, an electric signal amplifying device 16 further is provided, and the first measurement terminal 13a or the second measurement terminal 13b is connected to the first electrode 27a or the second electrode 27b via this electric signal amplifying device 16.

摘要翻译： 本发明提供一种细胞电位测量容器，即使在要进行测量的细胞数量增加的同时，也可以以高精度测量细胞电位，同时抑制噪声。 细胞电位测量容器包括第一溶液储存器14，第二溶液储存器15，分隔基板18，第一电极27a，第二电极27b，第一测量端子13a和第二测量端子13b。 第一溶液储存器14和第二溶液储存器15被分隔基板18分隔开，分隔基板18具有通孔19.通孔19的第一端向第一溶液储存器14开口，而第二端 通孔19朝向第二溶液储存器15开口。通孔19的第一端处的开口可以容纳电池。 第一电极27a被布置成使得第一溶液可以与第一电极接触，并且第二电极27b被布置成使得第二溶液可以与第二电极接触。 在具有上述结构的细胞电位测量容器中，还设置有电信号放大装置16，并且第一测量端子13a或第二测量端子13b经由该电信号放大与第一电极27a或第二电极27b连接 设备16。

公开(公告)号：US20080131813A1

公开(公告)日：2008-06-05

申请号：US11979466

申请日：2007-11-02

申请人： Tomohiro Etou ,  Eiji Watanabe ,  Ryouta Mineo

发明人： Tomohiro Etou ,  Eiji Watanabe ,  Ryouta Mineo

IPC分类号： G03F7/004 ,  C08F24/00

CPC分类号： G03F7/0233 ,  C08F216/36 ,  C08F220/18 ,  C08F220/32

摘要： The invention provides an alkali soluble polymer including a specific vinylketone phenol and a derivative thereof as radical polymerizable monomers and a positive working photosensitive resin composition containing the alkali soluble polymer and a photosensitizing agent. According to the invention, there can be provided an alkali soluble resin having high solvent resistance, high water resistance, high acid resistance, high alkali resistance, high thermal resistance, high transparency, excellent adhesiveness with a substrate, and the like and useful for the formation of a patterned resin film obtained by developing in an aqueous alkali solution and a positive working photosensitive resin composition including such an alkali soluble resin.

摘要翻译： 本发明提供一种包含特定乙烯基酮苯酚及其衍生物作为可自由基聚合单体的碱溶性聚合物和含有碱溶性聚合物和光敏剂的正性感光性树脂组合物。 根据本发明，可以提供耐溶剂性高，耐水性高，耐酸性高，耐碱性高，耐热性高，透明性高，与基材粘合性优异的碱溶性树脂等， 形成通过在碱性水溶液中显影获得的图案化树脂膜和包含这种碱溶性树脂的正性感光性树脂组合物。

公开(公告)号：US20060219429A1

公开(公告)日：2006-10-05

申请号：US11180780

申请日：2005-07-14

申请人： Masamitsu Ikumo ,  Tadahiro Okamoto ,  Eiji Watanabe

发明人： Masamitsu Ikumo ,  Tadahiro Okamoto ,  Eiji Watanabe

IPC分类号： H05K1/03 ,  H05K3/36

CPC分类号： H01L23/5385 ,  H01L21/481 ,  H01L21/4857 ,  H01L21/6835 ,  H01L23/13 ,  H01L2224/16 ,  H01L2224/16235 ,  H01L2924/00011 ,  H01L2924/00014 ,  H01L2924/01078 ,  H01L2924/01079 ,  H01L2924/15311 ,  H05K3/0052 ,  H05K3/007 ,  H05K3/20 ,  H05K3/28 ,  H05K3/4682 ,  H05K2201/0187 ,  H05K2201/09036 ,  H05K2201/09518 ,  H05K2203/016 ,  Y10T29/49126 ,  Y10T428/24802 ,  Y10T428/24917 ,  H01L2224/0401

摘要： A multilayer wiring board comprises a plurality of wiring boards in which wiring layers and resin layers in each wiring board are alternately arranged in a laminated formation. In the multilayer wiring board, all the resin layers and the wiring layers, except a resin layer in the plurality of wiring boards, are separated in a same position between the plurality of wiring boards and the resin layer is continuous in the same position.

摘要翻译： 多层布线板包括多个布线板，其中布线层和每个布线板中的树脂层以叠层形式交替布置。 在多层布线基板中，除了多个布线基板中的树脂层以外的所有树脂层和布线层在多个布线基板之间的相同位置分离，并且树脂层在相同位置连续。