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公开(公告)号：US20170096552A1
公开(公告)日：2017-04-06
申请号：US15282169
申请日：2016-09-30
发明人： Alberto Cláudio Habert , Cristiano Piacsek Borges , Cristina Cardoso Pereira , Maria Elizabeth Ferreira Garcia , Jane Hitomi Fujiyama-Novak , Rafael Aislan Amaral , Bárbara Iria Silva Mano , Vinicius Galhard Grassi , Rogério Massanori Sakahara , Marcelo Farah , Mariele Kaipers Stocker , Marcos Roberto Paulino Bueno
摘要： Polymer compositions may include a polymer matrix containing a polyolefin, one or more polymer particles dispersed in the polymer matrix, wherein the one or more polymer particles include a polar polymer selectively crosslinked with a crosslinking agent, and wherein the one or more polymer particles has an average particle size of up to 200 μm. Processes of preparing a polymer composition may include mixing a polyolefin, a polar polymer, and a crosslinking agent; and selectively crosslinking the polar polymer with the crosslinking agent in the presence of the polyolefin. Methods may include increasing stress cracking resistance of a polyolefin by mixing a polar polymer with the polyolefin; and selectively crosslinking the polar polymer in the presence of the polyolefin with a crosslinking agent to form crosslinked polar polymer particles dispersed in the polyolefin.
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公开(公告)号：US20160368833A1
公开(公告)日：2016-12-22
申请号：US15034367
申请日：2013-11-08
申请人： BRASKEM S.A.
CPC分类号： C07C1/24 , C07C5/2213 , C07C5/2506 , C07C6/04 , C07C2521/04 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2523/02 , C07C2523/06 , C07C2523/10 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2529/04 , C12P5/026 , C12P7/04 , C12P7/065 , C12P7/16 , Y02E50/10 , Y02E50/17 , C07C11/04 , C07C11/06 , C07C11/08
摘要： The present invention relates to a process for the production of propene from a mixture of alcohols obtained from at least one renewable source of carbon, comprising the following steps: (a) fermentation of at least one renewable source of carbon for the production of a mixture of alcohols comprising ethanol, isopropanol and 1-butanol; (b) simplified removal of the alcohols from the fermentative wort to generate an aqueous solution containing chiefly ethanol, isopropanol and 1-butanol; (c) joint dehydration of the alcohols to produce a mixture of olefins comprising chiefly ethene, propene and linear butenes, the linear butenes being a mixture of 1-butene and 2-butenes (cis and trans isomers), besides water and by-products, among which oxygenated compounds; (d) removal of water, oxygenated compounds and other by-products to generate a mixture of olefins comprising chiefly ethene, propene and linear butenes; and (f) passing the mixture of olefins through an isomerized bed, so that 1-butene will be isomerized to 2-butenes and, subsequently, passing the mixture of olefins comprising chiefly ethene, propene and 2-butenes through a metathesis bed, for reaction between ethene and 2-butenes, generating additional propene, the molar ratio ethene:linear butenes being corrected to be between 1:1 and 1.3:1, by means of one of the alternatives selected from the group comprising: (i) addition of a stream containing ethanol to the process in step (c); (ii) addition of a stream containing ethene to the process in step (e); (iii) addition of a stream containing ethanol to the process in step (c) and a stream containing ethene in step (e).
摘要翻译： 本发明涉及由从至少一种可再生碳源获得的醇的混合物生产丙烯的方法，其包括以下步骤：（a）至少一种可再生的碳源的发酵以产生混合物 包含乙醇，异丙醇和1-丁醇的醇; （b）从发酵麦汁中简化醇的去除以产生主要包含乙醇，异丙醇和1-丁醇的水溶液; （c）醇的联合脱水以产生主要包括乙烯，丙烯和线性丁烯的烯烃混合物，线性丁烯是1-丁烯和2-丁烯（顺式和反式异构体）的混合物，除了水和副产物 ，其中含氧化合物; （d）除去水，含氧化合物和其它副产物以产生主要包括乙烯，丙烯和线性丁烯的烯烃混合物; 和（f）将烯烃混合物通过异构化床，使得1-丁烯将异构化成2-丁烯，随后将主要包括乙烯，丙烯和2-丁烯的烯烃混合物通过复分解床，用于 乙烯和2-丁烯之间的反应，产生另外的丙烯，乙烯的摩尔比：线性丁烯被校正为1:1至1.3:1，通过选自以下的选择之一：（i）加入 将步骤（c）中的方法中含有乙醇的料流; （ii）向步骤（e）中的方法中加入含有乙烯的料流; （iii）向步骤（c）中的方法中加入含有乙醇的料流和在步骤（e）中含有乙烯的料流）。
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93.发明申请MODIFIED MICROORGANISMS AND METHODS OF CO-PRODUCING BUTADIENE WITH 1-PROPANOL AND/OR 1,2-PROPANEDIOL 审中-公开与1,2-丙醇和/或1,2-丙二醇共同生产丁二烯的改性微生物和方法公开(公告)号：US20150152440A1
公开(公告)日：2015-06-04
申请号：US14409292
申请日：2013-06-18
申请人： Braskem S.A.
发明人： Mateus Schreiner Garcez Lopes , Avram Michael Slovic , Paulo Luiz de Andrade Coutinho , Antonio Luiz Ribeiro De Castro Morschbacker
CPC分类号： C12P5/026 , C12N15/63 , C12P7/04 , C12P7/18 , C12P2203/00
摘要： The present disclosure generally relates to microorganisms that comprise one or more polynucleotides coding for enzymes in a pathway that catalyzes a conversion of a fermentable carbon source to butadiene and/or one or more polynucleotides coding for enzymes in a pathway that catalyzes a conversion of a fermentable carbon source to 1-propanol and/or 1,2-propanadiol. Also provided are methods of using the microorganisms to produce butadiene and co-products such 1-propanol and/or 1,2-propanediol.
摘要翻译： 本公开内容通常涉及包含一种或多种编码酶的多核苷酸的微生物，所述多核苷酸在催化可发酵碳源转化为丁二烯的途径中和/或一种或多种编码催化转化可发酵的途径中的酶的多核苷酸 碳源至1-丙醇和/或1,2-丙二醇。 还提供了使用微生物来生产丁二烯和副产物如1-丙醇和/或1,2-丙二醇的方法。
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94.发明公开公开(公告)号：US20240352162A1
公开(公告)日：2024-10-24
申请号：US18640514
申请日：2024-04-19
申请人： Braskem S.A.
发明人： Edmundo Ferreira Barros Filho , Fernando da Silva Gomes , Juliano Rosa Dos Santos Muller , Tahyná Barbalho Fontoura , Dihogenes Adriano Pozzer , Edwin Towsend
CPC分类号： C08F10/02 , B01J19/0013 , B01J2219/00076
摘要： Provided is a process for the polymerization of ethylene comprising introducing ethylene, a liquid light hydrocarbon diluent, at least one catalyst, at least one cocatalyst, and optionally one or more comonomers into a reactor; polymerizing the ethylene and optionally the one or more comonomers in the reactor to produce an ethylene polymer; wherein the reactor is fluidly connected to a cooling system, the cooling system comprising a slurry-free heat exchanger, and the cooling system is configured to receive a vapor stream comprising light hydrocarbon vapor produced in the reactor. Also provided is an ethylene polymer produced from the process for polymerizing ethylene and a system for producing an ethylene polymer.
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公开(公告)号：US20240317980A1
公开(公告)日：2024-09-26
申请号：US18592867
申请日：2024-03-01
申请人： Braskem S.A.
CPC分类号： C08L23/0853 , B29B7/005 , B29B7/007 , C08L23/06 , C08L23/12 , C08L2205/02 , C08L2207/04 , C08L2207/062
摘要： A polymer blend composition may include from 0.01 to 99.99 wt % of a thermoplastic resin matrix; and from 0.01 to 99.99 wt % of a dynamically crosslinked polymer. A thermoplastic vulcanizate composition may include from 0.01 to 99.99 phr of a thermoplastic resin; from 0.01 to 99.99 phr of a dynamically crosslinked polymer; from 0 to 150 phr of plasticizer; and from 0 to 600 phr of at least one filler.
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公开(公告)号：US20240309275A1
公开(公告)日：2024-09-19
申请号：US18605195
申请日：2024-03-14
申请人： BRASKEM S.A.
CPC分类号： C10G7/12 , B01D3/4205 , B01J8/0242 , C10G11/05 , C10G11/20 , B01J2208/027 , C10G2300/1003 , C10G2300/301 , C10G2300/4006 , C10G2300/4012 , C10G2300/4081 , C10G2300/70 , C10G2400/04
摘要： This invention relates to a process for recovering a liquid product from a pyrolysis stream. The process comprises preheating a pyrolysis stream comprising a mixture of hydrocarbons; distilling the preheated pyrolysis stream in a distillation column to produce one or more streams including a top stream at the top of the distillation column; cooling the top stream withdrawn from the distillation column in a condenser; refluxing the stream that has exited the condenser in a reflux vessel; and withdrawing at least part of a liquid product from the bottom of the reflux vessel to recover a liquid naphtha or naphtha-like product. The invention also relates to various recovered liquid products produced from the process described herein. The invention also relates to an apparatus for recovering liquid products from a pyrolysis stream, comprising a preheater; a distillation column that does not contain a reboiler; a condenser; and a reflux vessel.
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公开(公告)号：US20240209123A1
公开(公告)日：2024-06-27
申请号：US18296776
申请日：2023-04-06
申请人： Braskem S.A.
摘要： Described is a fluidic seal apparatus for continuously injecting a sealing gas into a bottom section of a gas-solids separation chamber. The fluidic seal apparatus includes an external section, a feed tube in fluid communication with a sealing gas supply, and an internal section. The external section connects the sealing gas supply to the internal section. The internal section includes gas distribution nozzles for distributing the sealing gas inside the bottom section of the gas-solids separation chamber. An internal chamber between the internal section and the external section is pressurized by the sealing gas.
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公开(公告)号：US12006526B2
公开(公告)日：2024-06-11
申请号：US16796417
申请日：2020-02-20
申请人： Braskem S.A.
CPC分类号： C12P7/18 , C12N1/20 , C12N15/52 , C12P5/026 , C12P7/28 , C12P17/02 , C12N1/205 , C12R2001/19 , C12Y101/01043 , C12Y101/01301 , C12Y102/01009 , C12Y203/01008 , C12Y207/01011 , C12Y207/02003 , C12Y301/01031 , C12Y401/02022 , C12Y501/03001 , C12Y503/01006 , C12Y504/02
摘要： The present application relates to recombinant microorganisms useful in the biosynthesis of monoethylene glycol (MEG), or optionally MEG and one or more co-product, from one or more hexose feedstock. The present application also relates to recombinant microorganisms useful in the biosynthesis of glycolic acid (GA), or optionally GA and one or more co-product, from one or more hexose feedstock. The present application relates to recombinant microorganisms useful in the biosynthesis of xylitol, or optionally xylitol and one or more co-product, from one or more hexose feedstock. Also provided are methods of producing MEG (or GA or xylitol), or optionally MEG (or GA or xylitol) and one or more co-product, from one or more hexose feedstock using the recombinant microorganisms, as well as compositions comprising the recombinant microorganisms and/or the products MEG (or GA or xylitol), or optionally MEG (or GA or xylitol) and one or more co-product.
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99.发明公开公开(公告)号：US20240124665A1
公开(公告)日：2024-04-18
申请号：US18374910
申请日：2023-09-29
申请人： Braskem S.A.
IPC分类号： C08J5/18 , B29C48/00 , B29C48/08 , B32B17/10 , B32B27/06 , B32B27/16 , B32B27/26 , B32B27/30 , B32B37/10 , C08L23/08
CPC分类号： C08J5/18 , B29C48/022 , B29C48/08 , B32B17/10678 , B32B17/10697 , B32B17/10788 , B32B27/06 , B32B27/16 , B32B27/26 , B32B27/30 , B32B37/1018 , C08L23/0853 , B29C2948/92152 , B32B2250/03 , B32B2305/72 , B32B2307/7376 , C08J2323/08 , C08L2203/204
摘要： Provided is a film comprising a polymer composition comprising a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate, with an ethylene content in an amount ranging from 40 to 99.9 wt %, and having a melt index (I2) from 0.1 to 100 g/10 min ASTM D1238 (190° C. and load of 2.16 kg). Also provided are a method of producing a film, an article comprising a film, a solar cell encapsulant comprising a film, a laminate comprising a film and a method of manufacturing an article.
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公开(公告)号：US20240092949A1
公开(公告)日：2024-03-21
申请号：US18241735
申请日：2023-09-01
申请人： Braskem S.A.
发明人： Normando José Castro de Jesus , Márcio Henrique dos Santos Andrade , Antonio Luiz Duarte Bragança , Priscila Martins Beck , Rita Cristina C. Marinho , Tahyná Barbalho Fontoura , Nathalia Oliveira Martins , Thiago Roberto Almeida , John Henry Percival Brooman
CPC分类号： C08F14/06 , B01J19/006 , B01J19/1831 , B01J2219/00777
摘要： A process for polymerization of vinyl chloride may include contacting vinyl chloride, demineralized water, at least one stabilizer agent, at least one dispersing agent, an initiator and optionally one or more comonomers; continuously feeding the vinyl chloride, demineralized water, at least one stabilizer agent, at least one dispersing agent, an initiator and optionally one or more comonomers into a tubular reactor having a length of at least 20 times an internal diameter of the tubular reactor; and continuously polymerizing the vinyl chloride, and optionally the one or more comonomers.
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