公开(公告)号：US20090286978A1

公开(公告)日：2009-11-19

申请号：US12120725

申请日：2008-05-15

申请人： Britt A. Minch ,  Charles R. Hickenboth ,  Richard F. Karabin ,  Steven R. Zawacky ,  Thomas R. Hockswender ,  Gregory J. McCollum

发明人： Britt A. Minch ,  Charles R. Hickenboth ,  Richard F. Karabin ,  Steven R. Zawacky ,  Thomas R. Hockswender ,  Gregory J. McCollum

IPC分类号： C07D253/08

CPC分类号： C07D487/04

摘要： The present invention is directed to a method producing bicyclic guanidine comprising heating a cyclic thiourea to a temperature ranging from ≧140° C. in a substantially non-hydrocarbon solvent to form the bicyclic guanidine.

摘要翻译： 本发明涉及一种产生双环胍的方法，其包括在基本上非烃溶剂中加热环状硫脲至> 140℃的温度以形成双环胍。

公开(公告)号：US07619040B2

公开(公告)日：2009-11-17

申请号：US11116706

申请日：2005-04-28

申请人： Steven V. Barancyk ,  Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer

发明人： Steven V. Barancyk ,  Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer

IPC分类号： C08F8/32

CPC分类号： C08F8/00 ,  B05D1/007 ,  B05D3/0209 ,  B05D3/067 ,  B05D7/53 ,  B05D7/57 ,  C08F210/10 ,  C08F220/10 ,  C09D123/22 ,  C08F210/00 ,  C08F220/12 ,  C08L2666/28

摘要： A composition that includes a non-gelled copolymer that contains residues having structural units (I): where n is an integer from 1 to 10,000; R1 is linear or branched C1 to C4 alkyl; R2 is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl, and R3 is a group resulting from a post polymerization reaction selected from transesterification, transamidification and hydrolysis with a compound selected from hydroxy functional compounds and amine functional compounds. The composition may contain co-reactive functional groups and may be a thermosetting composition. A substrate may be coated with the thermosetting composition singly or as part of a multi-layer composite coating that includes a base coat layer and a substantially pigment free top coat layer.

摘要翻译： 包含含有具有结构单元（I）的残基的非胶凝共聚物的组合物：其中n为1至10,000的整数; R1是直链或支链C1-C4烷基; R 2选自甲基，直链，环状或支链C 2至C 20烷基，烯基，芳基，烷芳基和芳烷基，并且R 3是由选择酯交换，转酰胺化和水解的后聚合反应得到的基团， 由羟基官能化合物和胺官能化合物组成。 组合物可以含有共反应性官能团并且可以是热固性组合物。 基材可以单独地涂覆有热固性组合物，或者作为多层复合涂层的一部分，其包括底涂层和基本上不含颜料的顶涂层。

公开(公告)号：US20090020039A1

公开(公告)日：2009-01-22

申请号：US11780867

申请日：2007-07-20

申请人： David Fenn ,  Geoffrey R. Webster ,  Gregory J. McCollum

发明人： David Fenn ,  Geoffrey R. Webster ,  Gregory J. McCollum

IPC分类号： C08L93/04 ,  C08G8/34

CPC分类号： C08L63/00 ,  C08L2666/26

摘要： Modified epoxy resins comprising the reaction product of a cycloaliphatic, polycyclic and/or aromatic biomass derived compound and an epoxy resin are disclosed. Aqueous dispersions and coatings comprising these reaction products are also disclosed.

摘要翻译： 公开了包含脂环族，多环和/或芳族生物质衍生化合物与环氧树脂的反应产物的改性环氧树脂。 还公开了包含这些反应产物的水分散体和涂层。

公开(公告)号：US20080075870A1

公开(公告)日：2008-03-27

申请号：US11839155

申请日：2007-08-15

申请人： Ronald R. Ambrose ,  Anthony M. Chasser ,  Susan F. Donaldson ,  Gregory J. McCollum ,  William H. Retsch

发明人： Ronald R. Ambrose ,  Anthony M. Chasser ,  Susan F. Donaldson ,  Gregory J. McCollum ,  William H. Retsch

IPC分类号： C08J7/04 ,  B32B27/28 ,  C08L83/00

CPC分类号： C09D183/14 ,  C08G59/4085 ,  C09D163/00 ,  C09D183/10

摘要： Disclosed are low temperature, moisture curable coating compositions, related coated substrates, and methods for coating a substrate. The coating compositions include an ungelled, secondary amine-containing Michael addition reaction product of reactants including a compound comprising more than one site of ethylenic unsaturation, and an aminofunctional silane.

公开(公告)号：US20060141143A1

公开(公告)日：2006-06-29

申请号：US11280376

申请日：2005-11-16

申请人： Gregory J. McCollum ,  Thomas C. Moriarity ,  Kevin C. Olson ,  Michael G. Sandala

发明人： Gregory J. McCollum ,  Thomas C. Moriarity ,  Kevin C. Olson ,  Michael G. Sandala

IPC分类号： B05D5/06

CPC分类号： H05K1/056 ,  H05K3/4676 ,  H05K2203/135

摘要： Provided is a method for preparing a circuit assembly. The method includes (a) applying a curable coating composition to a substrate, the curable coating composition formed from (i) one or more active hydrogen-containing resins, (ii) one or more polyester curing agents, and (iii) optionally, one or more transesterification catalysts; (b) curing the curable coating composition to form a coating on the substrate; and (c) applying a conductive layer to the surface of at least part of said cured composition. A circuit assembly prepared by the method also is provided.

摘要翻译： 提供了一种制备电路组件的方法。 该方法包括（a）将可固化涂料组合物施用到基材上，所述可固化涂料组合物由（i）一种或多种含活性氢的树脂，（ii）一种或多种聚酯固化剂，和（iii）任选的一种 或更多的酯交换催化剂; （b）固化可固化涂料组合物以在基材上形成涂层; 和（c）将导电层施加到所述固化的组合物的至少一部分的表面上。 还提供了一种通过该方法制备的电路组件。

公开(公告)号：US06770705B2

公开(公告)日：2004-08-03

申请号：US10361096

申请日：2003-02-06

申请人： Noel R. Vanier ,  Calum H. Munro ,  Gregory J. McCollum ,  James B. O'Dwyer ,  Cynthia Kutchko

发明人： Noel R. Vanier ,  Calum H. Munro ,  Gregory J. McCollum ,  James B. O'Dwyer ,  Cynthia Kutchko

IPC分类号： C08F21604

CPC分类号： C08L33/06 ,  C08K3/22 ,  C08K3/36 ,  C09D7/61 ,  C09D7/67 ,  C09D133/06

摘要： A curable film-forming composition is provided comprising in a medium (i) 10 to 90 percent by weight based on the total weight of solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight based on the total weight of solids in the film-forming composition of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) at least 20 percent by volume based on the total volume of the film-forming composition of particles having a mean particle size less than 100 nm. A cured composition comprising the crosslinking agent of (i) and the polymer of (ii) has a cured softening point of less than 30° C. The particles of component (iii) further have a hardness value greater than 5 on the Moh hardness scale, and have an affinity for the medium sufficient to keep the particles suspended therein. The affinity of the particles for the medium is greater than the affinity of the particles for each other, thereby preventing agglomeration of the particles within the medium. Cured compositions having a film thickness of at least 5 microns demonstrate excellent chip resistance, superior sandability and resistance to scratching, water spotting and acid etch.

摘要翻译： 提供了一种可固化成膜组合物，其包含在基于成膜组合物中交联剂的固体总重量的10至90重量％的介质中（i） （ii）10至90重量％，基于成膜组合物中含有与交联剂反应的多个官能团的聚合物的固体总重量; 和（iii）基于平均粒径小于100nm的成膜组合物的总体积至少20体积％。 包含（i）的交联剂和（ii）的聚合物的固化组合物的固化软化点小于30℃。组分（iii）的颗粒在莫氏硬度标度上还具有大于5的硬度值 并且对于足以使颗粒悬浮在其中的介质具有亲和力。 颗粒对介质的亲和力大于颗粒彼此的亲和力，从而防止颗粒在介质中的团聚。具有至少5微米的膜厚度的组合物表现出优异的耐碎性，优异的耐砂性和耐电性 划伤，水渍和酸蚀。

公开(公告)号：US06686432B2

公开(公告)日：2004-02-03

申请号：US10076984

申请日：2002-02-15

申请人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

发明人： Simion Coca ,  Edward R. Coleridge ,  Gregory J. McCollum ,  James B. O'Dwyer ,  James E. Poole ,  Victoria A. Trettel

IPC分类号： C08F1000

CPC分类号： C09D201/02 ,  C08F8/00 ,  C08F10/00 ,  C08F20/00

摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

公开(公告)号：US06248225B1

公开(公告)日：2001-06-19

申请号：US09309851

申请日：1999-05-11

申请人： Thomas Palaika ,  Ellor J. Van Buskirk ,  Victor G. Corrigan ,  Venkatachalam Eswarakrishnan ,  Gregory J. McCollum ,  Robert R. Zwack ,  Philippe Faucher ,  Craig A. Wilson ,  Chester J. Szymanski ,  James E. Poole ,  Keith S. Ritter ,  Richard F. Syput

发明人： Thomas Palaika ,  Ellor J. Van Buskirk ,  Victor G. Corrigan ,  Venkatachalam Eswarakrishnan ,  Gregory J. McCollum ,  Robert R. Zwack ,  Philippe Faucher ,  Craig A. Wilson ,  Chester J. Szymanski ,  James E. Poole ,  Keith S. Ritter ,  Richard F. Syput

IPC分类号： C25D1312

CPC分类号： C08G18/0814 ,  C08G18/0823 ,  C08G18/8064 ,  C09D5/4465 ,  C09D5/448 ,  C25D13/22 ,  C25D15/00 ,  Y10S524/901

摘要： A process for applying two electrodeposited coatings, one on top of the other, to an electrically conductive substrate is provided. An electrically conductive first coating is applied to provide for corrosion resistance and a second polyurethane-based coating is applied to the first coating to provide chip resistance. Also, aqueous dispersions of the polyurethane coating compositions are disclosed.

摘要翻译： 提供了将两个电沉积涂层（一个在另一个顶部）上施加到导电基底的方法。 施加导电的第一涂层以提供耐腐蚀性，并且将第二聚氨酯基涂层施加到第一涂层以提供耐芯片性。 此外，还公开了聚氨酯涂料组合物的水分散体。

公开(公告)号：US5969058A

公开(公告)日：1999-10-19

申请号：US997284

申请日：1997-12-23

申请人： Lawrence G. Anderson ,  Gerald W. Gruber ,  Kurt A. Humbert ,  Gregory J. McCollum ,  Karen A. Barkac ,  John W. Burgman ,  Robert D. Lippert

发明人： Lawrence G. Anderson ,  Gerald W. Gruber ,  Kurt A. Humbert ,  Gregory J. McCollum ,  Karen A. Barkac ,  John W. Burgman ,  Robert D. Lippert

IPC分类号： C08G59/42 ,  C08G59/68 ,  C09D133/06 ,  C09D163/00 ,  C08F283/00

CPC分类号： C09D133/068 ,  C08G59/42 ,  C08G59/68 ,  C09D163/00

摘要： Curable film-forming compositions containing epoxy functional copolymers, polycarboxylic acid crosslinking agents, and triaryltin compound having the chemical structure of (Ar).sub.3 SnOR wherein the aryl groups are the same or different and at least one aryl group is substituted with at least one atom or group selected from the group consisting of carbon, nitrogen, oxygen, sulfur, phosphorous, silicon and halogen and R is selected from the group consisting of hydrogen, alkyl, and acyl groups are disclosed. The compositions do not release benzene during cure. The compositions may be powder or liquid and are useful as clear coats, particularly in a color-plus-clear composite coating system.

摘要翻译： 含有环氧官能共聚物，多元羧酸交联剂和具有（Ar）3SnOR化学结构的三芳基锡化合物的可固化成膜组合物，其中芳基相同或不同，至少一个芳基被至少一个原子或 选自碳，氮，氧，硫，磷，硅和卤素的基团，R选自氢，烷基和酰基。 组合物在固化过程中不释放苯。 组合物可以是粉末或液体，并且可用作透明涂层，特别是在彩色 - 透明复合涂层体系中。

公开(公告)号：US5767191A

公开(公告)日：1998-06-16

申请号：US700978

申请日：1996-08-21

申请人： Steven R. Zawacky ,  Robert R. Zwack ,  Gregory J. McCollum ,  Venkatachalam Eswarakrishnan ,  Edward R. Coleridge

发明人： Steven R. Zawacky ,  Robert R. Zwack ,  Gregory J. McCollum ,  Venkatachalam Eswarakrishnan ,  Edward R. Coleridge

IPC分类号： C09D175/04 ,  C08G18/16 ,  C08G18/80 ,  C09D5/44 ,  C25D13/06 ,  C08J3/00 ,  C08K3/20 ,  C08L63/00 ,  C08L75/00

CPC分类号： C08G18/161 ,  C09D5/4492

摘要： An improved electrodepositable composition is provided comprising: (a) an active hydrogen-containing cationic resin electrodepositable on a cathode; (b) a capped polyisocyanate curing agent; and (c) an organotin-containing catalyst. The improvement comprises the addition to the electrodepositable composition of a water immiscible acid functional compound having a hydrocarbon chain of at least 5 carbon atoms like abietic acid and natural sources thereof. A preferred acid functional compound is abietic acid. The composition provides improved cure response and appearance properties when electrodeposited over conductive substrates.

摘要翻译： 提供了一种改进的可电沉积组合物，其包括：（a）可阴极沉积的含活性氢的阳离子树脂; （b）封端的多异氰酸酯固化剂; 和（c）含有机锡的催化剂。 改进之处在于向可电沉积组合物中加入具有至少5个碳原子的烃链，如松香酸及其天然来源的水不混溶的酸官能化合物。 优选的酸官能化合物是松香酸。 当电沉积在导电基底上时，组合物提供改善的固化反应和外观性能。