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    Hydroconversion process for petroleum resids using selective membrane separation followed by hydroconversion over carbon supported metal catalyst
    11.
    发明授权
    Hydroconversion process for petroleum resids using selective membrane separation followed by hydroconversion over carbon supported metal catalyst 有权
    使用选择性膜分离，然后在碳负载金属催化剂上加氢转化，石油渣的加氢转化法

    公开(公告)号：US07943037B2

    公开(公告)日：2011-05-17

    申请号：US12073844

    申请日：2008-03-11

    Applicant: Martin L. Gorbaty ,  David T. Ferrughelli ,  Edward W. Corcoran ,  Stephen M. Cundy

    Inventor： Martin L. Gorbaty ,  David T. Ferrughelli ,  Edward W. Corcoran ,  Stephen M. Cundy

    IPC: C10G47/02 ,  C07C7/144

    CPC classification number: C10G67/02 ,  C10G65/14 ,  C10G69/14

    Abstract: A heavy residual petroleum feed boiling above 650° F.+ (345° C.+) is subjected to membrane separation to produce a produce a permeate which is low in metals and Microcarbon Residue (MCR) as well as a retentate, containing most of the MCR and metals, the retentate is then subjected to hydroconversion at elevated temperature in the presence of hydrogen at a hydrogen pressure not higher than 500 psig (3500 kPag) using a dispersed metal-on-carbon catalyst to produce a hydroconverted effluent which is fractionated to give naphtha, distillate and gas oil fractions. The permeate from the membrane separation may be used as FCC feed either as such or with moderate hydrotreatment to remove residual heteroatoms. The process has the advantage that the hydroconversion may be carried out in low pressure equipment with a low hydrogen consumption as saturation of aromatics is reduced.

    Abstract translation: 将高于650°F +（345°C +）沸腾的重残余石油原料进行膜分离以产生低金属和微量残渣（MCR）的渗透物以及含有大部分 MCR和金属，然后使用分散的金属对碳催化剂在氢气压力不高于500psig（3500kPag）的氢气存在下，在升高的温度下对渗余物进行加氢转化，以产生分级的加氢转化的流出物 得到石脑油，馏出物和瓦斯油馏分。 来自膜分离的渗透物可以如本文使用或作为FCC进料或中等加氢处理以除去残留的杂原子。 该方法的优点是可以在具有低氢消耗的低压设备中进行加氢转化，从而降低芳族化合物的饱和度。

    Process for flexible vacuum gas oil conversion
    12.
    发明申请
    Process for flexible vacuum gas oil conversion 有权
    柔性真空瓦斯油转化工艺

    公开(公告)号：US20100018895A1

    公开(公告)日：2010-01-28

    申请号：US12459729

    申请日：2009-07-07

    Applicant: Martin L. Gorbaty ,  Bruce R. Cook ,  David T. Ferrughelli ,  Jason B. English ,  Steven S. Lowenthal

    Inventor： Martin L. Gorbaty ,  Bruce R. Cook ,  David T. Ferrughelli ,  Jason B. English ,  Steven S. Lowenthal

    IPC: C10G69/04 ,  C10G47/00

    CPC classification number: C10G69/06 ,  C10G11/18 ,  C10G51/04 ,  C10G69/02 ,  C10G69/04 ,  C10G2300/1074 ,  C10G2300/4081 ,  C10G2400/02

    Abstract: The present invention relates to a process for the selective conversion of hydrocarbon feed having a Conradson Carbon Residue content of 0 to 6 wt %, based on the hydrocarbon feed. The hydrocarbon feed is treated in a two-step process. The first is thermal conversion and the second is catalytic cracking of the products of the thermal conversion. The present invention results in a process for increasing the distillate production from a hydrocarbon feedstream for a fluid catalytic cracking unit. The resulting product slate from the present invention can be further varied by changing the conditions in the thermal and catalytic cracking steps as well as by changing the catalyst in the cracking step.

    Abstract translation: 本发明涉及一种基于烃进料选择性转化具有0至6重量％的康拉德森碳残余物的烃进料的方法。 烃进料以两步法处理。 第一种是热转化，第二种是热转化产物的催化裂化。 本发明导致用于增加用于流化催化裂化装置的烃进料流的馏出物生产的方法。 通过改变热和催化裂化步骤的条件以及通过改变裂化步骤中的催化剂，可进一步改变本发明产生的产品板条。

    Hydroconversion process for petroleum resids by hydroconversion over carbon supported metal catalyst followed by selective membrane separation
    13.
    发明申请
    Hydroconversion process for petroleum resids by hydroconversion over carbon supported metal catalyst followed by selective membrane separation 有权
    通过在碳负载的金属催化剂上加氢转化，然后进行选择性膜分离，石油的加氢转化方法残留

    公开(公告)号：US20090234166A1

    公开(公告)日：2009-09-17

    申请号：US12073843

    申请日：2008-03-11

    Applicant: Martin L. Gorbaty ,  David T. Ferrughelli ,  Edward W. Corcoran ,  Stephen M. Cundy ,  Andrew Kaldor

    Inventor： Martin L. Gorbaty ,  David T. Ferrughelli ,  Edward W. Corcoran ,  Stephen M. Cundy ,  Andrew Kaldor

    IPC: C07C5/00

    CPC classification number: C10G47/12 ,  C10G2300/107

    Abstract: A heavy residual petroleum feed boiling above 650° F.+ (345° C.+) is subjected to hydroconversion at elevated temperature in the presence of hydrogen at a hydrogen pressure not normally higher than 500 psig (3500 kPag) using a dispersed metal-on-carbon catalyst to produce a hydroconverted effluent which is fractionated to form a low boiling fraction and a relatively higher boiling fraction which is subjected to membrane separation to produce a permeate which is low in metals and Microcarbon Residue (MCR) as well as a retentate, containing most of the MCR and metals. The process has the advantage that the hydroconversion may be carried out in low pressure equipment with a low hydrogen consumption as saturation of aromatics is reduced.

    Abstract translation: 在氢气存在下，在通常不高于500psig（3500kPag）的氢气压力下，在高温下在高于650°F +（345℃+）下沸腾的重残余石油原料进行加氢转化， 碳酸催化剂以产生加氢转化的流出物，其被分馏以形成低沸点馏分和相对较高沸点馏分，其进行膜分离以产生低金属和微碳残余物（MCR）的渗透物以及滞留物 ，含有大部分MCR和金属。 该方法的优点是可以在具有低氢消耗的低压设备中进行加氢转化，从而降低芳族化合物的饱和度。

    Process for removal of heteroatoms under reducing conditions in supercritical water
    14.
    发明授权
    Process for removal of heteroatoms under reducing conditions in supercritical water 失效
    在超临界水中还原条件下去除杂原子的方法

    公开(公告)号：US5611915A

    公开(公告)日：1997-03-18

    申请号：US583692

    申请日：1996-01-05

    Applicant: Michael Siskin ,  David T. Ferrughelli ,  Alan R. Katritzky ,  William N. Olmstead

    Inventor： Michael Siskin ,  David T. Ferrughelli ,  Alan R. Katritzky ,  William N. Olmstead

    IPC: C07B37/00 ,  C07C1/00 ,  C07C1/32 ,  C07C15/02 ,  C10G1/00 ,  C10G1/04 ,  C10G1/06

    CPC classification number: C07C1/322 ,  C07C1/323 ,  C10G1/00 ,  Y02P20/544 ,  Y10S208/952

    Abstract: A process for heteroatom removal-enhancing hydrogenation of highly refractory aromatic ring structures that involves contacting a highly refractory structure having at least one aryl linkage connecting a first heteroaryl moiety and a moiety selected from the group consisting of an aryl moiety and a second heteroaryl moiety with supercritical water having a temperature of from about 400.degree. C. to about 600.degree. C. in the presence of from about 3.4 MPa to about 18.6 MPa of CO to produce lower molecular weight products having decreased aromatic and heteroatom content. The process has utility for producing more valuable lower molecular weight products having a reduced aromatic heteroatom content from starting materials that are highly refractory and widely considered to be difficult to upgrade such as coals and asphaltenes, and model compounds containing the biaryl linkages.

    Abstract translation: 使高难度芳族环结构的杂原子去除增强氢化的方法包括将具有至少一个连接第一杂芳基部分的芳基与选自芳基部分和第二杂芳基部分的部分的至少一个芳基键接触的高度耐火结构与 在约3.4MPa至约18.6MPa的CO存在下，温度为约400℃至约600℃的超临界水，以产生具有降低的芳族和杂原子含量的较低分子量产物。 该方法可用于生产具有降低的芳族杂原子含量的低价分子量产物，所述低分子量产物具有高度耐火且被广泛认为难以升级的起始材料，例如煤和沥青质，以及含有联芳基键的模型化合物。

    Delayed coking process
    18.
    发明授权
    Delayed coking process 失效
    延迟焦化工艺

    公开(公告)号：US08147676B2

    公开(公告)日：2012-04-03

    申请号：US11256728

    申请日：2005-10-21

    Applicant: Michael Siskin ,  David T. Ferrughelli ,  Martin L. Gorbaty ,  Simon R. Kelemen ,  Leo D. Brown

    Inventor： Michael Siskin ,  David T. Ferrughelli ,  Martin L. Gorbaty ,  Simon R. Kelemen ,  Leo D. Brown

    IPC: C10B55/00

    CPC classification number: C10B57/06 ,  C10B55/00 ,  C10B57/08 ,  C10G9/005 ,  C10G55/04 ,  C10G2300/107 ,  C10G2300/1077 ,  C10G2300/202 ,  C10G2300/206

    Abstract: The present invention relates to an improved delayed coking process. A coker feed, such as a vacuum resid, is treated with (i) a metal-containing agent and (ii) an oxidizing agent. The feed is treated with the oxidizing agent at an oxidizing temperature. The oxidized feed is then pre-heated to coking temperatures and conducted to a coking vessel for a coking time to allow volatiles to evolve and to produce a substantially free-flowing coke. A metals-containing composition is added to the feed at at least one of the following points in the process: prior to the heating of the feed to coking temperatures, during such heating, and/or after such heating.

    Abstract translation: 本发明涉及一种改进的延迟焦化方法。 用（i）含金属试剂和（ii）氧化剂处理焦化饲料如真空渣油。 在氧化温度下用氧化剂处理进料。 然后将氧化的进料预加热至焦化温度，并导入焦化容器中以获得焦化时间，以允许挥发物放出并产生基本上自由流动的焦炭。 在此过程中，将进料加热至焦化温度，在此加热期间和/或在此类加热之后，将含金属的组合物加入到进料中的至少一个方面。

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