公开(公告)号：US5015614A

公开(公告)日：1991-05-14

申请号：US375225

申请日：1989-07-03

Applicant: William C. Baird, Jr. ,  Ehsan I. Shoukry

Inventor： William C. Baird, Jr. ,  Ehsan I. Shoukry

IPC: B01J21/04 ,  B01J21/10 ,  B01J21/12 ,  B01J21/14 ,  B01J23/58 ,  B01J23/656 ,  C10G35/085 ,  C10G35/09

CPC classification number: B01J23/58 ,  B01J21/04 ,  B01J21/14 ,  B01J23/6567 ,  C10G35/085 ,  C10G35/09 ,  B01J21/10 ,  B01J21/12

Abstract: Disclosed is a catalyst support material comprised of alumina and a modifier comprised of about 100 to 500 wppm Si and at least 10 wppm of one or more alkaline earth metals selected from Ca, Mg, Ba, and Sr wherein the total amount of modifier does not exceed 5000 wppm.

Abstract translation: 公开了一种催化剂载体材料，其由氧化铝和由约100至500wppm Si和至少10wppm的一种或多种选自Ca，Mg，Ba和Sr的碱土金属组成的改性剂组成，其中改性剂的总量不为 超过5000wppm。

公开(公告)号：US4963249A

公开(公告)日：1990-10-16

申请号：US375570

申请日：1989-07-03

Applicant: William C. Baird, Jr. ,  Kenneth L. Riley ,  George A. Swan, III

Inventor： William C. Baird, Jr. ,  Kenneth L. Riley ,  George A. Swan, III

IPC: B01J23/62 ,  C10G35/09

CPC classification number: C10G35/09 ,  B01J23/626

Abstract: A process for reforming gasoline boiling range naphthas which process comprises use of catalysts comprised of Pt and Sn on alumina and a modifier comprised of at least about 100 wppm Si and at least 10 wppm of one or more alkaline earth metals selected from Ca, Mg, Ba, and Sr wherein the total amount of modifier does not exceed about 5000 wppm.

Abstract translation: 一种重整汽油沸程石脑油的方法，该方法包括在氧化铝上使用由Pt和Sn组成的催化剂，以及由至少约100wppm Si和至少10wppm的一种或多种选自Ca，Mg， Ba和Sr，其中改性剂的总量不超过约5000wppm。

公开(公告)号：US4812435A

公开(公告)日：1989-03-14

申请号：US157605

申请日：1988-02-19

Applicant: William C. Baird, Jr.

Inventor： William C. Baird, Jr.

IPC: B01J23/46 ,  B01J23/656 ,  C10G35/09 ,  B01J21/04 ,  B01J27/13 ,  B01J27/132 ,  B01J27/135

CPC classification number: B01J23/6567 ,  B01J23/468 ,  C10G35/09

Abstract: A catalyst useful for reforming a naphtha feed at reforming conditions which comprises an iridium component dispersed throughout and bound within an alumina support matrix, a platinum component dispersed upon said iridium-containing alumina support, and halogen. In all of its aspects, the iridium component will remain in its dispersed state, without significant agglomeration, when subjected to temperature in the presence of oxygen for extended periods sufficient to agglomerate presently known halogenated platinum-iridium catalysts. This catalyst is prepared in an initial step by dispersing the iridium within the alumina matrix, and then calcining the iridium-containing alumina at high temperature to bind the iridium within the alumina support matrix. The platinum, or platinum and additional metal promoters, especially rhenium, is then impregnated upon the iridium-alumina support. This catalyst can be used in reforming at reforming conditions to provide high activity, high activity maintenance, high sulfur tolerance, low coke make and high C.sub.5 + liquid volume yield.

Abstract translation: 一种可用于在重整条件下重整石脑油进料的催化剂，其包含分散在氧化铝载体基质内的结合的铱组分，分散在所述含铱氧化铝载体上的铂组分和卤素。 在其所有方面中，当在氧气存在下经受长时间的温度以足够聚集目前已知的卤化铂 - 铱催化剂时，铱组分将保持分散状态而没有显着的团聚。 该催化剂在初始步骤中通过将铱分散在氧化铝基体内，然后在高温下煅烧含铱氧化铝以将铱在氧化铝载体基质内结合来制备。 然后将铂或铂和另外的金属促进剂，特别是铼浸渍在铱 - 氧化铝载体上。 该催化剂可用于重整条件下的重整，以提供高活性，高活性维持性，高硫耐受性，低焦炭成分和高C5 +液体体积产率。

公开(公告)号：US4701255A

公开(公告)日：1987-10-20

申请号：US933380

申请日：1986-11-21

Applicant: William C. Baird, Jr.

Inventor： William C. Baird, Jr.

IPC: B01J27/045 ,  B01J23/46 ,  B01J27/00 ,  B01J27/13 ,  C10G35/085 ,  C10G35/09 ,  C10G35/08

CPC classification number: C10G35/09 ,  B01J23/46

Abstract: A process for reforming a naphtha feed at reforming conditions by contacting said feed, and hydrogen, with a halogenated, supported platinum catalyst promoted with an agglomerated iridium component. The iridium component is agglomerated sufficient to exhibit a crystallinity greater than 50 percent, preferably greater than 75 percent, and more preferably 100 percent, as measured by x-ray.

公开(公告)号：US4330392A

公开(公告)日：1982-05-18

申请号：US182508

申请日：1980-08-29

Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge ,  William C. Baird, Jr.

Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge ,  William C. Baird, Jr.

IPC: C10G1/08 ,  C10G47/02 ,  C10G47/12 ,  C10G47/26 ,  C10G1/06 ,  C10G47/04

CPC classification number: C10G1/086 ,  C10G47/02 ,  C10G47/12 ,  C10G47/26

Abstract: Nitrogen-containing carbonaceous feeds such as hydrocarbonaceous oils and coal are hydroconverted in the presence of a solid vanadium-containing catalyst and a hydrogen halide.

Abstract translation: 在固体含钒催化剂和卤化氢的存在下，将含氮碳质进料如烃油和煤加氢转化。

公开(公告)号：US4303500A

公开(公告)日：1981-12-01

申请号：US206091

申请日：1980-11-12

Applicant: Paul E. Eberly, Jr. ,  Charles H. Mauldin ,  William C. Baird, Jr.

Inventor： Paul E. Eberly, Jr. ,  Charles H. Mauldin ,  William C. Baird, Jr.

IPC: B01J23/89 ,  B01J27/057 ,  C10G35/09 ,  C10G35/085

CPC classification number: B01J23/8926 ,  B01J27/0573 ,  C10G35/09

Abstract: A catalyst comprised of platinum, copper, selenium and halogen, composited with an inorganic oxide support or carrier, preferably alumina. The catalyst is one which possesses an intrinsically high activity, is stable and can operate at reforming conditions at high severities.

Abstract translation: 由铂，铜，硒和卤素组成的催化剂，与无机氧化物载体或载体，优选氧化铝复合。 该催化剂是具有本质上高活性的，稳定的并且能够在高浓度的重整条件下操作的催化剂。

公开(公告)号：US4003823A

公开(公告)日：1977-01-18

申请号：US571912

申请日：1975-04-28

Applicant: William C. Baird, Jr. ,  Roby Bearden, Jr.

Inventor： William C. Baird, Jr. ,  Roby Bearden, Jr.

IPC: C10G19/00 ,  C10G19/08 ,  C10G47/22 ,  C10G13/06 ,  B01J27/04

CPC classification number: C10G19/00 ,  C10G19/08 ,  C10G47/22

Abstract: Processes for the simultaneous desulfurization and hydroconversion of heavy carbonaceous feeds, including various sulfur-containing heavy petroleum oils, are disclosed. These feeds are contacted with alkali metal hydroxides in a conversion zone, in the presence of added hydrogen, and at elevated temperatures, whereby the feeds are substantially desulfurized, while at the same time significant upgrading of these feedstocks is obtained as demonstrated by decreased Conradson carbon, increased API gravity, and the conversion of a substantial portion of the 1,050.degree. F+ portion of the feedstream. In addition, methods for the regeneration of alkali metal hydroxides from the alkali metal salts produced in the conversion zone are disclosed.

Abstract translation: 公开了重质碳质饲料（包括各种含硫重质石油）同时脱硫和加氢转化的方法。 这些进料在转化区，在加入的氢气存在下，在升高的温度下与碱金属氢氧化物接触，从而使进料基本上脱硫，同时，这些原料的显着升级得到，如Conradson碳 ，API重力增加，以及进料流的1,050°F +部分的大部分转化。 此外，公开了在转化区中产生的碱金属盐再生碱金属氢氧化物的方法。

公开(公告)号：US06723230B1

公开(公告)日：2004-04-20

申请号：US09620796

申请日：2000-07-21

Applicant: Jingguang G. Chen ,  Leo D. Brown ,  William C. Baird, Jr. ,  Gary B. McVicker ,  Edward S. Ellis ,  Michele S. Touvelle ,  Darryl P. Klein ,  David E. W. Vaughan

Inventor： Jingguang G. Chen ,  Leo D. Brown ,  William C. Baird, Jr. ,  Gary B. McVicker ,  Edward S. Ellis ,  Michele S. Touvelle ,  Darryl P. Klein ,  David E. W. Vaughan

IPC: C10G2500

CPC classification number: C10G45/10 ,  B01J20/0229 ,  B01J20/06 ,  B01J20/3204 ,  B01J20/3236 ,  B01J20/3433 ,  B01J20/3458 ,  B01J20/3466 ,  B01J23/89 ,  B01J23/94 ,  B01J38/06 ,  B01J2220/56 ,  C10G25/003 ,  C10G45/04 ,  C10G45/62 ,  C10G65/043

Abstract: A process to regenerate iron-based hydrogen sulfide sorbents using steam. The steam is preferably mixed with hydrogen-containing gas and/or an inert gas, such as nitrogen. In a preferred embodiment, the sorbent is first exposed to the steam and then exposed to a hydrogen-containing gas at regeneration conditions.

Abstract translation: 使用蒸汽再生铁基硫化氢吸附剂的方法。 蒸汽优选与含氢气体和/或惰性气体如氮气混合。 在优选的实施方案中，首先将吸附剂暴露于蒸汽，然后在再生条件下暴露于含氢气体。

公开(公告)号：US06623625B2

公开(公告)日：2003-09-23

申请号：US09897192

申请日：2001-07-02

Applicant: William C. Baird, Jr. ,  Jingguang G. Chen ,  Gary B. McVicker

Inventor： William C. Baird, Jr. ,  Jingguang G. Chen ,  Gary B. McVicker

IPC: C10G3509

CPC classification number: B01J23/622 ,  B01J23/38 ,  B01J23/58 ,  B01J23/60 ,  B01J23/8926 ,  C07C5/13 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/06 ,  C07C2523/14 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/46 ,  C07C2523/50 ,  C07C2523/52 ,  C07C2523/72 ,  C10G45/62 ,  Y10S585/94 ,  Y10S585/95

Abstract: Disclosed is a process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst which comprises at least one of a Group VIII metal selected from Ir, Pt, Pd, Rh, and Ru in an amount effective to ring open naphthene rings on naphthene ring-containing compounds, the metal being supported on a substrate comprising at least one Group IB, IIB, and IVA metal in an amount effective to moderate cracking of a naphthene ring-containing feed to form methane.

公开(公告)号：US06586650B2

公开(公告)日：2003-07-01

申请号：US09897191

申请日：2001-07-02

Applicant: William C. Baird, Jr. ,  Darryl P. Klein ,  Michele S. Touvelle ,  Jingguang G. Chen ,  Gary B. McVicker

Inventor： William C. Baird, Jr. ,  Darryl P. Klein ,  Michele S. Touvelle ,  Jingguang G. Chen ,  Gary B. McVicker

IPC: C07C513

CPC classification number: B01J23/58 ,  C07C5/13 ,  C07C2521/02 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/02 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/12 ,  C07C2523/26 ,  C07C2523/42 ,  C07C2523/46

Abstract: A process for opening naphthenic rings of naphthenic ring-containing compounds, along with catalysts which can be used in that process. The naphthene ring opening catalyst is a catalyst comprising at least one Group VIII metal selected from Ir, Pt, Rh, and Ru, wherein these metals are supported on an alkali metal or alkaline-earth metal modified support in an amount effective for opening a naphthene ring-containing compound at a tertiary carbon site.

Abstract translation: 一种用于开环环烷环的环烷环化合物的方法，以及可用于该方法的催化剂。 环烷烃开环催化剂是包含至少一种选自Ir，Pt，Rh和Ru的Ⅷ族金属的催化剂，其中这些金属以有效打开环烷烃的量负载在碱金属或碱土金属改性的载体上 含碳化合物在叔碳位点。