Polyethyleneimine and polyvinylamine derivatives, aluminum-based
substrate materials coated with these derivatives and the use thereof
for the production of offset printing plates
    94.
    发明授权
    Polyethyleneimine and polyvinylamine derivatives, aluminum-based substrate materials coated with these derivatives and the use thereof for the production of offset printing plates 失效
    聚乙烯和聚乙烯胺衍生物,用这些衍生物涂覆的基于铝的基材料及其用于生产偏移印刷板的用途

    公开(公告)号:US5217813A

    公开(公告)日:1993-06-08

    申请号:US805179

    申请日:1991-12-11

    摘要: In novel polyethyleneimine and polyvinylamine derivatives, the polyethyleneimines contain the structural elements Ia and/or Ib ##STR1## and the polyvinylamines contain the structural elements II.sub.a, II.sub.b and II.sub.c ##STR2## where, for the degrees of polymerization n, m and p, n.gtoreq.1, m.gtoreq.0 and p.gtoreq.0, and X.sup.1 is CR.sup.1 R.sup.2 PO.sub.3 R.sup.3 R.sup.4 or CR.sup.1 R.sup.2 SO.sub.3 R.sup.3, X.sup.2 independently of X.sup.1 is hydrogen, CR.sup.1 R.sup.2 PO.sub.3 R.sup.3 R.sup.4 or CR.sup.1 R.sup.2 SO.sub.3 R.sup.3, Y.sup.1 and Y.sup.2 independently of one another are each one or more CHR.sup.1 PO.sub.3 R.sup.3 R.sup.4 or CHR.sup.1 SO.sub.3 R.sup.3 groups or hydrogen, Y.sup.3 and Y.sup.4 independently of one another and of Y.sup.1 and Y.sup.2 are each hydrogen, CHR.sup.1 PO.sub.3 R.sup.3 R.sup.4 or CHR.sup.1 SO.sub.3 R.sup.3, and Z.sup.1 -Z.sup.4 are identical or different inorganic and/or organic radicals, wherein R.sup.1 and R.sup.2 independently of one another are each hydrogen, C.sub.1 -C.sub.12 -alkyl or aryl and R.sup.3 and R.sup.4 independently of one another are each hydrogen, an alkali metal atom or NR.sup.5 R.sup.6 R.sup.7 R.sup.8, where R.sup.5 to R.sup.8 are identical or different radicals selected from the group consisting of hydrogen, alkyl, aryl, hydroxyalkyl and benzyl.Aluminum-based substrates coated with these polyethyleneimines and/or polyvinylamines are used for the production of offset printing plates.

    摘要翻译: 在新型聚乙烯亚胺和聚乙烯胺衍生物中,聚乙烯亚胺含有结构元素Ia和/或Ib Ib,聚乙烯胺含有结构元素IIa,IIb和IIc IIa图像IIb图像IIc 其中,对于聚合度n,m和p,n> / = 1,m> / = 0和p> / = 0,X1为CR1R2PO3R3R4或CR1R2SO3R3,独立于X1的X2为氢,CR1R2PO3R3R4或CR1R2SO3R3,Y1 和Y2彼此独立地为一个或多个CHR1PO3R3R4或CHR1SO3R3基团,或氢,Y3和Y4彼此独立且Y1和Y2各自为氢,CHR1PO3R3R4或CHR1SO3R3,Z1-Z4为相同或不同的无机和/或 有机基团,其中R 1和R 2彼此独立地为氢,C 1 -C 12 - 烷基或芳基,且R 3和R 4彼此独立地为氢,碱金属原子或NR 5 R 6 R 7 R 8,其中R 5至R 8为相同或不同的基团 选自氢,等 烷基,芳基,羟基烷基和苄基。 用这些聚乙烯亚胺和/或聚乙烯胺涂覆的铝基基材用于生产胶版印刷版。

    Preparation of insoluble polymer powders which are only slightly
swellable
    97.
    发明授权
    Preparation of insoluble polymer powders which are only slightly swellable 失效
    只能轻微溶胀的不溶性聚合物粉末的制备

    公开(公告)号:US4647637A

    公开(公告)日:1987-03-03

    申请号:US777327

    申请日:1985-09-18

    CPC分类号: C08F226/10

    摘要: Insoluble polymer powders which are only slightly swellable and are based on N-vinylpyrrolidone are prepared by polymerization of N-vinylpyrrolidone or a mixture of this with copolymerizable monomers and from 0.1 to 10% by weight, based on the total amount of monomers, of a crosslinking agent in a powder bed in the presence of a heat-transfer medium, which is inert to the reactants, and in the absence of oxygen and polymerization initiators, at from 90.degree. to 220.degree. C., while maintaining the powder state, circulating the reaction mass and evaporating the heat-transfer medium from the polymerization zone. The resulting insoluble polymers which are only slightly swellable are used as adsorbents or formulation assistants for fertilizers and crop protection agents.

    摘要翻译: 通过N-乙烯基吡咯烷酮或其混合物与可共聚单体的聚合反应制备仅基于N-乙烯基吡咯烷酮轻微溶胀并且基于N-乙烯基吡咯烷酮的不溶性聚合物粉末,基于单体总量为0.1-10重量% 交联剂在粉末床中,在对反应物呈惰性的热传递介质存在下,在不存在氧和聚合引发剂的情况下,在90℃至220℃下,同时保持粉末状态,循环 反应物质并从聚合区蒸发传热介质。 所得的不溶性聚合物只是稍微溶胀,被用作肥料和作物保护剂的吸附剂或制剂助剂。