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公开(公告)号：US4533500A
公开(公告)日：1985-08-06
申请号：US476295
申请日：1983-03-17
IPC分类号： C07C233/46 , C09F5/00 , C09F7/00 , C11C3/00
CPC分类号： C07C233/46
摘要： N-acyliminodiacetic acids are manufactured by reacting formaldehyde or a formaldehyde generator compound with a N-unsubstituted amide or a generator thereof and with carbon monoxide in contact with a carbonylation catalyst, for example, a cobalt compound, the ratio of the aldehyde groups to the amide groups being at least 2:1. The formaldehyde generator can be a polymeric form of formaldehyde and the amide generator can be a carboxylic ester, acid or anhydride.
摘要翻译： N-酰基亚氨基二乙酸是通过使甲醛或甲醛发生剂化合物与N-未取代的酰胺或其发生剂和与羰基化催化剂例如钴化合物接触的一氧化碳反应制备的，醛基与 酰胺基团为至少2:1。 甲醛发生器可以是甲醛的聚合形式，酰胺发生剂可以是羧酸酯，酸或酸酐。
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公开(公告)号：US4264515A
公开(公告)日：1981-04-28
申请号：US103774
申请日：1979-12-14
IPC分类号： C07C233/45 , C07C102/00
CPC分类号： C07C233/45
摘要： A N-acyl .alpha.-amino acid is manufactured by reacting an unsaturated vegetable oil or a C.sub.8 -C.sub.30 mono-olefinic compound with an amide, carbon monoxide and hydrogen, in the presence of a cobalt catalyst. The process is operated in one step, providing for an increased selectivity as compared with a two-step process.
摘要翻译： 通过使不饱和植物油或C 8 -C 30单烯烃化合物与酰胺，一氧化碳和氢气在钴催化剂存在下反应制备N-酰基α-氨基酸。 该方法在一个步骤中操作，与两步法相比提供了增加的选择性。
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3.发明授权Non-aqueous liquid composition with an ionic character and its use as a solvent 失效非水性液体组合物，具有离子性，并作为溶剂使用
公开(公告)号：US5104840A
公开(公告)日：1992-04-14
申请号：US672236
申请日：1991-03-20
申请人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
发明人： Yves Chauvin , Dominique Commereuc , Isabelle Guibard , Andre Hirschauer , Helene Olivier , Lucien Saussine
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/24 , B01J31/28 , C07B61/00 , C07C2/32 , C07C11/02 , C07C15/12 , C07F5/06 , C08F10/00
CPC分类号： B01J31/24 , B01J31/0284 , B01J31/0288 , B01J31/1805 , C07F5/06 , C07F5/064 , C08F10/00 , B01J2231/20 , B01J2531/847 , B01J31/0239 , B01J31/0268 , B01J31/2234
摘要： A non-aqueous liquid composition with an ionic character resulting from the contacting of at least one alkylaluminum dihalide with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, said composition being liquid below 80.degree. C., for example, between -70.degree. and +40.degree. C., is useful as a solvent of catalysts for the dimerization, codimerization and oligomerization of olefins.
摘要翻译： 由至少一种烷基铝二卤化物与至少一种季铵卤化物和/或至少一种季鏻卤化物接触而产生的具有离子性质的非水性液体组合物，所述组合物在低于80℃的液体下，例如， 在-70℃至+ 40℃之间，可用作烯烃二聚，共聚和低聚的催化剂溶剂。
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4.发明授权
公开(公告)号：US5750455A
公开(公告)日：1998-05-12
申请号：US547205
申请日：1995-10-24
申请人： Yves Chauvin , Andre Hirschauer , Helene Olivier
发明人： Yves Chauvin , Andre Hirschauer , Helene Olivier
IPC分类号： B01J31/22 , B01J27/122 , B01J31/02 , B01J31/30 , C07B61/00 , C07C2/60 , C07C9/16 , B01J31/00 , B01J23/70 , C07C2/58
CPC分类号： C07C2/60 , B01J27/122 , B01J31/0284 , B01J31/26 , B01J31/30 , B01J2231/321 , C07C2527/08 , C07C2527/10 , C07C2527/122 , C07C2527/125 , C07C2531/02 , C07C2531/26
摘要： The invention concerns a catalytic composition resulting from mixing at least one aluminum halide, at least one quaternary ammonium halide and/or at least one amine halohydrate and at least one cuprous compound, preferable a halide. The invention also concerns a process for the alkylation of isoparaffins by olefins with that composition.
摘要翻译： 本发明涉及通过混合至少一种卤化铝，至少一种季铵卤化物和/或至少一种胺卤化水合物和至少一种亚铜化合物，优选卤化物而得到的催化组合物。 本发明还涉及用该组合物用烯烃烷基化异链烷烃的方法。
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5.发明授权公开(公告)号：US06677268B2
公开(公告)日：2004-01-13
申请号：US10193705
申请日：2002-07-12
申请人： Gerhard Hillebrand , Andre Hirschauer , Dominique Commereuc , Helene Olivier-Bourbigou , Lucien Saussine
发明人： Gerhard Hillebrand , Andre Hirschauer , Dominique Commereuc , Helene Olivier-Bourbigou , Lucien Saussine
IPC分类号： B01J3100
摘要： An improved catalyst based on cobalt and/or rhodium dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion.
摘要翻译： 一种基于溶解在低于90℃温度下为液体的非水离子溶剂中的钴和/或铑的改进的催化剂。更具体地，催化剂包含至少一种钴和/或铑配合物 与至少一种含氮配体和非水离子溶剂包含至少一种季铵和/或鏻阳离子和至少一种无机阴离子。
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6.发明授权Aliphatic alkylation catalyst comprising an active phase containing a cuprous compound on a support 失效脂肪族烷基化催化剂包含在载体上含有亚铜化合物的活性相
公开(公告)号：US5693585A
公开(公告)日：1997-12-02
申请号：US664538
申请日：1996-06-17
申请人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
发明人： Eric Benazzi , Yves Chauvin , Andre Hirschauer , Nathalie Ferrer , Helene Olivier , Jean-Yves Bernhard
IPC分类号： B01J21/08 , B01J27/125 , B01J31/02 , B01J31/26 , B01J31/28 , B01J32/00 , B01J35/02 , B01J35/10 , C07B61/00 , C07C2/58 , C07C2/60 , C07C9/16 , B01J27/122 , B01J27/25 , B01J31/00
CPC分类号： C07C2/60 , B01J31/0294 , B01J31/26 , B01J31/28 , B01J31/30 , B01J21/08 , B01J2231/323 , B01J35/023 , B01J35/1019 , B01J35/1047 , C07C2521/08 , C07C2527/053 , C07C2527/122 , C07C2527/125 , C07C2527/126 , C07C2527/24 , C07C2531/02 , C07C2531/04 , Y02P20/584
摘要： A catalyst containing a porous organic or mineral support and at least one active phase having at least one aluminum halide, at least one compound selected for quaternary ammonium halides and amine hydrohalides, and at least one cuprous compound, the support having been impregnated with the active phase, the catalyst essentially constituted by particles with an average diameter in the range 0.1 .mu.m to 150 .mu.m, and the support, before impregnation with the active phase, has a total pore volume in the range 0.1 cm.sup.3 /g and 6 cm.sup.3 /g.
摘要翻译： 含有多孔有机或矿物载体和至少一种具有至少一种卤化铝，至少一种选自季铵卤化物和胺氢卤化物的化合物和至少一种亚铜化合物的活性相的催化剂，该载体已经浸渍有活性 相，催化剂基本上由平均直径在0.1μm至150μm的颗粒构成，并且在用活性相浸渍之前，载体的总孔体积在0.1cm 3 / g和6cm 3 / G。
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公开(公告)号：US4038295A
公开(公告)日：1977-07-26
申请号：US545189
申请日：1975-01-29
申请人： Robert Stern , Eugene Ucciani , Andre Hirschauer , Georges Cecchi
发明人： Robert Stern , Eugene Ucciani , Andre Hirschauer , Georges Cecchi
CPC分类号： C11C3/12
摘要： Highly unsaturated oils of vegetable or animal origin are selectively hydenated to less highly unsaturated oils using a catalytic composition obtained by dissolving a compound of a metal selected from the IB, IV B to VII B or VIII groups in an unsaturated oil and then adding thereto an organic derivative or hydride of a metal from groups I A, II A, II B or III A, in the absence of a stabilizing solvent.
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公开(公告)号：US5892124A
公开(公告)日：1999-04-06
申请号：US999390
申请日：1997-12-29
申请人： Helene Olivier , Andre Hirschauer
发明人： Helene Olivier , Andre Hirschauer
IPC分类号： C07B37/12 , C07C45/69 , C07C49/623
摘要： Improved process for implementing the Diels-Alder reaction that consists in using reagents in the presence of at least one liquid salt of general formula Q.sup.+ A.sup.-, in which Q.sup.+ represents a quaternary ammonium and/or phosphonium and A.sup.- represents an anion and optionally at least one Lewis acid. The anion is preferably selected from the group that is formed by tetrafluoroborate, hexafluorophosphate, hexafluoroantimonate, hexafluoroarsenate, perfluoroalkylsulfonate, fluorosulfonate or else dichlorocuprate, tetrachloroborate, tetrachloroaluminate, and trichlorozincate. At the end of the reaction, the organic phase is separated, and the polar phase is reused.
摘要翻译： 改进的实施Diels-Alder反应的方法，其包括在存在至少一种通式Q + A-的液体盐的情况下使用试剂，其中Q +代表季铵和/或鏻，A-代表阴离子和任选的 至少一种路易斯酸。 阴离子优选选自由四氟硼酸盐，六氟磷酸盐，六氟锑酸盐，六氟砷酸盐，全氟烷基磺酸盐，氟代磺酸盐或二氯磷酸盐，四氯硼酸盐，四氯铝酸盐和三氯酸锌形成的基团。 在反应结束时，将有机相分离，极性相重复使用。
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公开(公告)号：US6028024A
公开(公告)日：2000-02-22
申请号：US55886
申请日：1998-04-07
CPC分类号： B01J31/26 , B01J27/125 , B01J31/0239 , B01J31/0284 , B01J31/38 , C07C2/60 , C10G50/00 , B01J2231/323 , C07C2527/125 , C07C2527/126 , C07C2527/135 , C07C2531/02 , C07C2531/38
摘要： The invention concerns a catalytic composition resulting from a mixture of at least one aluminium halide, at least one quaternary ammonium halide and/or at least one amine hydrohalide and at least one group IVB metal compound, preferably a group IVB metal halide. The invention also concerns a process for alkylating isoparaffins by olefins using that composition, the olefin preferably being a low reactivity olefin.
摘要翻译： 本发明涉及由至少一种卤化铝，至少一种卤化铵和/或至少一种胺氢卤化物和至少一种IVB族金属化合物，优选IVB族金属卤化物的混合物产生的催化组合物。 本发明还涉及使用该组合物使烯烃烷基化异构烷烃的方法，烯烃优选为低活性烯烃。
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