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    Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin
    11.
    发明授权
    Quaternized polymer for use as a cosmetic agent in cosmetic compositions for the hair and skin 失效
    用作头发和皮肤的化妆品组合物中的化妆品的季铵化聚合物

    公开(公告)号：US5196189A

    公开(公告)日：1993-03-23

    申请号：US897483

    申请日：1992-06-12

    Applicant: Bernard Jacquet ,  Gerard Lang

    Inventor： Bernard Jacquet ,  Gerard Lang

    IPC: A01N33/12 ,  A61K8/04 ,  A61K8/41 ,  A61K8/84 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/08 ,  A61Q5/10 ,  A61Q15/00 ,  C08G73/02

    CPC classification number: C08G73/0226 ,  A01N33/12 ,  A61K8/046 ,  A61K8/416 ,  A61K8/84 ,  A61Q15/00 ,  A61Q5/02 ,  A61Q5/04 ,  A61Q5/06 ,  A61Q5/08 ,  A61Q5/10 ,  C08G73/02 ,  C08G73/024 ,  C08G73/0253 ,  A61K2800/5426 ,  Y10S514/845 ,  Y10S514/846

    Abstract: A quaternized polymer for use as a cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing a maximum of 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is a divalent group selected from ##STR2## wherein x, y and t are whole numbers ranging from 0 to 11 such that the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,--(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --, (3)--(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --, (4)--(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --, (5)--(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --, (6)--(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.n --and (7) ##STR3## wherein n is equal to 2 or 3; B represents a divalent group selected from ##STR4## wherein D and G represent hydrogen or an aliphatic radical having less than 18 carbon atoms and v, z and u are whole numbers ranging from 0 to 11, with two of v, z and u simultaneously being capable of being 0, such that the sum (v+z+u) is greater than or equal to 1 and lower than 18 and such that the sum (v+z+u) is greater than 1 when the sum (x+y+t) is equal to 0, ##STR5## wherein n is 2 or 3; and X.sup..crclbar. is an anion derived from an organic or mineral acid. The quaternized polymer is employed in cosmetic compositions for the hair and skin.

    Abstract translation: 用作化妆剂的季铵化聚合物具有下式的重复单元：其中R是低级烷基或-CH 2 -CH 2 OH; R'是含有最多20个碳原子的脂族，脂环族或芳基脂族基团，或者R和R'与它们所连接的氮原子一起形成能够含有氮以外的杂原子的杂环; A是选自式（1）的邻 - ，间 - 或对 - 亚二甲苯基的二价基团，其中x，y和t是0〜11的整数，使得（ x + y + t）大于或等于0并且低于18，并且E和K表示氢或具有少于18个碳原子的脂族基团， - （CH 2）n -S-（CH 2）n - ， 3） - （CH 2）n O-（CH 2）n - ，（4） - （CH 2）nSS-（CH 2）n - ，（5） - （CH 2）n -SO-（CH 2） （CH 2）n -SO 2 - （CH 2）n - 和（7）其中n等于2或3; B表示选自式（1）的邻 - ，间 - 或对 - 亚二甲苯基的二价基团，其中D和G表示氢或具有少于18个碳原子的v的脂族基团， z和u是从0到11的整数，其中v，z和u中的两个同时能够为0，使得和（v + z + u）大于或等于1并且低于18， （x + y + t）等于0时，总和（v + z + u）大于1，其中n（x） 是2或3; 而X（ - ）是衍生自有机或无机酸的阴离子。 季铵化聚合物用于头发和皮肤的化妆品组合物中。

    Cosmetic temporary coloring compositions containing protein derivatives
    12.
    发明授权
    Cosmetic temporary coloring compositions containing protein derivatives 失效
    含有蛋白质衍生物的化妆品临时着色剂

    公开(公告)号：US5192332A

    公开(公告)日：1993-03-09

    申请号：US771478

    申请日：1991-10-07

    Applicant: Gerard Lang ,  Serge Forestier ,  Gerard Malle ,  Alex Junino

    Inventor： Gerard Lang ,  Serge Forestier ,  Gerard Malle ,  Alex Junino

    IPC: A61K8/64 ,  A61K8/65 ,  A61Q1/06 ,  A61Q5/06 ,  A61Q5/10 ,  A61Q19/04

    CPC classification number: A61K8/645 ,  A61K8/64 ,  A61K8/65 ,  A61Q1/06 ,  A61Q19/04 ,  A61Q5/06 ,  A61Q5/10 ,  A61K2800/43 ,  A61K2800/57

    Abstract: The present invention provides a cosmetic temporary coloring composition which comprises a cosmetically acceptable support and, as an active ingredient, at least one chemically modified protein derivative which contains residues of molecules of dye grafted onto the protein chain. Thus, certain of the side chains of the protein derivative having amine, alcohol or thiol functions are substituted by residues of dye molecules. The present invention further provides a process for the temporary coloring of human hair, nails or skin comprising applying thereto in an amount effective to color the human hair, nails or skin a composition containing a solution in water, a lower mono-alcohol or polyol or an aqueous alcoholic mixture wherein the alcohol is present in an amount ranging from 0.5 to 50 percent by weight of the chemically modified protein derivative.

    Abstract translation: 本发明提供了一种化妆品临时着色组合物，其包含化妆品可接受的载体和作为活性成分的至少一种化学修饰的蛋白质衍生物，其含有接枝到蛋白质链上的染料分子的残基。 因此，具有胺，醇或硫醇官能团的蛋白质衍生物的某些侧链被染料分子的残基取代。 本发明还提供了一种用于临时着色人发，指甲或皮肤的方法，其包括以有效使人头发，指甲或皮肤着色的组合物施用于含有水溶液，低级单醇或多元醇的组合物或 醇的混合物，其中所述醇的存在量为所述化学修饰的蛋白质衍生物的0.5至50重量％。

    Process for dyeing keratinous fibres combining isatin or its derivatives with an aminoindole or an aminoindoline, and compositions used
    13.
    发明授权
    Process for dyeing keratinous fibres combining isatin or its derivatives with an aminoindole or an aminoindoline, and compositions used 失效
    用氨基酸或氨基吲哚组合ISATIN或其衍生物的KERATINOUS纤维的染色方法和使用的组合物

    公开(公告)号：US5190564A

    公开(公告)日：1993-03-02

    申请号：US828299

    申请日：1992-01-30

    Applicant: Gerard Lang ,  Jean Cotteret

    Inventor： Gerard Lang ,  Jean Cotteret

    IPC: A61K8/00 ,  A61K8/25 ,  A61K8/34 ,  A61K8/37 ,  A61K8/49 ,  A61K8/73 ,  A61K8/97 ,  A61Q5/10

    CPC classification number: A61Q5/10 ,  A61K8/492

    Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the simultaneous or sequential application of a composition (A) containing a compound of formula (I): ##STR1## in which: R.sub.1 denotes hydrogen, alkyl, acetyl, benzoyl, phenyl or C.sub.1 -C.sub.4 carboxyalyl (sic);R.sub.2 and R.sub.3 denote hydrogen, alkyl, alkoxy, hydroxyalkyl, amino, halogen, nitro, alkylphenyl, phenyl, alkylamino, hydroxyalkylamino;and a composition (B) containing at least one compound of formula (II): ##STR2## in which: R.sub.4 and R.sub.6 denote hydrogen, alkyl;R.sub.5 denotes hydrogen, alkyl, COOR' where R' is hydrogen or alkyl;Z.sub.1 represents hydrogen, halogen, alkyl, alkoxy or hydroxyl;Z.sub.2 represents hydrogen or alkyl or a compound of formula (III): ##STR3## in which: R.sub.7 and R.sub.8 denote hydrogen or alkyl;X.sub.1 and X.sub.2 represent hydrogen or an NH.sub.2 radical;R.sub.9 denotes hydrogen, alkyl, alkoxy;as well as the compositions used.

    Abstract translation: 本发明涉及染色角质纤维的方法，包括同时或顺序施用含有式（I）化合物的组合物（A）：其中：R 1表示氢，烷基，乙酰基，苯甲酰基 ，苯基或C 1 -C 4羧酰基（sic）; R2和R3表示氢，烷基，烷氧基，羟基烷基，氨基，卤素，硝基，烷基苯基，苯基，烷基氨基，羟基烷基氨基; 和含有至少一种式（II）的化合物的组合物（B）：其中：R 4和R 6表示氢，烷基; R5表示氢，烷基，COOR'，其中R'是氢或烷基; Z1表示氢，卤素，烷基，烷氧基或羟基; Z 2表示氢或烷基或式（III）化合物：其中：R7和R8表示氢或烷基; X1和X2表示氢或NH2基团; R9表示氢，烷基，烷氧基; 以及所用的组合物。

    3-substituted para-amino phenols and their use as oxidation dye precursors in compositions for dyeing kerafinous fibers
    15.
    发明授权
    3-substituted para-amino phenols and their use as oxidation dye precursors in compositions for dyeing kerafinous fibers 失效
    3-取代的PARA-AMINO PHENOLS及其作为氧化染料前体在组合物中的用途，用于染色KERAFINOUS FIBERS

    公开(公告)号：US5084067A

    公开(公告)日：1992-01-28

    申请号：US316921

    申请日：1989-02-28

    Applicant: Alex Junino ,  Alain Genet ,  Gerard Lang

    Inventor： Alex Junino ,  Alain Genet ,  Gerard Lang

    IPC: A61K8/00 ,  A61K8/33 ,  A61K8/40 ,  A61K8/41 ,  A61K8/46 ,  A61K8/49 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/26 ,  C07C217/84 ,  C07C323/36 ,  D06P3/00

    CPC classification number: A61K8/415 ,  A61Q5/10 ,  C07C205/37 ,  C07C217/84 ,  C07C323/36

    Abstract: 3-Substituted para-aminophenols of general formula: ##STR1## where X.dbd.H, halogen; Y.dbd.O--, --S--; R.dbd.alkyl, hydroxyalkyl, C.sub.1-4 aminoalkyl or C.sub.3 -C.sub.6 polyhydroxyalkyl;with the proviso that, when X.dbd.H, R is not methyl, and when X.dbd.H and Y.dbd.O, R is not ethyl;process for preparing them, intermediate compounds of formula: ##STR2## where X.sub.1 =halogen, Y and R have the meaning stated above; with the proviso that, when Y.dbd.O, R is not methyl, and when R=aminoalkyl, X.sub.1 can also denote hydrogen;dyeing compositions containing one or more compounds of formula (I), and a process for dyeing human hair.

    Abstract translation: 3-取代的对位氨基苯酚，其通式如下：其中X = H，卤素; Y = O-，-S-; R =烷基，羟基烷基，C 1-4氨基烷基或C 3 -C 6多羟基烷基; 条件是当X = H时，R不是甲基，当X = H且Y = O时，R不是乙基; 制备它们的方法，式中的中间体化合物：其中X1 =卤素，Y和R具有上述含义; 条件是当Y = O时，R不是甲基，当R =氨基烷基时，X1也可以表示氢; 含有一种或多种式（I）化合物的染色组合物和染发人发的方法。

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