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公开(公告)号：US20160053035A1
公开(公告)日：2016-02-25
申请号：US14859638
申请日：2015-09-21
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F10/08 , C08F10/14 , C08F2500/05 , C08F2500/07 , C08F2500/12 , C08F4/65927 , C08F4/65904 , C08F4/65925 , C08F210/14 , C08F2500/17 , C08F2500/13
摘要： Disclosed herein are ethylene-based polymers having a higher molecular weight component and a lower molecular weight component, and characterized by a density greater than 0.945 g/cm3, a melt index less than 1.5 g/10 min, and a ratio of high load melt index to melt index ranging from 40 to 175. These polymers have the processability of chromium-based resins, but with improved stiffness and stress crack resistance, and can be used in blow molding and other end-use applications.
摘要翻译： 本文公开了具有较高分子量组分和较低分子量组分的乙烯基聚合物，其特征在于密度大于0.945g / cm 3，熔体指数小于1.5g / 10min，高负载熔体 熔体指数指数范围从40至175.这些聚合物具有铬基树脂的加工性，但具有改善的刚度和抗应力开裂性，并且可用于吹塑和其它终端应用。
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公开(公告)号：US20150322184A1
公开(公告)日：2015-11-12
申请号：US14278303
申请日：2014-05-15
IPC分类号： C08F210/14 , B65D81/34 , C08J5/18
CPC分类号： C08F210/14 , B65D81/34 , B65D2581/34 , C08F4/65912 , C08F4/65916 , C08J5/18 , C08J2323/08 , Y10T428/1352 , C08F210/16 , C08F2500/17 , C08F2500/26 , C08F2500/10 , C08F110/02 , C08F4/65927 , C08F4/65925
摘要： A metallocene-catalyzed polyethylene copolymer having a zero shear viscosity (ηo) of from about 1×102 Pa-s to about 5×103 Pa-s and a ratio of a z-average molecular weight to a number average molecular weight (Mz/Mn) of from about 4 to about 15, and when tested in accordance with ASTM F1249 displays a moisture vapor transmission rate of less than or equal to about 0.9 g-mil/100 in2/day. A metallocene-catalyzed polyethylene copolymer which when tested in accordance with ASTM F1249 has a moisture vapor transmission rate (MVTR) that is decreased by at least 5% when compared to an MVTR determined in accordance with ASTM F1249 of an otherwise similar metallocene-catalyzed polyethylene homopolymer.
摘要翻译： 具有约1×102Pa·s至约5×10 3 Pa·s的零剪切粘度（＆eegr o）的茂金属催化的聚乙烯共聚物和z-平均分子量与数均分子量的比（ Mz / Mn）为约4至约15，并且当根据ASTM F1249测试时，显示小于或等于约0.9g-mil / 100in2 /天的水蒸汽透过率。 茂金属催化的聚乙烯共聚物当根据ASTM F1249测试时具有与根据ASTM F1249测定的另一种类似的茂金属催化聚乙烯的MVTR相比降低至少5％的水蒸汽透过率（MVTR） 均聚物
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公开(公告)号：US20150175726A1
公开(公告)日：2015-06-25
申请号：US14639582
申请日：2015-03-05
发明人： Max P. McDaniel , Ashish M. Sukhadia , Errun Ding , Chung Ching Tso , Albert P. Masino , Qing Yang , Lloyd W. Guatney , Guylaine St. Jean , Daniel G. Hert
IPC分类号： C08F210/16 , C08J5/18
CPC分类号： C08F210/16 , C08F4/65916 , C08F4/65925 , C08F4/65927 , C08F210/14 , C08F2410/02 , C08F2500/05 , C08F2500/08 , C08F2500/09 , C08F2500/12 , C08J5/18 , C08J2323/08 , C08L23/0815 , C08L2205/02 , C08L2205/025 , C08L2314/06 , C08F4/65904 , C08F2500/04 , C08F2500/07 , C08F2500/26
摘要： Disclosed herein are broad molecular weight distribution olefin polymers having densities in the 0.895 to 0.930 g/cm3 range, and with improved impact and tear resistance. These polymers can have a ratio of Mw/Mn in the 8 to 35 range, a high load melt index in the 4 to 50 range, less than about 0.008 LCB per 1000 total carbon atoms, and a reverse comonomer distribution.
摘要翻译： 本文公开了具有在0.895至0.930g / cm 3范围内的密度并具有改善的耐冲击性和抗撕裂性的宽分子量分布烯烃聚合物。 这些聚合物可以具有8至35范围内的Mw / Mn比，4至50范围内的高负荷熔体指数，每1000个总碳原子小于约0.008LCB，反向共聚单体分布。
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94.发明授权High activity catalyst compositions containing silicon-bridged metallocenes with bulky substituents 有权含有硅桥连金属茂与高体积取代基的高活性催化剂组合物公开(公告)号：US08987392B2
公开(公告)日：2015-03-24
申请号：US13849595
申请日：2013-03-25
发明人： Joel L. Martin , Qing Yang , Max P. McDaniel , Jim B. Askew
CPC分类号： C08F4/76 , C07F17/00 , C08F4/65908 , C08F4/65912 , C08F4/65916 , Y10S526/943 , C08F210/16 , C08F4/65927 , C08F210/14
摘要： The present invention discloses catalyst compositions employing silicon-bridged metallocene compounds with bulky substituents. Methods for making these silicon-bridged metallocene compounds and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
摘要翻译： 本发明公开了使用具有庞大取代基的硅桥连金属茂化合物的催化剂组合物。 还提供了制备这些硅桥联金属茂化合物和在催化剂组合物中用于烯烃聚合的方法。
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95.发明授权Methods for controlling dual catalyst olefin polymerizations with an alcohol compound 有权用醇化合物控制双重催化烯烃聚合的方法公开(公告)号：US08957168B1
公开(公告)日：2015-02-17
申请号：US13962982
申请日：2013-08-09
发明人： Qing Yang , Max P. McDaniel , Tony R. Crain , Albert P. Masino , Ted H. Cymbaluk , John D. Stewart
IPC分类号： C08F4/649 , C08F4/642 , C08F4/653 , C08F4/6592 , C08F10/00 , C08F210/14
CPC分类号： C08F4/76 , C08F2/01 , C08F4/52 , C08F4/649 , C08F4/65904 , C08F4/65916 , C08F210/14 , C08F210/16 , C08F2410/01 , C08L23/0815 , Y10S526/943 , C08F4/65925 , C08F4/65927 , C08F2/38 , C08F2500/04 , C08F2500/05 , C08F2500/12
摘要： Methods for controlling properties of an olefin polymer using an alcohol compound are disclosed. The MI and the HLMI of the polymer can be decreased, and the Mw and the Mz of the polymer can be increased, via the addition of the alcohol compound.
摘要翻译： 公开了使用醇化合物控制烯烃聚合物性能的方法。 可以降低聚合物的MI和HLMI，并且可以通过加入醇化合物来增加聚合物的Mw和Mz。
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公开(公告)号：US08940844B2
公开(公告)日：2015-01-27
申请号：US13864306
申请日：2013-04-17
发明人： Qing Yang , Max P. McDaniel , Tony R. Crain , Kathy S. Collins
IPC分类号： C08F2/00 , C08F4/00 , C09K15/06 , C08F2/42 , C08F110/02
CPC分类号： C08F6/02 , C08F2/42 , C08F110/02 , C08F2400/02 , C09K15/06
摘要： Catalyst deactivating agents and compositions containing catalyst deactivating agents are disclosed. These catalyst deactivating agents can be used in methods of controlling polymerization reactions, methods of terminating polymerization reactions, methods of operating polymerization reactors, and methods of transitioning between catalyst systems.
摘要翻译： 公开了含有催化剂失活剂的催化剂失活剂和组合物。 这些催化剂失活剂可用于控制聚合反应的方法，终止聚合反应的方法，操作聚合反应器的方法和催化剂体系之间的转化方法。
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97.发明申请Catalyst System with Three Metallocenes for Producing Broad Molecular Weight Distribution Polymers 有权具有三种茂金属的催化剂体系用于生产广泛的分子量分布聚合物公开(公告)号：US20150005460A1
公开(公告)日：2015-01-01
申请号：US14485897
申请日：2014-09-15
发明人： Qing Yang , Max P. McDaniel , Tony R. Crain , Youlu Yu , Yongwoo Inn
IPC分类号： C08F210/16
CPC分类号： C08F110/02 , C08F4/65904 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F210/00 , C08F210/16 , C08L23/00 , C08L23/0815 , C08L2314/06 , Y10S526/943 , C08F2500/04 , C08F2500/12 , C08F2500/24 , C08F2500/05 , C08F210/14 , C08L23/06
摘要： Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes use a catalyst system containing three metallocene components, often resulting in polymers having a reverse comonomer distribution and a broad and non-bimodal molecular weight distribution.
摘要翻译： 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法使用含有三种茂金属组分的催化剂体系，其常常导致聚合物具有反向共聚单体分布和广泛的和非双峰分子量分布。
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98.发明授权Use of hydrogen and an organozinc compound for polymerization and polymer property control 有权氢和有机锌化合物用于聚合和聚合物性质控制公开(公告)号：US08829125B2
公开(公告)日：2014-09-09
申请号：US13927165
申请日：2013-06-26
发明人： Errun Ding , Qing Yang , Albert P. Masino , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
IPC分类号： C08F4/00 , C08F4/06 , C08F4/12 , C08F2/00 , C08F210/00 , C08F210/16 , C08F10/00 , C08F110/02
CPC分类号： C08F210/16 , C08F10/00 , C08F110/02 , C08F2400/02 , C08F2/00 , C08F2/42 , C08F2500/04 , C08F2500/12
摘要： Methods of controlling polymerization reactions using a synergistic amount of hydrogen and an organozinc compound are disclosed. The resulting polymers have lower molecular weights and higher melt flow indices.
摘要翻译： 公开了使用协同量的氢和有机锌化合物控制聚合反应的方法。 所得聚合物具有较低的分子量和较高的熔体流动指数。
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公开(公告)号：US20140114039A1
公开(公告)日：2014-04-24
申请号：US13655024
申请日：2012-10-18
CPC分类号： B01J4/02 , B01J4/008 , B01J14/00 , B01J19/06 , B01J19/123 , B01J19/127 , B01J19/1837 , B01J2204/002 , B01J2219/00094 , B01J2219/00164 , B01J2219/00182 , B01J2219/00186 , B01J2219/0801 , C08F4/00 , C08F110/02 , C08F2420/00 , C08F2500/05 , C08F2500/07 , C08F2500/08 , C08F210/16 , C08F210/14 , C08F10/00 , C08F2/01
摘要： Techniques are provided for catalyst preparation. A system for catalyst preparation may include an agitator disposed inside a polymerization catalyst tank and configured to mix a polymerization catalyst and a solvent to generate a polymerization catalyst solution. The system may also include a heating system coupled to the polymerization catalyst tank and configured to maintain a temperature of the polymerization catalyst solution above a threshold. The system may also include a precontactor configured to receive feed streams comprising an activator and the polymerization catalyst solution from the polymerization catalyst tank to generate a catalyst complex. The system may also include a transfer line configured to transfer the catalyst complex from an outlet of the precontactor to a reactor.
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100.发明申请Metallocene and Half Sandwich Dual Catalyst Systems for Producing Broad Molecular Weight Distribution Polymers 有权茂金属和半夹心双重催化剂体系，用于生产广泛的分子量分布聚合物公开(公告)号：US20140088274A1
公开(公告)日：2014-03-27
申请号：US13625898
申请日：2012-09-25
发明人： Errun Ding , Qing Yang , Youlu Yu , Lloyd W. Guatney , Jim B. Askew
CPC分类号： C08F4/76 , C08F4/52 , C08F4/65904 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/6592 , C08F4/65925 , C08F4/65927 , C08F10/00 , C08F10/02 , C08L23/00 , C08L23/04 , C08L23/10 , C08F110/02 , C08F2500/04 , C08F2500/12 , C08F210/16 , C08F210/14 , C08F2500/03
摘要： Disclosed herein are polymerization processes for the production of olefin polymers. These polymerization processes can use a dual catalyst system containing a zirconium or hafnium based metallocene compound and a titanium based half-metallocene compound containing an indenyl group.
摘要翻译： 本文公开了用于生产烯烃聚合物的聚合方法。 这些聚合方法可以使用含有锆或铪基茂金属化合物和含有茚基的钛基半茂金属化合物的双重催化剂体系。
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