公开(公告)号：US11857944B2

公开(公告)日：2024-01-02

申请号：US17315833

申请日：2021-05-10

Applicant: Northwestern University

Inventor： Mercouri G. Kanatzidis ,  Debajit Sarma ,  Emmanouil Manos

IPC: B01J20/22 ,  B01D53/02 ,  B01J41/08 ,  B01J20/32 ,  B01J41/12 ,  B01J41/05 ,  C08L5/04 ,  B01J47/018 ,  B01J47/02

CPC classification number: B01J20/226 ,  B01D53/02 ,  B01J20/3206 ,  B01J20/3208 ,  B01J20/3274 ,  B01J41/05 ,  B01J41/08 ,  B01J41/12 ,  C08L5/04 ,  B01D2253/204 ,  B01D2253/206 ,  B01J47/018 ,  B01J47/02

Abstract: Metal organic resins, composite materials composed of the metal organic resins, and anion exchange columns packed with the composite materials are provided. Also provided are methods of using the composite materials to remove metal anions from a sample, methods of using the metal organic resins as fluorescence sensors for detecting metal anions in a sample, and methods of making the metal organic resins and the composite materials. The metal organic resins are amine-functionalized metal organic frameworks and their associated counter anions. The composite materials are composed of metal organic resin particles coated with organic polymers, such as alginic acid polymers.

公开(公告)号：US09687840B2

公开(公告)日：2017-06-27

申请号：US14413772

申请日：2013-07-09

Applicant: THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE

Inventor： Douglas Gin ,  Trevor Carlisle ,  Richard Noble ,  Garret Nicodemus ,  William McDanel ,  Matthew Cowan

IPC: B01D53/22 ,  B01J39/18 ,  B01D67/00 ,  B01D71/64 ,  B01D71/34 ,  B01J41/08 ,  B01D69/12 ,  C08G59/26 ,  C08G59/50 ,  C08F12/26 ,  C08F12/32 ,  C08F112/14 ,  C08F112/32 ,  C08F8/30 ,  B01J39/19 ,  B01J41/09

CPC classification number: B01J39/19 ,  B01D53/228 ,  B01D67/0013 ,  B01D69/12 ,  B01D71/34 ,  B01D71/64 ,  B01D2053/221 ,  B01D2323/46 ,  B01J41/09 ,  C08F8/30 ,  C08F12/26 ,  C08F12/32 ,  C08F112/14 ,  C08F112/32 ,  C08G59/26 ,  C08G59/5006 ,  C08F12/18

Abstract: The invention includes compositions comprising curable imidazolium-functionalized poly(room-temperature ionic liquid) copolymers and homopolymers. The invention further includes methods of preparing and using the compositions of the invention. The invention further includes novel methods of preparing thin, supported, room-temperature ionic liquid-containing polymeric films on a porous support. In certain embodiments, the methods of the invention avoid the use of a gutter layer, which greatly reduces the overall gas permeance and selectivity of the composite membrane. In other embodiments, the films of the invention have increased gas selectivity and permeance over films prepared using methods described in the prior art.

公开(公告)号：US20160279628A1

公开(公告)日：2016-09-29

申请号：US14777954

申请日：2014-01-15

Applicant: SHIN-ETSU CHEMICAL CO., LTD.

Inventor： Masahiko ISHIDA ,  Hiroshi SAITO ,  Atsushi YOSHIDA

IPC: B01J41/04 ,  B01J49/00 ,  B01J41/08 ,  C01B33/107 ,  C01B33/04

CPC classification number: B01J49/57 ,  B01J41/07 ,  B01J41/09 ,  C01B33/046 ,  C01B33/1071 ,  C01B33/10778 ,  C01B33/10784

Abstract: The present invention provides a technique which allows stable use of an ion-exchange resin for removing boron impurities over a long period of time in the purification step of a silane compound or a chlorosilane compound. In the present invention, a weakly basic ion-exchange resin used for the purification of a silane compound and a chlorosilane compound is cleaned with a gas containing hydrogen chloride. When this cleaning treatment is used for the initial activation of the weakly basic ion-exchange resin, a higher impurity-adsorbing capacity can be obtained. Further, use of the cleaning treatment for the regeneration of the weakly basic ion-exchange resin allows stable use of the ion-exchange resin for a long time. This allows reduction in the amount of the resin used in a long-term operation and reduction in the cost of used resin disposal.

Abstract translation: 本发明提供了在硅烷化合物或氯代硅烷化合物的精制工序中，能够在长时间内稳定地使用离子交换树脂除去硼杂质的技术。 在本发明中，用含有氯化氢的气体清洗用于硅烷化合物和氯硅烷化合物的纯化的弱碱性离子交换树脂。 当这种清洁处理用于弱碱性离子交换树脂的初始活化时，可以获得更高的杂质吸附能力。 此外，使用清洁处理来进行弱碱性离子交换树脂的再生，可以长时间稳定地使用离子交换树脂。 这样可以减少长时间运行中使用的树脂的量和降低使用的树脂处理成本。

公开(公告)号：US20150259200A1

公开(公告)日：2015-09-17

申请号：US14726248

申请日：2015-05-29

Applicant: VTU Holding GmbH

Inventor： Roland Kalb

IPC: C01B3/08 ,  B01J41/08 ,  H01M8/06

CPC classification number: C01B3/08 ,  B01J41/09 ,  C01B3/001 ,  C01B3/065 ,  C01B6/23 ,  C07C211/63 ,  C07F9/5407 ,  H01M8/0606 ,  Y02E60/324 ,  Y02E60/327 ,  Y02E60/362

Abstract: A method releases hydrogen by forming a second ionic liquid from a first ionic liquid by releasing hydrogen from the first ionic liquid by exposing the second ionic liquid to water and a catalyst. The first ionic liquid includes a cation and an anion including a borohydride. The release of the hydrogen forms a borate, which makes up the anion of the second ionic liquid. The cation of the first ionic liquid is the same as that of the second ionic liquid. A reaction system includes the first and second ionic liquids, water and a catalyst.

Abstract translation: 一种方法是通过从第一离子液体形成第二离子液体来释放氢气，通过将第二离子液体暴露于水和催化剂中，从第一离子液体释放氢。 第一离子液体包括阳离子和包含硼氢化物的阴离子。 氢的释放形成硼酸盐，其构成第二离子液体的阴离子。 第一离子液体的阳离子与第二离子液体的阳离子相同。 反应体系包括第一和第二离子液体，水和催化剂。

公开(公告)号：US20150209776A1

公开(公告)日：2015-07-30

申请号：US14413772

申请日：2013-07-09

Applicant: THE REGENTS OF THE UNIVERSITY OF COLORADO, A BODY CORPORATE

Inventor： Douglas Gin ,  Trevor Carlisle ,  Richard Noble ,  Garret Nicodemus ,  William McDaniel ,  Matthew Cowan

IPC: B01J39/18 ,  B01D53/22 ,  B01D67/00 ,  B01D71/64 ,  B01D71/34 ,  B01J41/08 ,  B01D69/12

CPC classification number: B01J39/19 ,  B01D53/228 ,  B01D67/0013 ,  B01D69/12 ,  B01D71/34 ,  B01D71/64 ,  B01D2053/221 ,  B01D2323/46 ,  B01J41/09 ,  C08F8/30 ,  C08F12/26 ,  C08F12/32 ,  C08F112/14 ,  C08F112/32 ,  C08G59/26 ,  C08G59/5006 ,  C08F12/18

Abstract: The invention includes compositions comprising curable imidazolium-functionalized poly(room-temperature ionic liquid) copolymers and homopolymers. The invention further includes methods of preparing and using the compositions of the invention. The invention further includes novel methods of preparing thin, supported, room-temperature ionic liquid-containing polymeric films on a porous support. In certain embodiments, the methods of the invention avoid the use of a gutter layer, which greatly reduces the overall gas permeance and selectivity of the composite membrane. In other embodiments, the films of the invention have increased gas selectivity and permeance over films prepared using methods described in the prior art.

Abstract translation: 本发明包括包含可固化的咪唑官能化聚（室温离子液体）共聚物和均聚物的组合物。 本发明还包括制备和使用本发明组合物的方法。 本发明还包括在多孔载体上制备薄的，负载的室温离子液体聚合物膜的新方法。 在某些实施方案中，本发明的方法避免使用沟槽层，这大大降低了复合膜的整体气体渗透性和选择性。 在其它实施方案中，本发明的膜具有增加的气体选择性和渗透性，这是使用现有技术中描述的方法制备的薄膜。

公开(公告)号：US20100098607A1

公开(公告)日：2010-04-22

申请号：US12573934

申请日：2009-10-06

Applicant: Matthew J. Davis ,  Morris Lewellyn ,  Qi Dai ,  Haunn-Lin Tony Chen ,  Matthew Taylor

Inventor： Matthew J. Davis ,  Morris Lewellyn ,  Qi Dai ,  Haunn-Lin Tony Chen ,  Matthew Taylor

IPC: C01F7/02 ,  B01D21/01 ,  B01J41/08 ,  C08L83/00 ,  C08L43/04

CPC classification number: C01F7/0653 ,  C02F1/545 ,  C02F1/56 ,  C02F2103/10

Abstract: The suspended solids content of a process stream in a process for digesting bauxite ore to produce alumina is reduced by contacting the stream with silicon-containing polymers.

Abstract translation: 通过使流与含硅聚合物接触，在消化铝土矿以生产氧化铝的方法中的工艺流的悬浮固体含量被降低。

公开(公告)号：US20080164211A1

公开(公告)日：2008-07-10

申请号：US11792092

申请日：2005-11-18

Applicant: Wolfgang Lindner ,  Michael Maemmerhofer

Inventor： Wolfgang Lindner ,  Michael Maemmerhofer

IPC: B01J41/08 ,  B01J41/20 ,  B01J41/00

CPC classification number: B01J20/286 ,  B01J20/261 ,  B01J20/264 ,  B01J20/267 ,  B01J20/28042 ,  B01J20/287 ,  B01J20/288 ,  B01J20/289 ,  B01J20/3204 ,  B01J20/321 ,  B01J20/3217 ,  B01J20/3219 ,  B01J20/3227 ,  B01J20/3251 ,  B01J20/3255 ,  B01J20/3257 ,  B01J20/3259 ,  B01J20/3261 ,  B01J20/3263 ,  B01J20/3285 ,  B01J41/20 ,  B01J2220/54 ,  B01J2220/58 ,  B01J2220/82

Abstract: The present invention relates to mixed-modal anion-exchange materials composed of a support on which a ligand is immobilized. The ligand combines at least one basic domain based on cyclic monobasic derivatives with two or more rings as anion-exchange domain and at least one non-ionic binding domain. The basic domain is ionized under the conditions of use and may contain secondary, tertiary, or quaternary nitrogen forming a weakly (WAX) or strongly (SAX) basic anionic exchange domains. The non-ionic binding domain allows adjustment of the overall hydrophobicity/hydrophilicity of the material and represents a second binding site for the solute to be separated. Binding to this second binding site is based on reversed phase (RP), hydrophobic interaction (HIC) or hydrophilic interaction (HILIC). Linker sites, which can be represented by a chemical bond or by hydrophobic moieties like alkyl(ene) chains or hydrophilic moieties like amide structures connect the support to the binding domains and the binding domains to each other.

Abstract translation: 本发明涉及由其上固定有配体的载体组成的混合模式阴离子交换材料。 该配体将至少一个基于环状一元衍生物的碱性结构域与两个或多个环作为阴离子交换域和至少一个非离子结合结构域结合。 碱性结构域在使用条件下离子化，可能含有形成弱（WAX）或强（SAX）碱性阴离子交换域的二级，三级或四级氮。 非离子结合结构域允许调节材料的整体疏水性/亲水性，并表示待分离溶质的第二结合位点。 与第二结合位点的结合基于反相（RP），疏水相互作用（HIC）或亲水相互作用（HILIC）。 可以通过化学键表示的连接位点或通过疏水部分如烷基（烯）链或亲水部分如酰胺结构将支持物连接到结合域和结合结构域。

公开(公告)号：US5187200A

公开(公告)日：1993-02-16

申请号：US808884

申请日：1991-12-18

Applicant: Norman B. Rainer

Inventor： Norman B. Rainer

IPC: B01J41/08 ,  B01J45/00 ,  B01J47/00

CPC classification number: B01J47/006 ,  B01J41/085 ,  B01J45/00 ,  B01J47/007 ,  C08J2479/00

Abstract: A process for selectively removing anions from an aqueous solution involves contacting the solution for an effective period of time with a specialized polymer in a porous format. The polymer has ligand sites capable of forming coordination or complexation bonds with multi-valent metal cations which serve to activate the polymer with respect to chemical interaction with anions. The polymer, saturated with the multivalent metal cations, contains between 2% and 20% of metal cation based upon the dry weight of the polymer.

Abstract translation: 从水溶液中选择性地除去阴离子的方法包括使溶液与多孔形式的特殊聚合物接触有效的时间段。 该聚合物具有能够与多价金属阳离子形成配位或络合键的配体位点，其用于在与阴离子的化学相互作用下活化聚合物。 基于聚合物的干重，用多价金属阳离子饱和的聚合物含有2％至20％的金属阳离子。

公开(公告)号：US4780239A

公开(公告)日：1988-10-25

申请号：US866015

申请日：1986-05-22

Applicant: Thomas S. Snyder ,  Herbert A. Burgman ,  Martin D. Nahemow

Inventor： Thomas S. Snyder ,  Herbert A. Burgman ,  Martin D. Nahemow

IPC: G21F9/12 ,  B01J39/02 ,  B01J39/08 ,  B01J41/02 ,  B01J41/08 ,  B01J41/10 ,  G21F9/00 ,  G21F9/16 ,  G21F9/30 ,  C01B31/16 ,  C04B33/32 ,  G21F9/08

CPC classification number: B01J39/085 ,  B01J39/02 ,  B01J41/02 ,  B01J41/10

Abstract: Disclosed is a method of making an ion exchange material. A ceramic material is ion implanted with sulfur, carbon, phosphorus, or nitrogen, which is oxidized to sulfate, carboxylate or carbonate, phosphate, or nitrate, respectively, or the nitrogen is reduced to amine amide. Alternatively, a mixture of ceramic powder and a binder containing sulfur, carbon, phosphorus, or nitrogen is heated in a nonoxidizing atmosphere to a temperature up to 1000.degree. C. The sulfur is then oxidized to sulfate, the carbon to carboxylate or carbonate, phosphorus to phosphate, and nitrogen to nitrate, or the nitrogen is reduced to amine or amide. Also disclosed is an ion exchange material made by these methods and a method of treating acidic aqueous solutions containing dissolved radioactive materials by passing them through an ion exchange column containing the ion exchange material.

Abstract translation: 公开了一种制备离子交换材料的方法。 用硫，碳，磷或氮离子注入陶瓷材料，分别氧化成硫酸盐，羧酸盐或碳酸盐，磷酸盐或硝酸盐，或将氮还原成胺酰胺。 或者，将陶瓷粉末和含有硫，碳，磷或氮的粘合剂的混合物在非氧化气氛中加热至高达1000℃的温度。然后将硫氧化成硫酸盐，将碳氧化成硫酸盐，将碳氧化成碳酸盐或碳酸盐，磷 至磷酸盐，氮至硝酸盐，或将氮还原为胺或酰胺。 还公开了通过这些方法制备的离子交换材料和通过使含有溶解的放射性物质的酸性水溶液通过含有离子交换材料的离子交换柱的方法。

公开(公告)号：US4576969A

公开(公告)日：1986-03-18

申请号：US541646

申请日：1983-10-13

Applicant: Yoshiaki Echigo ,  Yoshiyuki Suematsu ,  Tadashi Ishikura

Inventor： Yoshiaki Echigo ,  Yoshiyuki Suematsu ,  Tadashi Ishikura

IPC: C08L61/00 ,  B01J39/08 ,  B01J39/16 ,  B01J39/18 ,  B01J41/08 ,  B01J41/12 ,  B01J43/00 ,  B01J45/00 ,  B01J47/00 ,  C02F1/28 ,  C02F1/42 ,  C08G8/00 ,  C08L61/04 ,  C08F8/10

CPC classification number: C02F1/288 ,  B01J39/165 ,  B01J39/185 ,  B01J41/12 ,  B01J47/007 ,  C02F1/42 ,  C02F2101/103

Abstract: A spherical ion exchange resin composed of a phenolic resin and a metal hydroxide is disclosed. The metal hydroxide is enclosed and bound with the phenolic resin. A method for producing such an ion exchange resin and a method for selectively adsorbing ions using the same is also disclosed. The ion exchange resin is capable of efficiently recovering ions contained or dissolved in water in trace amounts and, hence, can be applied to any aqueous solution containing ions. For example, it can be used to recover useful substances from sea water and to purify waste waters from nonferrous refineries and nuclear power plants.

Abstract translation: 公开了一种由酚醛树脂和金属氢氧化物组成的球形离子交换树脂。 金属氢氧化物被封闭并与酚醛树脂结合。 还公开了这种离子交换树脂的制造方法和使用该离子交换树脂选择性吸附离子的方法。 离子交换树脂能够有效地回收微量含有或溶解在水中的离子，因此可以应用于任何含有离子的水溶液。 例如，它可用于从海水中回收有用物质，并从有色炼油厂和核电厂净化废水。