Abstract:
The invention relates to a gravure printing ink and a method of multi-color gravure printing on flexible substrates with liquid radiation curable inks. Individual colors are transferred via direct contact between engraved gravure cylinder and a substrate. Each color is dried such that the sequentially printed ink layers transfer through the press without distortion of the printed image during multiple web turns around turn bars. Finally the printed substrate is cured by exposing an electron beam unit. The gravure printing ink comprises an admixture of a) a water dispersible pigment; b) a water dispersible, ethylenically unsaturated monomer, ethylenically unsaturated oligomer or ethylenically unsaturated polymer which is polymerizable or crosslinkable by the application of sufficient electron beam radiation; c) a defoaming agent; d) sufficient water to form a dispersion with components a), b) and c), which dispersion has a viscosity of from about 25 cps to about 200 cps.
Abstract:
A liquid composition and a process for coating the composition onto a surface of a substrate in a substantially oxygen-free atmosphere, under vacuum conditions. The composition comprises one or more components, all of which components do not go into a gas or vapor phase under the vacuum conditions. The composition has an ethylenically unsaturated component composed of an ethylenically unsaturated methacrylate monomer, or a combination of an ethylenically unsaturated methacrylate monomer and an ethylenically unsaturated methacrylate oligomer. The ethylenically unsaturated component is polymerizable or crosslinkable by the application of sufficient electron beam radiation. The composition is substantially absent of ethylenically unsaturated acrylate components, substantially absent of polymerization initiators, and substantially absent of solvents. The composition optionally further comprises one or more polymers without an acrylate functional group and without a methacrylate functional group. The composition optionally further comprises one or more of waxes, pigments, and/or wetting agents.
Abstract:
The invention relates to a gravure printing ink and a method of multi-color gravure printing on flexible substrates with liquid radiation curable inks. Individual colors are transferred via direct contact between engraved gravure cylinder and a substrate. Each color is dried such that the sequentially printed ink layers transfer through the press without distortion of the printed image during multiple web turns around turn bars. Finally the printed substrate is cured by exposing an electron beam unit. The gravure printing ink comprises an admixture of a) a water dispersible pigment; b) a water dispersible, ethylenically unsaturated monomer, ethylenically unsaturated oligomer or ethylenically unsaturated polymer which is polymerizable or crosslinkable by the application of sufficient electron beam radiation; c) a defoaming agent; d) sufficient water to form a dispersion with components a), b) and c), which dispersion has a viscosity of from about 25 cps to about 200 cps.
Abstract:
The invention provides an article and process for producing electronic devices. More particularly the invention relates to an article and process for fabricating patterns of electrically conductive materials on non-electrically conductive substrates by laser ablation. Such an article and process find use in the production of RDIF devices, antennae, electrical circuits, microwave susceptors, contacts, leads, conductors, interactive displays, electrostatic shielding devices and the like. The process involves first providing an electrically conductive metal layer on an electrically non-conductive substrate. Then an electronic circuit is electrically connected to the electrically conductive metal layer. Thereafter a portion of the electrically conductive metal layer is ablated with infrared laser radiation to form a pattern of electrically conductive areas and electrically non-conductive areas on the substrate, wherein at least a portion of the electrically conductive areas are electrically connected to the electronic circuit.
Abstract:
The present invention provides a liquid printing ink that produces high quality flexographic or gravure printing images that have excellent solvent and abrasion resistance. In addition, the printing ink of the invention has high re-solubility, even after complete drying, upon contact with the liquid vehicle of the same ink, thereby preventing clogging of the printing plate, anilox or gravure cylinders over time. These characteristics of the printing ink are obtained by preparing a hybrid ink in which conventional organic solvent and/or water-based liquid inks are mixed with energy curable monomers and/or oligomers of resins and, optionally, a photoinitiator. After drying the ink, the printed images are exposed to an actinic radiation so that highly cross-linked polymers are formed in the printed images, which become water, chemical and abrasion-resistant.
Abstract:
The present invention is for a method and associated apparatus whereby low viscosity flexograhic printing inks having a viscosity controlling diluent are used in implementing wet trapping of sequentially applied ink layers by controlling the time between ink layer applications such that sufficient diluent evaporates from an applied layer to increase the first applied layer viscosity sufficiently to wet trap a subsequently applied superposed ink layer.
Abstract:
Provided are a printed packaging and a method for printing and decorating packaging materials, such as paper, paper board, metals, and various flexible and rigid polymer films by electron beam exposure of plural layers of curable inks, which do not substantially change viscosity during the printing process. The inks are essentially free of volatile components such as organic solvents, inorganic solvents, water and low molecular weight fractions before, during and after exposure to electron beam irradiation. The method involves applying multiple layers of ink and an optional coating onto a substrate. The ink is an admixture of a colorant, and an unsaturated component such that the inks have a maximum of 10% volatile components. Thereafter these layers are simultaneously exposed with electron beam radiation to cause the ethylenically unsaturated components to polymerize or crosslink such that they become dried.
Abstract:
An aqueous polymer dispersion comprising a polymer substantially free of cationic polymerizable groups and a cationic photoinitiator, wherein the polymer is capable of being precipitated by an acid or base generating photoinitiator upon exposure to radiation and is optionally an energy curable polymer.
Abstract:
An Offset Lithographic Printing Process employing low VOC lithographic printing ink formulations containing monomeric diluents, curable by cationic polymerization in the presence of fountain solution and resin rheology modifiers compatible with cationic catalysts.