公开(公告)号：US5424445A

公开(公告)日：1995-06-13

申请号：US99140

申请日：1993-07-29

申请人： Johan H. Hendrick ter Maat ,  Marion Meyer ,  Knut Oppenlaender ,  Michael Zirnstein ,  Walter Denzinger ,  Lothar Franz

发明人： Johan H. Hendrick ter Maat ,  Marion Meyer ,  Knut Oppenlaender ,  Michael Zirnstein ,  Walter Denzinger ,  Lothar Franz

IPC分类号： B01F17/00 ,  B01F17/18 ,  B01F17/46 ,  C07C217/08 ,  C07C229/12 ,  C07C229/22 ,  C07C233/18 ,  C07D207/26 ,  C07D207/27 ,  C07D207/273 ,  C07D207/40 ,  C07D207/404 ,  C07D207/408 ,  C07D207/452 ,  C08G65/32 ,  C08G65/333 ,  C08J3/22

CPC分类号： C07D207/273 ,  B01F17/0042 ,  C07C217/08 ,  C07C229/12 ,  C07C229/22 ,  C07D207/404 ,  C08G65/333 ,  C08J3/226 ,  C08J2471/00

摘要： Alkoxylation products which are suitable as dispersants and are of the general formula I ##STR1## where A is oxygen or --CO--O-- when x and y are each 1 or is nitrogen when x+y=3,B is ethylidene or 1,2-propylidene,Z is one of the groups ##STR2## D.sup..crclbar. is formate, acetate, propionate or hydroxide, E.sup..crclbar. is carboxylate or sulfonate,M is a bridge group for completion of a pyrrolidone, succinimide or maleimide ring to give a group ##STR3## n is from 1 to 50, q is from 1 to 4,x and y are each 1 or 2, with the proviso that x+y.ltoreq.3,R.sup.1 is C.sub.8 -C.sub.30 -alkyl or, when A is oxygen, is C.sub.4 -C.sub.12 -alkyl-substituted phenyl,R.sup.2, R.sup.3 and R.sup.4 are each hydrogen, methyl or ethyl andR.sup.5 is hydrogen or methyl,a process for their preparation, their use for dispersing finely divided solids in flowable media, and formulations containing the alkoxylation products.

摘要翻译： 适合作为分散剂并具有通式I（R1）xA [（BO）nBNR2R3] y的烷氧基化产物，其中当x和y各自为1时，A为氧或-CO-O-，当x + y = 3，B是亚乙基或1,2-亚丙基，Z是乙酸酯，丙酸酯或氢氧化物之一，E（ - ）是羧酸酯或磺酸酯，M是完成吡咯烷酮，琥珀酰亚胺或马来酰亚胺环的桥基， n为1至50，q为1至4，x和y各自为1或2，条件是x + y = 3，R 1为C 8 -C 30 - 烷基，或 A是氧，是C 4 -C 12烷基取代的苯基，R 2，R 3和R 4各自是氢，甲基或乙基，R 5是氢或甲基，其制备方法，它们用于将细碎固体分散在可流动介质中， 和含有烷氧基化产物的制剂。

公开(公告)号：US5124181A

公开(公告)日：1992-06-23

申请号：US582329

申请日：1990-09-14

申请人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C08L33/04 ,  C08L33/06 ,  C09K3/18 ,  C14C9/00

CPC分类号： C14C9/00

摘要： Copolymers which containa) from 50 to 90% by weight of C.sub.8 -C.sub.40 -alkyl methacrylates, vinyl esters of C.sub.8 -C.sub.40 -carboxylic acids or mixtures thereof andb) from 10 to 50% by weight of monoethylenically unsaturated C.sub.3 -C.sub.12 -carboxylic acids, monoethylenically unsaturated dicarboxylic anhydrides, monoesters or monoamides of monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids, amides of C.sub.3 -C.sub.12 -monocarboxylic acids or mixtures thereofas copolymerized units and have molecular masses of from 500 to 30,000 are used in at least partially neutralized form in aqueous solution or dispersion for making leather and furs water repellent.

摘要翻译： 包含a）50-90％重量的甲基丙烯酸C 8 -C 40烷基酯，C 8 -C 40羧酸的乙烯基酯或其混合物的共聚物，和b）10-50％重量的单烯属不饱和C 3 -C 12羧酸 酸，单烯键式不饱和二羧酸酐，单烯属不饱和C4-C12-二羧酸的单酯或单酰胺，C3-C12-一元羧酸的酰胺或其混合物作为共聚单元，分子量为500至30,000，至少部分中和 在水溶液或分散体中形成皮革和毛皮防水剂。

公开(公告)号：US5352729A

公开(公告)日：1994-10-04

申请号：US973986

申请日：1992-11-09

申请人： Hermann Birkhofer ,  Walter Denzinger ,  Heinrich Hartmann ,  Juan A. G. Gomez ,  Paul Guenthert ,  Joachim Jesse ,  Robert Kreuzer ,  Knut Oppenlaender ,  Reinhard U. Roth ,  Benno Sens

发明人： Hermann Birkhofer ,  Walter Denzinger ,  Heinrich Hartmann ,  Juan A. G. Gomez ,  Paul Guenthert ,  Joachim Jesse ,  Robert Kreuzer ,  Knut Oppenlaender ,  Reinhard U. Roth ,  Benno Sens

IPC分类号： C09B67/08 ,  C09B67/20 ,  C09B67/46 ,  C09C3/10 ,  C09D7/00 ,  C09D11/037 ,  C08L35/08 ,  C08L33/02 ,  C08L23/20 ,  C08L23/24

CPC分类号： C09D11/037 ,  C09B67/0063 ,  C09B67/009 ,  C09D7/007 ,  Y10T428/2998

摘要： Pigment formulations containing(a) at least one finely divided pigment,(b) at least one copolymer obtainable by free radical polymerization of(.alpha..sub.1) C.sub.8 -C.sub.40 -monoolefins or(.alpha..sub.2) C.sub.8 -C.sub.40 -alkyl vinyl ethers or(.alpha..sub.3) a mixture of C.sub.8 -C.sub.40 -alkyl vinyl ethers and up to 50 mol % of C.sub.8 -C.sub.40 -monoolefins with(.beta.) monoethylenically unsaturated C.sub.4 -C.sub.12 -dicarboxylic acids or C.sub.4 -C.sub.12 -dicarboxylic anhydridesand having a molecular weight of from 500 to 20,000 g/mol, some or all of whose carboxyl or anhydride groups may be reacted with ammnonia, amines, alcohols, amino- or hydroxycarboxylic acids or alkali metal or alkaline earth metal hydroxides, and(c) if required, further assistants conventionally used in pigment formulationsare used for the preparation of pastes, printing inks and coatings.

摘要翻译： 含有（a）至少一种细分散颜料的颜料配方，（b）至少一种可通过（α1）C8-C40-单烯烃或（α2）C8-C40-烷基乙烯基醚的自由基聚合获得的共聚物或（α 3）C8-C40烷基乙烯基醚和高达50mol％的C8-C40-单烯烃与（β）单烯属不饱和C4-C12-二羧酸或C4-C12-二羧酸酐的混合物，其分子量为 500至20,000g / mol，其羧基或酸酐基团的一些或全部可与氨基，胺，醇，氨基或羟基羧酸或碱金属或碱土金属氢氧化物反应，和（c）如果需要， 用于颜料配方中用于制备糊剂，印刷油墨和涂料。

公开(公告)号：US5266165A

公开(公告)日：1993-11-30

申请号：US955270

申请日：1992-10-01

申请人： Arnold DeClercq ,  Walter Denzinger ,  Norbert Greif ,  Heinrich Hartmann ,  Knut Oppenlaender ,  Ulrich Riebeling

发明人： Arnold DeClercq ,  Walter Denzinger ,  Norbert Greif ,  Heinrich Hartmann ,  Knut Oppenlaender ,  Ulrich Riebeling

IPC分类号： C08F8/32 ,  C08F8/44 ,  C08F10/00 ,  C08F210/00 ,  D21H17/16 ,  D21H19/16 ,  D21H17/45 ,  C08F8/30 ,  C08F222/06 ,  D21H21/16

CPC分类号： D21H17/16 ,  C08F8/44

摘要： Abstract of the Disclosure: Copolymers of (a) C.sub.12 - to C.sub.24 -monoolefins and (b) maleic anhydride or itaconic anhydride, having molecular weights of from 800 to 100,000 g/mol, in the form of partially or completely neutralized semiamides with morpholine, in aqueous solution or dispersion, can be used as sizes for paper.

摘要翻译： 公开的摘要：（a）C12-至C24-单烯烃和（b）分子量为800至100,000g / mol的马来酸酐或衣康酸酐的共聚物为部分或完全中和的具有吗啉的半酰胺形式， 在水溶液或分散体中，可用作纸张的尺寸。

公开(公告)号：US5009670A

公开(公告)日：1991-04-23

申请号：US352418

申请日：1989-05-16

申请人： Franz-Dieter Martischius ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Franz-Dieter Martischius ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C10L1/224 ,  C10L1/196 ,  C10L1/197 ,  C10L1/24 ,  C10L1/26 ,  C10L1/30 ,  C10L10/08 ,  F02B1/04

CPC分类号： C10L10/04 ,  C10L1/1963 ,  C10L1/1966 ,  C10L1/1973 ,  C10L1/2468 ,  C10L1/2675 ,  C10L10/08 ,  F02B1/04

摘要： Fuels for gasoline engines contain small amounts of copolymers of alkyl (meth)-acrylates where the alkyl radical is of 8 to 40 carbon atoms and/or vinyl esters of carboxylic acids of 8 to 40 carbon atoms and monoethylenically unsaturated mono- and/or dicarboxylic acids of 3 to 12 carbon atoms and/or monoethylenically unsaturated compounds having sulfo and/or phosphonic acid groups, having a total molecular weight of from 500 to 20,000 g per mole, some or all of the carboxyl, sulfo and phosphonic acid groups of the copolymers having been reacted with an alkali or alkaline earth with formation of the alkali metla salts or alkaline earth metal salts and the remainder of the acid groups having been reacted with ammonia and/or amines of not more than 50 carbon atoms to give the corresponding amide groups and/or ammonium salts.

摘要翻译： 汽油发动机的燃料含有少量的（甲基）丙烯酸烷基酯（其中烷基为8〜40个碳原子）和/或碳原子数为8〜40的羧酸的乙烯基酯和单烯属不饱和单 - 和/或二羧酸的共聚物 3至12个碳原子的酸和/或具有磺基和/或膦酸基团的单烯属不饱和化合物，总分子量为每摩尔500至20,000克，部分或全部羧基，磺基和膦酸基团 已经与碱金属或碱土金属反应形成碱金属盐或碱土金属盐，其余的酸基已经与不超过50个碳原子的氨和/或胺反应得到相应的酰胺 基团和/或铵盐。

公开(公告)号：US5279613A

公开(公告)日：1994-01-18

申请号：US829565

申请日：1992-02-05

申请人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C14C9/00 ,  C14C11/00

CPC分类号： C14C9/00

摘要： Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 --C.sub.40 -monoolefins with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides by mass polymerization at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for rendering leathers and skins water-repellent.

摘要翻译： 共聚物可以通过（a）C8-C40-单烯烃与（b）烯键式不饱和C4-C8-二羧酸酐在80摄氏度至300摄氏度下进行大量聚合而自由基共聚获得，得到分子量为 500至20,000g / mol，随后溶剂分解共聚物的酸酐基团，并在溶剂分解期间形成的羧基部分或完全中和，在水性介质中通过碱，并以水分散体的形式存在 或溶液，用作皮革和皮肤防水剂的制剂。

公开(公告)号：US4959077A

公开(公告)日：1990-09-25

申请号：US243072

申请日：1988-09-12

申请人： Franz-Dieter Martischius ,  Hans P. Rath ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Franz-Dieter Martischius ,  Hans P. Rath ,  Hans-Henning Vogel ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C10L1/234 ,  C08F8/44 ,  C10L1/18 ,  C10L1/192 ,  C10L1/195 ,  C10L1/196 ,  C10L1/22 ,  C10L1/236 ,  C10L10/08 ,  F02B1/04 ,  F02B75/02

CPC分类号： C10L1/2364 ,  C08F8/44 ,  C10L1/1955 ,  C10L1/1966 ,  F02B1/04 ,  F02B2075/027

摘要： A fuel for gasoline engines contains a small amount of a copolymer of an olefin of from 2 to 40 carbon atoms and/or a cycloolefin of from 3 to 10 carbon atoms with maleic anhydride and/or a copolymer of an alkyl vinyl ether of from 1 to 30 carbon atoms in the alkyl group and/or a cycloalkyl vinyl ether of from 3 to 10 carbon atoms in the alkyl group with maleic anhydride and/or a copolymer of an alkyl vinyl ether of from 1 to 30 carbon atoms in the alkyl group and/or a cycloalkyl vinyl ether of from 3 to 10 carbon atoms in the alkyl group and an olefin of from 2 to 40 carbon atoms and/or a cycloolefin of from 3 to 10 carbon atoms with maleic anhydride having a total molecular weight of from 500 to 20,000 g per mole, the carboxyl groups on the copolymer having been wholly or partly converted with an alkali metal or alkaline earth metal to form an alkali metal or alkaline earth metal salt and the remaining carboxyl groups having been converted with an alcohol and/or an amine of up to 50 carbon atom into the corresponding ester and/or amide groups and/or ammonium salts.

摘要翻译： 汽油发动机的燃料含有少量的含有2-40个碳原子的烯烃和/或3-10个碳原子的烯烃与马来酸酐和/或烷基乙烯基醚共聚物的共聚物，其中共聚物为1 烷基中的至少30个碳原子和/或烷基中具有3至10个碳原子的环烷基乙烯基醚与烷基中的马来酸酐和/或1至30个碳原子的烷基乙烯基醚的共聚物 和/或烷基中具有3至10个碳原子的环烷基乙烯基醚和2至40个碳原子的烯烃和/或3至10个碳原子的环烯烃与马来酸酐的总分子量为 每摩尔500至20,000g，共聚物中的羧基已经用碱金属或碱土金属完全或部分转化，以形成碱金属或碱土金属盐，剩余的羧基已被醇和/ 或高达50的胺 碳原子进入相应的酯和/或酰胺基和/或铵盐。

公开(公告)号：US06264839B1

公开(公告)日：2001-07-24

申请号：US08089436

申请日：1993-07-12

申请人： Juergen Mohr ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann ,  Richard Baur ,  Charalampos Gousetis ,  Alexander Kud

发明人： Juergen Mohr ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann ,  Richard Baur ,  Charalampos Gousetis ,  Alexander Kud

IPC分类号： C02F142

CPC分类号： C08F8/40 ,  Y02W10/37

摘要： Phosphonomethylated poly-vinylamines which contain as characteristic structural elements units of the formula where R1 is hydrogen, C1-C6-alkyl or and X is hydrogen, an alkali metal, ammonium or one equivalent of an alkaline earth metal, are obtainable by phosphonomethylation of polymers which contain N-vinyl-amide or vinylamine groups and are useful as detergent additives and water treatment agents.

摘要翻译： 作为特殊结构单元的膦酰基甲基化聚乙烯胺，其中R 1为氢，C 1 -C 6 - 烷基或X为氢，碱金属，铵或1当量碱土金属，可通过聚合物的膦酰甲基化得到， N-乙烯基 - 酰胺或乙烯基胺基，可用作洗涤剂添加剂和水处理剂。

公开(公告)号：US5433752A

公开(公告)日：1995-07-18

申请号：US290779

申请日：1994-08-26

申请人： Hermann Birkhofer ,  Peter Danisch ,  Walter Denzinger ,  Heinrich Hartmann ,  Norbert Greif ,  Knut Oppenlaender

发明人： Hermann Birkhofer ,  Peter Danisch ,  Walter Denzinger ,  Heinrich Hartmann ,  Norbert Greif ,  Knut Oppenlaender

IPC分类号： C14C9/00 ,  C14C3/22 ,  C14C9/02

CPC分类号： C14C9/00

摘要： Products useful for fatliquoring and filling leather and fur skins are obtained on reactingA) homo- or copolymers based on monoethylenically unsaturated dicarboxylic anhydrides and obtainable by free-radically initiated polymerization ofa) from 30 to 100 mol % of one or more monoethylenically unsaturated dicarboxylic anhydrides of from 4 to 10 carbon atoms,b) from 0 to 70 mol % of one or more aromatic vinyl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, methyl or ethyl and k is 1 or 2,(c) from 0 to 70 mol % of one or more vinyl esters of C.sub.1 - to C.sub.8 -carboxylic acids,(d) from 0 to 50 mol % of one or more C.sub.2 - to C.sub.6 -olefins, and(e) from 0 to 30 mol % of one or more monoethylenically unsaturated C.sub.3 - to C.sub.5 -carboxylic acids, which mixture of monomers (a) to (e) may additionally contain up to 10% by weight of further copolymerizable monomers, withB) amines of the general formula R.sub.4 R.sub.5 NH, where R.sup.4 is hydrogen, C.sub.1 - to C.sub.20 -alkyl, C.sub.5 - to C.sub.8 -cycloalkyl or C.sub.2 - to C.sub.4 -hydroxyalkyl and R.sup.5 is C.sub.6 - to C.sub.30 -alkyl, C.sub.6 - to C.sub.30 -alkenyl, C.sub.5 - to C.sub.8 -cycloalkyl or C.sub.2 - to C.sub.4 -hydroxyalkyl, or alcohols of the general formula R.sup.6 --O--(C.sub.m H.sub.2m O).sub.p --(C.sub.n H.sub.2n O).sub.q --H, where R.sup.6 is C.sub.1 - to C.sub.30 -alkyl, C.sub.2 - to C.sub.30 -alkenyl, C.sub.5 - to C.sub.8 -cycloalkyl or--if p+q>0--hydrogen, m and n are each from 2 to 4 and p and q are each from 0 to 50, or mixtures of such amines and alcohols.

摘要翻译： PCT No.PCT / EP93 / 00354 Sec。 371日期1994年8月26日 102（e）日期1994年8月26日PCT提交1993年2月15日PCT公布。 公开号WO93 / 17130 PCT 日期：1993年9月2日。用于加脂和填充皮革和毛皮的产品可以通过A）基于单烯键式不饱和二羧酸酐的均聚物或共聚物获得，可通过自由基引发的a）30至100摩尔％ 的一种或多种具有4-10个碳原子的单烯键式不饱和二羧酸酐，b）0-70摩尔％的一种或多种通式I的芳族乙烯基化合物，其中R 1，R 2和R 3各自为氢， 甲基或乙基，k为1或2，（c）0至70摩尔％的一种或多种C 1至C 8羧酸的乙烯基酯，（d）0至50摩尔％的一种或多种C 2 - C6-烯烃，和（e）0-30mol％的一种或多种单烯键式不饱和C3-至C5-羧酸，单体（a）至（e）的混合物可另外含有高达10重量％ 可共聚的单体，B）通式为R4R5NH的胺，其中R4是氢，C1-至C20-烷基，C5-至 C 5 -C 8 - 环烷基或C 2 -C 4羟基烷基，R 5为C 6至C 30 - 烷基，C 6至C 30 - 烯基，C 5 -C 8 - 环烷基或C 2至C 4 - 羟烷基，或通式为R 6 -O - （CmH2mO）p-（CnH2nO）qH，其中R6是C1-至C30-烷基，C2-至C30-烯基，C5-至C8-环烷基或 - 如果p + q> O-氢，m和n各自 2至4，p和q各自为0至50，或这些胺和醇的混合物。

公开(公告)号：US5286263A

公开(公告)日：1994-02-15

申请号：US829062

申请日：1992-02-10

申请人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

发明人： Ortwin Schaffer ,  Herbert Bay ,  Karl Stork ,  Norbert Greif ,  Knut Oppenlaender ,  Walter Denzinger ,  Heinrich Hartmann

IPC分类号： C08F8/32 ,  C08F8/44 ,  C08F16/16 ,  C08F216/16 ,  C08F220/04 ,  C08F222/06 ,  C14C9/00 ,  C14C3/08

CPC分类号： C14C9/00 ,  C08F8/44

摘要： Copolymers which are obtainable by free radical copolymerization of (a) C.sub.8 -C.sub.40 -alkyl vinyl ethers, if necessary as a mixture with not more than 50 mol % of C.sub.8 -C.sub.40 -monoolefins, with (b) ethylenically unsaturated C.sub.4 -C.sub.8 -dicarboxylic anhydrides at from 80.degree. to 300.degree. C. to give copolymers having molecular weights of from 500 to 20,000 g/mol, subsequent solvolysis of the anhydride groups of the copolymers and partial or complete neutralization of the carboxyl groups formed during the solvolysis, in an aqueous medium by means of a base, and which are present in the form of aqueous dispersions or solutions, are used as agents for imparting water repellency to leathers and skins.

摘要翻译： （a）C8与C40烷基乙烯基醚的自由基共聚得到的共聚物，可能与高达50mol％的C 8〜C 40单烯烃混合，与（B）烯属不饱和C4〜C8二羧酸酐在80〜300℃的温度 C以500至200000g / mol的摩尔质量共聚，然后将共聚物的酸酐基溶剂分解，并且在水性介质中至少部分中和，其中通过溶剂解产生的羧基的碱可以以 水性分散体或防水皮革和毛皮的解决方案。