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253 条记录 (耗时 0.036 秒)

    Process for the sulfonation of an elastomeric polymer
    91.
    发明授权
    Process for the sulfonation of an elastomeric polymer 失效
    磺化弹性聚合物的方法

    公开(公告)号：US4184988A

    公开(公告)日：1980-01-22

    申请号：US951394

    申请日：1978-10-16

    申请人： Henry S. Makowski ,  Robert D. Lundberg ,  Jan Bock

    发明人： Henry S. Makowski ,  Robert D. Lundberg ,  Jan Bock

    IPC分类号： C08C19/20 ,  C08F8/36 ,  C08F8/44 ,  C08L91/00

    CPC分类号： C08C19/20 ,  C08F8/36 ,  C08F8/44 ,  C08F2800/20

    摘要： An improved process for the sulfonation of an unsaturated elastomeric polymer to form a sulfonated elastomeric polymer, wherein a cement which contains an elastomeric polymer dissolved in a nonreactive solvent is contacted with a sulfonating agent at between about -100.degree. C. and +100.degree. C. for a period of time sufficient to result in sulfonation of the elastomeric polymer wherein the improvement includes the use of a sulfonating agent which is formed from mixtures of acyl sulfate ##STR1## with carboxylic acid anhydrides ##STR2## with carboxylic acid halides ##STR3## or with both, wherein R is selected from the group consisting of CH.sub.3 --, C.sub.2 H.sub.5 --, C.sub.3 H.sub.7 --, C.sub.4 H.sub.9 --, C.sub.5 H.sub.11, C.sub.6 H.sub.13 or C.sub.6 H.sub.5 and mixtures thereof. The molar ratio of ##STR4## is at least one.

    摘要翻译： 用于磺化不饱和弹性体聚合物以形成磺化弹性体聚合物的改进方法，其中将含有溶解在非反应性溶剂中的弹性体聚合物的水泥与约-100℃至+ 100℃的磺化剂接触 一段时间足以导致弹性体聚合物的磺化，其中改进包括使用由酰基硫酸酯与羧酸酐与羧酸卤化物的混合物形成的磺化剂 或两者，其中R选自CH 3 - ，C 2 H 5 - ，C 3 H 7 - ，C 4 H 9 - ，C 5 H 11，C 6 H 13或C 6 H 5及其混合物。 的摩尔比至少为1。

    Foamable thermoelastic ionomer composition
    92.
    发明授权
    Foamable thermoelastic ionomer composition 失效
    可发泡热弹性离聚物组合物

    公开(公告)号：US4164512A

    公开(公告)日：1979-08-14

    申请号：US855727

    申请日：1977-11-29

    申请人： Douglas Brenner ,  Robert D. Lundberg

    发明人： Douglas Brenner ,  Robert D. Lundberg

    IPC分类号： C08J9/00 ,  C08J9/06

    CPC分类号： C08J9/0066 ,  C08J9/0014 ,  C08J9/06 ,  C08J2323/32 ,  Y10S521/905

    摘要： This invention relates to a novel elastomeric foamed material which has been found to exhibit a variety of unusual and desirable features both in its physical properties and in its process of manufacture. These foamed compositions of a lightly sulfonated elastomeric gum contain a non-volatile polar plasticizer and preferably extenders such as oil and fillers. These elastomer foams exhibit an unusual profile of physical properties including extremely rapid production, melt reprocessability of fabricated articles, a novel memory characteristic, and high temperature reshaping of foamed objects while maintaining a good foam structure. These novel foams can be manufactured with relatively uniform cell structures and with small cell sizes at foam densities from near bulk density to less than 0.1g/cc.

    摘要翻译： 本发明涉及一种新型的弹性体泡沫材料，其已被发现在其物理性质和制造方法中表现出各种不寻常和期望的特征。 这些轻质磺化弹性体胶的泡沫组合物含有非挥发性极性增塑剂，优选增量剂如油和填料。 这些弹性体泡沫表现出不寻常的物理特性，包括极快的生产，制造的制品的熔融再加工性，新颖的记忆特性，以及发泡物体的高温重塑，同时保持良好的泡沫结构。 这些新型泡沫可以制造成具有相对均匀的细胞结构，并且具有从近体积密度至小于0.1g / cc的泡沫密度的小泡孔尺寸。

    Oil-plasticized copolymers of SO.sub.2 and olefins
    94.
    发明授权
    Oil-plasticized copolymers of SO.sub.2 and olefins 失效
    SO {HD 2 {B和烯烃的油增塑共聚物

    公开(公告)号：US4100128A

    公开(公告)日：1978-07-11

    申请号：US787367

    申请日：1977-04-14

    申请人： Guido Sartori ,  Robert D. Lundberg

    发明人： Guido Sartori ,  Robert D. Lundberg

    IPC分类号： C08G75/22 ,  C08K5/01 ,  C08G75/18

    CPC分类号： C08G75/22 ,  C08K5/01

    摘要： The instant invention relates to compositions comprising a copolymer of sulfur dioxide and one or more olefins in combination with a hydrocarbon oil which is a mixture of paraffinic, aromatic and naphthenic hydrocarbons having a solubility parameter of about 7 to about 8.5. The olefins are alpha olefins, at least one having a carbon number of 20 or more, more preferably a carbon number of from 20 to 40. The copolymers useful in preparing the compositions of the instant invention are crystalline solids, which are combined with a sufficient amount, preferably from about 5 to 24 pph, of the hydrocarbon oil to yield flexible materials. The above compositions are useful as coatings.

    摘要翻译： 本发明涉及包含二氧化硫和一种或多种烯烃与烃油的共聚物的组合物，烃油是溶解度参数为约7至约8.5的链烷烃，芳族烃和环烷烃的混合物。 烯烃是α-烯烃，至少一种碳原子数为20以上，更优选碳原子数为20〜40。可用于制备本发明组合物的共聚物是结晶固体，它们与足够的 量，优选约5至24pph的烃油，以产生柔性材料。 上述组合物可用作涂层。

    Novel ionic foams
    95.
    发明授权
    Novel ionic foams 失效
    新型离子泡沫

    公开(公告)号：US3947387A

    公开(公告)日：1976-03-30

    申请号：US547639

    申请日：1975-02-06

    申请人： Robert D. Lundberg

    发明人： Robert D. Lundberg

    IPC分类号： C08J9/04 ,  C08J11/08 ,  C08F47/10 ,  C08J1/28

    CPC分类号： C08J9/04 ,  C08J11/08 ,  Y02W30/701 ,  Y10S264/05 ,  Y10S264/18

    摘要： This invention relates to novel foamed polymeric products which are prepared by foaming an ionic polymer in the presence of a volatile polar compound which acts as a plasticizer for the ionic groups present in said ionic polymer. The ionic polymer comprises from about 0.4 to 10 mole % pendant acid groups, especially sulfonic acid groups which have been neutralized to a degree of at least 97%, preferably 100%. In a most preferred embodiment of the instant invention, the foamed polymeric product is prepared from a sulfonated polystyrene polymer. This high strength, low density foam of the instant invention can be reprocessed by admixing with a low boiling solvent for the sulfonate groups, e.g., methanol, and repeating the above foaming process.

    摘要翻译： 本发明涉及通过在挥发性极性化合物存在下使离子聚合物发泡而制备的新型泡沫聚合产物，所述挥发性极性化合物充当所述离子聚合物中存在的离子基团的增塑剂。 离子聚合物包含约0.4至10摩尔％的侧基酸基团，特别是已被中和到至少97％，优选100％的程度的磺酸基团。 在本发明的最优选实施方案中，泡沫聚合产物由磺化聚苯乙烯聚合物制备。 本发明的这种高强度，低密度泡沫可以通过与低沸点溶剂混合用于磺酸盐基团，例如甲醇，并重复上述发泡方法来再加工。

    Block copolymers containing olefin sulfur dioxide segments and process for their preparation
    96.
    发明授权
    Block copolymers containing olefin sulfur dioxide segments and process for their preparation 失效
    含有烯烃二氧化硫段的嵌段共聚物及其制备方法

    公开(公告)号：US3932369A

    公开(公告)日：1976-01-13

    申请号：US521454

    申请日：1974-11-06

    申请人： Guido Sartori ,  Robert D. Lundberg

    发明人： Guido Sartori ,  Robert D. Lundberg

    IPC分类号： C08F293/00 ,  C08G75/22 ,  C08F28/00

    CPC分类号： C08G75/22 ,  C08F293/00

    摘要： The instant invention relates to novel block copolymers containing olefin sulfur-dioxide segments and a process for their preparation. The olefin of choice is a "strained" olefin thus capable of reaction with SO.sub.2 in the presence of radicals at very high rates. Examples of strained olefins include cyclopropene, cyclobutene, norbornene, and the derivatives thereof. The novel block copolymers are prepared by contacting the olefin and the sulfur dioxide with a polymer under conditions of shearing degradation whereby said polymer is broken down into radical-containing segments which subsequently combine with the olefin and sulfur dioxide to form the novel copolymers described above. The polymer may be selected from the group consisting of polyisobutylene, poly(ethylene oxide), ethylene-propylene copolymers, poly(propylene oxide), polybutadiene, polyisoprene, etc. A novel block polymer formed by this preferred process shows improved properties as compared to physical mixtures of said polymer and olefin-sulfur dioxide copolymers. For example, the novel polymers formed by the preferred process of the instant invention show higher moduli and may be plasticized to higher levels while retaining good physical properties.

    摘要翻译： 本发明涉及含有烯烃二氧化硫段的新型嵌段共聚物及其制备方法。 所选择的烯烃是一种“应变”烯烃，因此能够在极性存在自由基的情况下与SO2反应。 应变烯烃的实例包括环丙烯，环丁烯，降冰片烯及其衍生物。 通过在剪切降解的条件下使烯烃和二氧化硫与聚合物接触来制备新的嵌段共聚物，其中所述聚合物被分解成含自由基的链段，其随后与烯烃和二氧化硫结合以形成上述新的共聚物。 聚合物可以选自聚异丁烯，聚（环氧乙烷），乙烯 - 丙烯共聚物，聚（环氧丙烷），聚丁二烯，聚异戊二烯等。通过该优选方法形成的新的嵌段聚合物显示出与 所述聚合物和烯烃 - 二氧化硫共聚物的物理混合物。 例如，通过本发明优选方法形成的新型聚合物显示更高的模量，并且可以塑化至更高的水平，同时保持良好的物理性能。

    Oil soluble amino-substituted polymers containing graft polymer segments derived from aromatic nitrogen-containing monomers
    100.
    发明授权
    Oil soluble amino-substituted polymers containing graft polymer segments derived from aromatic nitrogen-containing monomers 失效
    含有衍生自芳族含氮单体的接枝聚合物链段的油溶性氨基取代聚合物

    公开(公告)号：US5382632A

    公开(公告)日：1995-01-17

    申请号：US130611

    申请日：1993-10-01

    申请人： Abhimanyu O. Patil ,  Sudhin Datta ,  Robert D. Lundberg

    发明人： Abhimanyu O. Patil ,  Sudhin Datta ,  Robert D. Lundberg

    IPC分类号： C08G73/00 ,  C10M149/00 ,  H01B1/12 ,  C08F8/32

    CPC分类号： H01B1/128 ,  C08G73/00 ,  C10M149/00 ,  C10M2205/00 ,  C10M2205/02 ,  C10M2217/00

    摘要： The novel polymers of the present invention are prepared by graft polymerization of at least one aromatic nitrogen-containing monomer onto an amino-substituted polymer (e.g., an ethylene alpha-olefin interpolymer substituted by primary amino or secondary amino groups). Preferred aromatic nitrogen-containing moieties are illustrated by aniline, and preferred amino-substituted interpolymers comprise amino-substituted ethylene propylene norbornene terpolymers. The polymers of this invention are oil soluble and are useful as dispersant and antioxidant additives in oleaginous compositions and are further useful in electrical, textile and other applications.

    摘要翻译： 通过将至少一种含芳族含氮单体接枝聚合到氨基取代的聚合物（例如被伯氨基或仲氨基取代的乙烯α-烯烃互聚物）上制备本发明的新型聚合物。 优选的芳族含氮部分由苯胺表示，优选的氨基取代的互聚物包括氨基取代的乙烯丙烯降冰片烯三元共聚物。 本发明的聚合物是油溶性的，并且可用作油性组合物中的分散剂和抗氧化剂添加剂，并且还可用于电气，纺织和其它应用。