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    Method for reducing water uptake in silyl terminated sulfopoly(ester-urethanes)
    91.
    发明授权
    Method for reducing water uptake in silyl terminated sulfopoly(ester-urethanes) 失效
    减少甲硅烷基封端的磺基聚合物（酯 - 氨基甲酸酯）吸水率的方法

    公开(公告)号：US5929160A

    公开(公告)日：1999-07-27

    申请号：US937487

    申请日：1997-09-25

    Applicant: Larry R. Krepski ,  Steven M. Heilmann ,  Daniel E. Mickus ,  Wayne K. Larson

    Inventor： Larry R. Krepski ,  Steven M. Heilmann ,  Daniel E. Mickus ,  Wayne K. Larson

    IPC: C08L75/06 ,  C08G18/08 ,  C08G18/10 ,  C08G18/46 ,  C08G18/71 ,  C08G18/83 ,  C08J3/00 ,  C08K3/20 ,  C08L75/00 ,  C08L83/00

    CPC classification number: C08G18/4676 ,  C08G18/0828 ,  C08G18/10

    Abstract: A method of decreasing the water uptake in a sulfopoly(ester-urethane) by preparing said sulfopoly(ester-urethane) from a chain extended sulfopolyester polyol which itself has been prepared in a two-step method, said sulfopoly(ester-urethane) comprising in its backbone at least one non-terminal arylene or alkylene group comprising a pendant sulfonic acid group or salt thereof, said sulfonic acid group or salt thereof having the formula ##STR1## wherein R is a trivalent aliphatic or aromatic group and M is a cation, said sulfonic acid group or salt thereof being bonded directly through said aliphatic or aromatic group to ester groups, the polymer of said sulfo(polyester-urethane) being terminated by at least one hydrolyzable silyl group,said two-step method for preparing said chain extended sulfopolyester polyol comprising the steps of:a) reacting a sulfopolycarboxylic acid or ester with a polyol to produce a sulfopolyester polyol,b) chain extending said sulfopolyester polyol by an esterification reaction with a lower aliphatic lactone to produce a chain extended sulfopolyester polyol, andsaid chain extended sulfopolyester polyol then, (1) in one embodiment, being reacted with a stoichiometric excess of a polyisocyanate and at least one of a polyol, polyamine, and polythiol to produce an isocyanate-terminated sulfo(polyester-urethane), which is then reacted with a nucleophilic, hydrolyzable silane or (2) in a second embodiment, being reacted with a polyisocyanate and a stoichiometric excess of at least one of a polyol, polyamine, and polythiol to produce a hydroxyl-, amino-, or mercapto-terminated sulfo(polyester-urethane) which is then reacted with an electrophilic hydrolyzable silane to produce said sulfopoly(ester-urethane), which when dried has decreased water uptake.

    Abstract translation: 所述磺基聚（酯 - 氨基甲酸酯）包括通过由两步法制备的扩链磺基聚酯多元醇制备所述锍聚（酯 - 氨基甲酸酯）来降低锍聚（酯 - 氨基甲酸酯）中的吸水率的方法， 在其主链中至少有一个非末端亚芳基或含有磺酸侧基的亚烷基或其盐，所述磺酸基或其盐具有下式：其中R是三价脂族或芳族基，M是阳离子，所述磺酸 所述磺基（聚酯 - 氨基甲酸酯）的聚合物被至少一个可水解的甲硅烷基封端，所述制备所述链延长磺基聚酯多元醇的两步法 包括以下步骤：a）使磺基多羧酸或酯与多元醇反应以产生磺基聚酯多元醇，b）通过酯化链延伸所述磺基聚酯多元醇 与低级脂肪族内酯反应以产生扩链磺基聚酯多元醇，并且所述链延长磺基聚酯多元醇然后，（1）在一个实施方案中，与化学计量过量的多异氰酸酯和多元醇，多胺和 多异硫氰酸酯以产生异氰酸酯封端的磺基（聚酯 - 氨基甲酸酯），然后与亲核的可水解的硅烷反应，或（2）在第二个实施方案中与多异氰酸酯和化学计量过量的多元醇， 多胺和多硫醇，以产生羟基，氨基或巯基封端的磺基（聚酯 - 氨基甲酸酯），然后与亲电的可水解硅烷反应产生所述磺化聚（酯 - 氨基甲酸酯），当干燥时，其吸水量降低。

    Polymeric supports
    96.
    发明授权
    Polymeric supports 失效
    聚合物载体

    公开(公告)号：US5403902A

    公开(公告)日：1995-04-04

    申请号：US183063

    申请日：1994-01-18

    Applicant: Steven M. Heilmann ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Dean S. Milbrath ,  Patrick L. Coleman ,  Margaret M. Walker

    Inventor： Steven M. Heilmann ,  Jerald K. Rasmussen ,  Larry R. Krepski ,  Dean S. Milbrath ,  Patrick L. Coleman ,  Margaret M. Walker

    IPC: A61K39/395 ,  B01J20/26 ,  C07K17/08 ,  C08F8/00 ,  C08F8/48 ,  C08F20/58 ,  C12N11/08 ,  C08F26/06 ,  C08F220/10 ,  C08F220/54

    CPC classification number: C12N11/08 ,  A61K39/39525 ,  B01J20/26 ,  C07K17/08 ,  C08F20/58 ,  C08F8/00 ,  C08F8/48

    Abstract: Azlactone-functional polymer supports are useful reactive supports for the attachment of functional materials to provide novel adduct beads. The adduct beads are useful as complexing agents, catalysts, polymeric reagents, chromatographic supports, and as enzyme- or other biologically active supports. Novel carboxylate-functional polymer beads, are intermediates in the preparation of the azlactone-functional beads.Azlactone-functional supports have units of the formula: ##STR1## wherein R.sup.1 is H or CH.sub.3,R.sup.2 and R.sup.3 independently can be an alkyl group having 1 to 14 carbon atoms, a cycloalkyl group having 3 to 14 carbon atoms, an aryl group having 5 to 12 ring atoms, an arenyl group having 6 to 26 carbon and 0 to 3 S, N, and nonperoxidic O heteroatoms, or R.sup.2 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms, andn is an integer 0 or 1, the azlactone functional supports having 0.1 to 99 molar parts of crosslinking monomer incorporated therein.

    Abstract translation: 吖内酯官能聚合物载体是用于附着功能材料以提供新型加合珠的有用的反应性载体。 加合珠可用作络合剂，催化剂，聚合物试剂，色谱载体，以及酶或其它生物活性载体。 新型羧酸盐官能化聚合物珠粒是制备吖内酯官能团珠粒的中间体。 吖内酯官能载体具有下式的单元：其中R 1为H或CH 3，R 2和R 3可独立地为具有1至14个碳原子的烷基，具有3至14个碳原子的环烷基，芳基 具有5至12个环原子，具有6至26个碳和0至3个S，N和非过氧O的杂原子的芳基，或与其连接的碳一起的R 2和R 3可以形成含有4至 12个环原子，n为0或1的整数，所述吖内酯官能载体中含有0.1至99摩尔份的交联单体。

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