公开(公告)号：US10184022B2

公开(公告)日：2019-01-22

申请号：US15435035

申请日：2017-02-16

Applicant: HEXION INC.

Inventor： Adam Daniel Dowden ,  Harden Christopher Wren ,  Todd Ross Miller

IPC: C08G16/02 ,  C08L97/00 ,  D21H17/58 ,  C08H7/00 ,  C08L61/00 ,  C08L61/34

Abstract: Polymeric materials and methods for making the polymeric materials utilizing bisphenolic stillbottoms, lignosulfonates, or both are disclosed. In one embodiment, a polymer is provided that includes a condensate of bisphenolic stillbottoms, an optional phenolic compound independent of bisphenolic stillbottoms, an aldehyde, and a lignosulfonate compound. The condensate may further include an amino compound, a catalyst, or combinations thereof. Alternatively, the polymer may be free of a phenolic compound independent of bisphenolic stillbottoms. The polymers may be used in the manufacture of articles including composites, laminates and paper products.

公开(公告)号：US20180298137A9

公开(公告)日：2018-10-18

申请号：US15435035

申请日：2017-02-16

Applicant: HEXION INC.

Inventor： Adam Daniel DOWDEN ,  Harden Christopher WREN ,  Todd Ross MILLER

IPC: C08G16/02 ,  C08L61/34 ,  C08L97/00 ,  D21H17/58

CPC classification number: C08G16/0237 ,  C08H6/00 ,  C08L61/00 ,  C08L61/34 ,  C08L97/005 ,  C08L2205/025 ,  D21H17/58

Abstract: Polymeric materials and methods for making the polymeric materials utilizing bisphenolic stillbottoms, lignosulfonates, or both are disclosed. In one embodiment, a polymer is provided that includes a condensate of bisphenolic stillbottoms, an optional phenolic compound independent of bisphenolic stillbottoms, an aldehyde, and a lignosulfonate compound. The condensate may further include an amino compound, a catalyst, or combinations thereof. Alternatively, the polymer may be free of a phenolic compound independent of bisphenolic stillbottoms. The polymers may be used in the manufacture of articles including composites, laminates and paper products.

公开(公告)号：US10040896B2

公开(公告)日：2018-08-07

申请号：US14863054

申请日：2015-09-23

Applicant: Hexion Inc.

Inventor： Antonina Nikitenko ,  Matthew Pinnow ,  Amitabh Bansal

IPC: C08G59/14 ,  C08L63/00 ,  C09D163/00 ,  C08G18/58 ,  C07F7/18

Abstract: Compositions comprising Silane functionalized compounds are provided. In one embodiment, the silane functionalized compounds include an epoxy resin derived backbone having silane functional groups pendant to the backbone or serving as end caps. The compositions comprising silane functionalized compounds may be utilized in a variety of applications including in coating formulations, adhesive formulations, composite materials, and combinations thereof.

公开(公告)号：US20170298260A1

公开(公告)日：2017-10-19

申请号：US15486998

申请日：2017-04-13

Applicant: Hexion Inc.

Inventor： Jaworski C. CAPRICHO ,  Karen Theresa LOVE ,  Alex BRUCE ,  Gary BYROM ,  Robert B. CURRIE

IPC: C09J161/06 ,  C09J5/00 ,  C08K3/00 ,  C08K5/55

CPC classification number: C09J161/06 ,  C08K3/013 ,  C08K5/55 ,  C08K2003/265 ,  C09J5/00 ,  C09J2401/006 ,  C09J2461/00 ,  C08K3/26 ,  C08L3/04

Abstract: Complexes, compositions, articles of manufacture, and method for making the same are provided herein. In one embodiment, a borate-polyol complex may be prepared by reacting a boron-containing compound and a polyol to form a reaction mixture and then neutralizing the reaction mixture to form a neutralized borate-polyol complex. The neutralized borate-polyol complex may then be used in combination with polymeric resins to form adhesive products, among other material products, which products can be in manufacturing articles.

公开(公告)号：US09598580B2

公开(公告)日：2017-03-21

申请号：US14642285

申请日：2015-03-09

Applicant: Hexion Inc.

Inventor： Adam Daniel Dowden ,  Harden Christopher Wren ,  Todd Ross Miller

IPC: C08G14/04 ,  C08L97/00 ,  C08G16/02 ,  D21H17/58 ,  C08H7/00 ,  C08L61/00

CPC classification number: C08G16/0237 ,  C08H6/00 ,  C08L61/00 ,  C08L61/34 ,  C08L97/005 ,  C08L2205/025 ,  D21H17/58

Abstract: Polymeric materials and methods for making the polymeric materials utilizing bisphenolic stillbottoms, lignosulfonates, or both are disclosed. In one embodiment, a polymer is provided that includes a condensate of bisphenolic stillbottoms, an optional phenolic compound independent of bisphenolic stillbottoms, an aldehyde, and a lignosulfonate compound. The condensate may further include an amino compound, a catalyst, or combinations thereof. Alternatively, the polymer may be free of a phenolic compound independent of bisphenolic stillbottoms. The polymers may be used in the manufacture of articles including composites, laminates and paper products.

公开(公告)号：US20170051119A1

公开(公告)日：2017-02-23

申请号：US15336503

申请日：2016-10-27

Applicant: Hexion Inc.

Inventor： Larry Steven CORLEY ,  Robert Dale Farris ,  Carlton E. Ash

IPC: C08J5/04 ,  C08G59/24 ,  C08G59/62 ,  C08J5/24

CPC classification number: C08J5/042 ,  B32B27/04 ,  B32B27/38 ,  C08G59/063 ,  C08G59/245 ,  C08G59/621 ,  C08J5/04 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/02 ,  C08J2363/04 ,  C08L63/00 ,  C08L63/04

Abstract: Compositions and methods for forming epoxy resin are provided, and compositions and methods for forming epoxy resin composites are provided. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component comprising a glycidyl ether of an aryl substituted phenolic compound, a curing agent component, and a substrate. In one embodiment, a composite comprises an epoxy resin composition comprising an epoxy resin component and a curing agent component comprising an aryl substituted phenolic compound, and a substrate.

Abstract translation: 提供了用于形成环氧树脂的组合物和方法，并且提供了用于形成环氧树脂复合材料的组合物和方法。 在一个实施方案中，复合材料包含环氧树脂组合物，其包含环氧树脂组分，其包含芳基取代的酚类化合物的缩水甘油醚，固化剂组分和底物。 在一个实施方案中，复合材料包含环氧树脂组合物，其包含环氧树脂组分和包含芳基取代的酚类化合物的固化剂组分和底物。

公开(公告)号：US09550894B2

公开(公告)日：2017-01-24

申请号：US14610852

申请日：2015-01-30

Applicant: Hexion Inc.

Inventor： Yingchao Zhang ,  Raman C. Subrayan ,  Vinay Malhotra ,  David A. Snover

IPC: C08L67/00 ,  C08L29/04 ,  C08K5/07 ,  C08L33/26 ,  C08L33/06 ,  C03C25/32 ,  C03C25/10 ,  D06M13/224 ,  D04H1/64 ,  D04H1/587 ,  D04H13/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/08 ,  C03C25/24

CPC classification number: C08L67/00 ,  C03C25/1095 ,  C03C25/24 ,  C03C25/323 ,  C08K5/07 ,  C08L29/04 ,  C08L33/00 ,  C08L33/02 ,  C08L33/08 ,  C08L33/26 ,  D04H1/587 ,  D04H1/64 ,  D04H13/00 ,  D06M13/224 ,  Y10T442/2779 ,  Y10T442/2787 ,  Y10T442/2811 ,  Y10T442/2844 ,  Y10T442/2861 ,  Y10T442/2934 ,  Y10T442/2967 ,  Y10T442/2992

Abstract: Polyester materials, methods for making polyesters materials, and uses of the polyester materials in binder materials and articles of manufacture are disclosed. In one embodiment, a process is provided for preparing a polyester solution, including mixing monomers of at least one organic acid containing at least three carboxylic groups and at least one multi-hydroxyl alcohol containing at least three hydroxyl groups to form a reaction mixture, heating the reaction mixture to a first temperature, polymerizing the monomers at the first temperature until reaching an acid value from about 200 to about 400 mg KOH/g, adjusting the temperature to a second temperature less than the first temperature, and forming the polyester solution. The polyester materials may be mixed with cross-linking materials to form binder materials. The binder material may then be used to form articles of manufacture.

Abstract translation: 公开了聚酯材料，聚酯材料的制备方法以及聚酯材料在粘合剂材料和制品中的应用。 在一个实施方案中，提供了制备聚酯溶液的方法，包括混合至少一种含有至少三个羧基的有机酸的单体和至少含有至少三个羟基的多羟基醇以形成反应混合物，加热 将反应混合物转化为第一温度，在第一温度下聚合单体，直到达到约200至约400mg KOH / g的酸值，将温度调节至低于第一温度的第二温度，并形成聚酯溶液。 聚酯材料可以与交联材料混合以形成粘合剂材料。 然后可以将粘合剂材料用于形成制品。

公开(公告)号：US09499672B2

公开(公告)日：2016-11-22

申请号：US14943943

申请日：2015-11-17

Applicant: Hexion Inc.

Inventor： Yingchao Zhang ,  David A. Snover

IPC: C08G63/48 ,  C08F8/00 ,  C08G81/02 ,  C08F16/06 ,  C08F8/30 ,  C08L61/24

CPC classification number: C08G81/024 ,  C08F8/30 ,  C08F16/06 ,  C08G12/12 ,  C08L61/24 ,  C08L2201/56 ,  C08L2312/04 ,  C08L29/04

Abstract: The mechanical properties of urea formaldehyde resins may be improved by incorporating therein polyvinyl alcohol. The polyvinyl alcohol may be incorporated during pre-mixing, mid mixing, and/or post mixing of the resin components. Resins prepared using polyvinyl alcohol are particularly desirable in articles requiring improved mechanical strength and water resistance, as compared to similar resins prepared without the polyvinyl alcohol such as shingles.

公开(公告)号：US09404025B1

公开(公告)日：2016-08-02

申请号：US14256950

申请日：2014-04-19

Applicant: Hexion Inc.

Inventor： Ivan E. Holte

IPC: C09J161/24 ,  C09J103/00 ,  C09J189/00

CPC classification number: C09J161/24 ,  C08L3/02 ,  C08L61/24 ,  C08L89/00 ,  C08L97/02 ,  C09J103/00 ,  C09J103/02 ,  C09J189/00

Abstract: An adhesive composition for manufacturing a composite wood product comprising an aqueous network of a formaldehyde condensation resin, wheat flour, and wheat gluten, said adhesive composition having a density less than water and is non-thixotropic. The composition is prepared by subjecting an aqueous formaldehyde condensation resin, wheat flour and wheat gluten to an intense high shear.

Abstract translation: 一种用于制造复合木制品的粘合剂组合物，其包含甲醛缩合树脂，小麦粉和小麦面筋的水性网络，所述粘合剂组合物的密度小于水并且是非触变性的。 通过使甲醛缩合树脂，小麦粉和小麦面筋水溶液进行强烈的高剪切力制备组合物。

公开(公告)号：US20160168306A1

公开(公告)日：2016-06-16

申请号：US14973265

申请日：2015-12-17

Applicant: Hexion Inc.

Inventor： Ganapathy S. VISWANATHAN ,  Vinay MALHOTRA

IPC: C08G14/10 ,  C08L63/00 ,  C08K5/05

CPC classification number: C08G14/10 ,  C08G59/623 ,  C08G59/68 ,  C08K5/05 ,  C08L61/34 ,  C08L63/00 ,  C08L63/04

Abstract: Compositions and methods for forming condensates and resin compositions are provided. In one embodiment, a condensate is formed from a reaction mixture including a triazine monomer, an arylhydroxy monomer, an aldehyde monomer and an acid catalyst having a pKa value of greater than 3.8. The condensates contain up to 28 wt. % of nitrogen and have a melt viscosity of 3,000 cps or less at 175° C. The condensates may have a solubility of at least 80 wt. % solids dissolved in an organic solvent for 120 hours or greater. Also disclosed are methods for the manufacture of the condensate as well as the condensate's use in fire-retardant epoxy resin compositions suitable for the manufacture of laminates for electronic applications. There is also disclosed a glycidylated triazine-arylhydroxy-aldehyde condensate of this invention.

Abstract translation: 提供了用于形成冷凝物和树脂组合物的组合物和方法。 在一个实施方案中，由包含三嗪单体，芳基羟基单体，醛单体和pKa值大于3.8的酸催化剂的反应混合物形成冷凝物。 冷凝物含有高达28wt。 ％的氮，并且在175℃下的熔融粘度为3,000cps以下。冷凝物的溶解度可以至少为80wt。 溶于有机溶剂中的固体固体含量为120小时或更长。 还公开了用于制造冷凝物的方法以及冷凝物在适用于制造用于电子应用的层压材料的阻燃环氧树脂组合物中的用途。 还公开了本发明的缩水甘油基三嗪 - 芳基羟基 - 醛缩合物。