公开(公告)号：US4394251A

公开(公告)日：1983-07-19

申请号：US258496

申请日：1981-04-28

申请人： Stephen J. Miller

发明人： Stephen J. Miller

IPC分类号： B01J29/035 ,  B01J29/06 ,  B01J29/40 ,  B01J29/80 ,  C01B37/02 ,  C01B39/00 ,  C01B39/04 ,  C01B39/36 ,  C01B39/38 ,  C01B39/40 ,  C01B39/42 ,  C07B61/00 ,  C07C1/00 ,  C07C2/12 ,  C07C5/13 ,  C07C5/23 ,  C07C67/00 ,  C10G11/00 ,  C10G11/05 ,  C10G35/095 ,  C10G45/64 ,  C10G47/16 ,  C10G49/08 ,  C10G50/00 ,  C10G50/02 ,  C10G73/02

CPC分类号： C10G11/05 ,  B01J29/40 ,  C01B33/2876 ,  C10G35/095 ,  C10G49/08 ,  B01J2229/62 ,  Y10S208/02

摘要： Hydrocarbon conversion processes with crystalline silicates surrounded by an alumina containing isostructural shell are claimed.

摘要翻译： 要求具有由含有同位素结构的壳的氧化铝包围的结晶硅酸盐的烃转化方法。

公开(公告)号：US4197214A

公开(公告)日：1980-04-08

申请号：US949703

申请日：1978-10-10

申请人： Nai Y. Chen ,  William J. Reagan ,  Vern W. Weekman, Jr.

发明人： Nai Y. Chen ,  William J. Reagan ,  Vern W. Weekman, Jr.

IPC分类号： C10G11/00 ,  B01J29/06 ,  B01J29/90 ,  B01J38/12 ,  C01B39/20 ,  C01B39/26 ,  C01B39/30 ,  C01B39/36 ,  C01B39/38 ,  C01B39/42 ,  C01B39/44 ,  C10G2/00 ,  C10G3/00 ,  B01J29/38 ,  C07C15/00 ,  C10G35/06

CPC分类号： B01J29/90 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/4006 ,  C10G2300/807 ,  C10G2400/02 ,  Y02P30/20

摘要： Crystalline zeolite catalysts are stabilized against reducing and moisture containing atmospheres by providing and maintaining substantial metal cationic sites in the zeolite during use in chemical reactions encountering reducing and/or moisture rich atmospheres at high temperature.

摘要翻译： 结晶沸石催化剂通过在使用期间在沸石中提供和维持大量的金属阳离子位点而稳定，以减少和含水气氛。在化学反应中遇到在高温下还原和/或富含水分的气氛。

公开(公告)号：US3849463A

公开(公告)日：1974-11-19

申请号：US31371772

申请日：1972-12-11

申请人： MOBIL OIL CORP

发明人： DWYER F ,  CHU P

IPC分类号： B01J29/08 ,  B01J29/40 ,  B01J29/70 ,  C01B39/36 ,  C01B33/28

CPC分类号： C01B33/2807 ,  B01J29/085 ,  B01J29/40 ,  B01J29/7011 ,  C01B33/2876 ,  Y10S423/22 ,  Y10S423/24 ,  Y10S423/25 ,  Y10S423/26 ,  Y10S423/27 ,  Y10S423/38

摘要： 1. A METHOD OF DECREASING SILICA PORE OBSTRUCTION IN CRYSTALLINE ALUMINOSILICATES HAVING A SIO2 A12O3 RATIO GREATER THAN 6 WHICH COMPRISES ADMIXING A CRYSTALLINE ALUMINOSILICATE ZEOLITE REACTION MIXTURE SUFFICIENT TO PREPARE A CRYASTALLINE ALUMINOSILICATE ZEOLITE, SAID REACTION MIXTURE COMPRISING THE FOLLOWING COMPONENTS EXPRESSED AS OXIDES IN THE MOLE RATIOS SET FORTH: NA2OO (R2O+NA2O) .31 TO O 6 H2O (R2O+NA2O) 15 TO 600 WHEREIN R IS A TETRAMETHYLAMMONIUM CATION, WITH AN ALKALI METAL SALT CONTAINING MONOVALENT ANIONS IN AN AMOUNT SUFFICIENT TO DECREASE SILICA PORE ABSTRUCTION, AND MAINTAINING THE MIXTURE UNTIL CRYSTALS HAVING THE X-RAY DIFFRACTION PATTERN VALUES SHOWN IN TABLE 2 OF THE SPECIFICATION ARE FORMED.

公开(公告)号：US20240246829A1

公开(公告)日：2024-07-25

申请号：US18153015

申请日：2023-01-11

申请人： Saudi Arabian Oil Company

发明人： Robert Peter HODGKINS ,  Omer Refa KOSEOGLU ,  Javier Ruiz MARTINEZ ,  Moussa ZAAROUR

IPC分类号： C01B39/36 ,  C01B39/04 ,  C01B39/50

CPC分类号： C01B39/36 ,  C01B39/04 ,  C01B39/50

摘要： The present disclosure is directed to a method to synthesize pure silica zeolites. This is accomplished by using an improved sol-gel formulation including a water-soluble fraction of ODSO as an additional component together with precursors and reagents effective for synthesis of pure silica zeolite.

公开(公告)号：US11040885B2

公开(公告)日：2021-06-22

申请号：US15996330

申请日：2018-06-01

申请人： UOP LLC

发明人： Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C01B39/36 ,  C01B39/40 ,  B01J29/40 ,  B01J29/46 ,  C01B39/04 ,  B01J29/072 ,  B01J35/00 ,  B01J35/10 ,  B01J29/06

摘要： A family of crystalline aluminosilicate zeolites has been synthesized that is a layered pentasil zeolite. These zeolites are represented by the empirical formula: Mmn+Rrp+Al1-xExSiyOz where M is an alkali, alkaline earth, or rare earth metal such as sodium or strontium, R can be a mixture of organoammonium cations and E is a framework element such as gallium, iron, boron, or indium. These zeolites are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes. The diffraction patterns can be characterized by the following table: 2Θ
d(Å)
I/Io 7.92-7.99
11.04-11.31
m 8.79-8.88
 9.94-11.09
m 20.28-20.56
4.31-4.35
w 23.10-23.18
3.83-3.84
vs 23.86-24.05
3.69-3.72
m 29.90-30.05
2.97-2.98
w 45.02-45.17
2.00-2.01
w

公开(公告)号：US20210017392A1

公开(公告)日：2021-01-21

申请号：US17060138

申请日：2020-10-01

申请人： ADMATECHS CO., LTD.

发明人： Shinta HAGIMOTO ,  Nobutaka TOMITA ,  Masaru KURAKI

IPC分类号： C09C1/40 ,  C01B39/20 ,  C01B39/36 ,  C09D11/037

摘要： A filler for resinous composition is contained and used in resinous composition constituting electronic packaging material for electronic device, and includes: a filler ingredient including a crystalline siliceous material with a crystal structure made of at least one member selected from the group consisting of type FAU, type FER, type LTA, type MFI and type CHA, and/or type MWW, wherein: the filler ingredient is free of any activity when evaluated by an “NH3-TPD” method; and includes the crystalline siliceous material in an amount falling in a range allowing the filler ingredient to exhibit a negative thermal expansion coefficient. The filler ingredient may further be free of a surface in which silver, copper, zinc, mercury, tin, lead, bismuth, cadmium, chromium, cobalt and nickel are exposed.

公开(公告)号：US10549267B2

公开(公告)日：2020-02-04

申请号：US16402506

申请日：2019-05-03

申请人： CHIYODA CORPORATION

发明人： Shinya Hodoshima ,  Fuyuki Yagi ,  Azusa Motomiya ,  Shuhei Wakamatsu ,  Sachio Asaoka

IPC分类号： C07C4/06 ,  B01J29/88 ,  B01J29/40 ,  C01B39/06 ,  C07C11/06 ,  B01J29/46 ,  C01B39/46 ,  B01J29/87 ,  B01J37/00 ,  C10G11/05 ,  C01B39/36 ,  B01J35/02 ,  B01J37/10

摘要： Provided are zeolite catalysts that allow reactions to proceed at temperatures as low as possible when lower olefins are produced from hydrocarbon feedstocks with low boiling points such as light naphtha, make it possible to make propylene yield higher than ethylene yield in the production of lower olefins, and have long lifetime. The zeolite catalysts are used in the production of lower olefins from hydrocarbon feedstocks with low boiling points such as light naphtha. The zeolite catalysts are MFI-type crystalline aluminosilicates containing iron atoms and have molar ratios of iron atoms to total moles of iron atoms and aluminum atoms in the range from 0.4 to 0.7. The use of the zeolite catalysts make it possible to increase propylene yield, to lower reaction temperatures, and to extend catalyst lifetime.

公开(公告)号：US10457636B2

公开(公告)日：2019-10-29

申请号：US16318791

申请日：2017-09-07

申请人： Sumitomo Chemical Company, Limited

发明人： Kazuaki Yoshimura ,  Nobufumi Watanabe ,  Kohei Seki ,  Masashi Teramori ,  Keisuke Tanaka

IPC分类号： C07D201/04 ,  C01B39/36 ,  B01J29/40

摘要： A method for producing ε-caprolactam involves a step of Beckmann-rearranging cyclohexanone oxime in a gas phase in the presence of a zeolite catalyst containing silicon and at least one element selected from alkaline earth metal elements and magnesium. The concentration of the above-described element in the zeolite catalyst is 3 ppm by mass or more and 10000 ppm by mass or less.

公开(公告)号：US20190241513A1

公开(公告)日：2019-08-08

申请号：US16318791

申请日：2017-09-07

申请人： Sumitomo Chemical Company, Limited

发明人： Kazuaki YOSHIMURA ,  Nobufumi WATANABE ,  Kohei SEKI ,  Masashi TERAMORI ,  Keisuke TANAKA

IPC分类号： C07D201/04 ,  B01J29/40 ,  C01B39/36

CPC分类号： C07D201/04 ,  B01J29/40 ,  C01B39/36 ,  C07D211/76 ,  Y02P20/52

摘要： A method for producing ε-caprolactam involves a step of Beckmann-rearranging cyclohexanone oxime in a gas phase in the presence of a zeolite catalyst containing silicon and at least one element selected from alkaline earth metal elements and magnesium. The concentration of the above-described element in the zeolite catalyst is 3 ppm by mass or more and 10000 ppm by mass or less.

公开(公告)号：US10336665B2

公开(公告)日：2019-07-02

申请号：US14636541

申请日：2015-03-03

申请人： UOP LLC

发明人： Gregory B. Kuzmanich ,  Jaime G. Moscoso ,  Deng-Yang Jan

IPC分类号： C07C5/27 ,  C07C7/12 ,  C01B39/36 ,  C01B39/40 ,  B01J29/40 ,  B01J29/90 ,  B01J35/00 ,  B01J35/02 ,  B01J35/10

摘要： A process for the production of para-xylene is presented. The process includes the isomerization of C8 aromatics to para-xylene utilizing a new catalyst. The new catalyst is a layer MFI zeolite and is represented by the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of: Mmn+Rrp+AlSiyOz where M is at least one exchangeable cation selected from the group consisting of alkali and alkaline earth metals and R is at least one organoammonium cation.