-
公开(公告)号:US20160222522A1
公开(公告)日:2016-08-04
申请号:US15095342
申请日:2016-04-11
发明人: Xikun Wang , Jie Liu , Anchuan Wang , Nitin K. Ingle , Jeffrey W. Anthis , Benjamin Schmiege
CPC分类号: C23F1/12 , H01J37/32091 , H01J37/32357 , H01J37/32422 , H01J37/3244 , H01J2237/327 , H01J2237/334 , H01J2237/3341 , H01L21/32135 , H01L21/32138
摘要: Methods are described herein for etching metal films which are difficult to volatize. The methods include exposing a metal film to a chlorine-containing precursor (e.g. Cl2). Chlorine is then removed from the substrate processing region. A carbon-and-nitrogen-containing precursor (e.g. TMEDA) is delivered to the substrate processing region to form volatile metal complexes which desorb from the surface of the metal film. The methods presented remove metal while very slowly removing the other exposed materials. A thin metal oxide layer may be present on the surface of the metal layer, in which case a local plasma from hydrogen may be used to remove the oxygen or amorphize the near surface region, which has been found to increase the overall etch rate.
-
公开(公告)号:US20150345028A1
公开(公告)日:2015-12-03
申请号:US14288696
申请日:2014-05-28
发明人: Xikun Wang , Jie Liu , Anchuan Wang , Nitin K. Ingle , Jeffrey W. Anthis , Benjamin Schmiege
IPC分类号: C23F1/12 , H01L21/3213 , H01J37/32
CPC分类号: C23F1/12 , H01J37/32091 , H01J37/32357 , H01J37/32422 , H01J37/3244 , H01J2237/327 , H01J2237/334 , H01J2237/3341 , H01L21/32135 , H01L21/32138
摘要: Methods are described herein for etching metal films which are difficult to volatize. The methods include exposing a metal film to a chlorine-containing precursor (e.g. Cl2). Chlorine is then removed from the substrate processing region. A carbon-and-nitrogen-containing precursor (e.g. TMEDA) is delivered to the substrate processing region to form volatile metal complexes which desorb from the surface of the metal film. The methods presented remove metal while very slowly removing the other exposed materials. A thin metal oxide layer may be present on the surface of the metal layer, in which case a local plasma from hydrogen may be used to remove the oxygen or amorphize the near surface region, which has been found to increase the overall etch rate.
摘要翻译: 本文描述了用于蚀刻难以挥发的金属膜的方法。 这些方法包括将金属膜暴露于含氯前体(例如Cl 2)。 然后从基板处理区域除去氯。 将含碳和氮的前体(例如TMEDA)输送到基底加工区域以形成从金属膜的表面解吸的挥发性金属络合物。 所提供的方法去除金属,同时非常缓慢地除去其它暴露的材料。 金属层的表面上可能存在薄的金属氧化物层,在这种情况下,可以使用来自氢的局部等离子体来除去氧或使近表面区域非晶化,这已经被发现增加了整个蚀刻速率。
-
公开(公告)号:US09190293B2
公开(公告)日:2015-11-17
申请号:US14215417
申请日:2014-03-17
发明人: Xikun Wang , Jie Liu , Anchuan Wang , Nitin K. Ingle
IPC分类号: H01L21/4763 , H01L21/3213 , H01J37/32
CPC分类号: H01L21/32136 , H01J37/32357 , H01J2237/334
摘要: Methods of evenly etching tungsten liners from high aspect ratio trenches are described. The methods include ion bombardment of a patterned substrate having high aspect ratio trenches. The ion bombardment includes fluorine-containing ions and the ion bombardment may be stopped before breaking through the horizontal liner portion outside the trenches but near the opening of the trenches. The methods then include a remote plasma etch using plasma effluents formed from a fluorine-containing precursor. Plasma effluents from the remote plasma are flowed into a substrate processing region where the plasma effluents react with the tungsten. The plasmas effluents react with exposed surfaces and remove tungsten from outside the trenches and on the sidewalls of the trenches. The plasma effluents pass through an ion suppression element positioned between the remote plasma and the substrate processing region.
摘要翻译: 描述了从高纵横比沟槽均匀地蚀刻钨衬垫的方法。 这些方法包括具有高纵横比沟槽的图案化衬底的离子轰击。 离子轰击包括含氟离子,并且可以在穿过沟槽外部的水平衬套部分但在沟槽的开口附近之前停止离子轰击。 然后,该方法包括使用由含氟前体形成的等离子体流出物的远程等离子体蚀刻。 来自远程等离子体的等离子体流出物流入基板处理区域,其中等离子体流出物与钨反应。 等离子体流出物与暴露的表面反应并从沟槽的外部和沟槽的侧壁上除去钨。 等离子体流出物通过位于远程等离子体和基板处理区域之间的离子抑制元件。
-
公开(公告)号:US20150118857A1
公开(公告)日:2015-04-30
申请号:US14584099
申请日:2014-12-29
发明人: Jie Liu , Jingchun Zhang , Anchuan Wang , Nitin K. Ingle , Seung Park , Zhijun Chen , Ching-Mei Hsu
IPC分类号: H01L21/3213
CPC分类号: H01L21/32136 , H01J37/32357
摘要: Methods of etching exposed titanium nitride with respect to other materials on patterned heterogeneous structures are described, and may include a remote plasma etch formed from a fluorine-containing precursor. Precursor combinations including plasma effluents from the remote plasma are flowed into a substrate processing region to etch the patterned structures with high titanium nitride selectivity under a variety of operating conditions. The methods may be used to remove titanium nitride at faster rates than a variety of metal, nitride, and oxide compounds.
摘要翻译: 描述了相对于图案化异质结构上的其它材料蚀刻暴露的氮化钛的方法,并且可以包括由含氟前体形成的远程等离子体蚀刻。 包括来自远程等离子体的等离子体流出物的前体组合流入基板处理区域以在各种操作条件下以高氮化钛选择性蚀刻图案化结构。 该方法可用于以比各种金属,氮化物和氧化物化合物更快的速率除去氮化钛。
-
公开(公告)号:US20180195179A1
公开(公告)日:2018-07-12
申请号:US15899234
申请日:2018-02-19
发明人: Benjamin Schmiege , Nitin K. Ingle , Srinivas D. Nemani , Jeffrey W. Anthis , Xikun Wang , Jie Liu , David Benjaminson
CPC分类号: C23F1/12 , C23F4/00 , C30B33/12 , H01J37/32009 , H01J2237/334
摘要: Provided are methods for etching films comprising transition metals which help to minimize higher etch rates at the grain boundaries of polycrystalline materials. Certain methods pertain to amorphization of the polycrystalline material, other pertain to plasma treatments, and yet other pertain to the use of small doses of halide transfer agents in the etch process.
-
公开(公告)号:US20170110475A1
公开(公告)日:2017-04-20
申请号:US15393105
申请日:2016-12-28
发明人: Jie Liu , Xikun Wang , Anchuan Wang , Nitin K. Ingle
IPC分类号: H01L27/11582 , H01L21/3213 , H01L21/67 , H01L27/11568
CPC分类号: H01L27/11582 , C23F4/00 , H01J37/32357 , H01L21/28 , H01L21/32136 , H01L21/67225 , H01L27/11568
摘要: Methods of selectively etching tungsten from the surface of a patterned substrate are described. The etch electrically separates vertically arranged tungsten slabs from one another as needed, for example, in the manufacture of vertical flash memory devices. The tungsten etch may selectively remove tungsten relative to films such as silicon, polysilicon, silicon oxide, aluminum oxide, titanium nitride and silicon nitride. The methods include exposing electrically-shorted tungsten slabs to remotely-excited fluorine formed in a capacitively-excited chamber plasma region. The methods then include exposing the tungsten slabs to remotely-excited fluorine formed in an inductively-excited remote plasma system. A low electron temperature is maintained in the substrate processing region during each operation to achieve high etch selectivity.
-
公开(公告)号:US09540736B2
公开(公告)日:2017-01-10
申请号:US14793977
申请日:2015-07-08
发明人: Benjamin Schmiege , Nitin K. Ingle , Srinivas D. Nemani , Jeffrey W. Anthis , Xikun Wang , Jie Liu , David Benjaminson
CPC分类号: C23F1/12 , C23F4/00 , C30B33/12 , H01J37/32009 , H01J2237/334
摘要: Provided are methods for etching films comprising transition metals which help to minimize higher etch rates at the grain boundaries of polycrystalline materials. Certain methods pertain to amorphization of the polycrystalline material, other pertain to plasma treatments, and yet other pertain to the use of small doses of halide transfer agents in the etch process.
摘要翻译: 提供了用于蚀刻包含过渡金属的膜的方法,其有助于最小化在多晶材料的晶界处的较高蚀刻速率。 某些方法涉及多晶材料的非晶化,其它方法涉及等离子体处理,而另一些方法涉及在蚀刻工艺中使用小剂量的卤化物转移剂。
-
公开(公告)号:US09309598B2
公开(公告)日:2016-04-12
申请号:US14288696
申请日:2014-05-28
发明人: Xikun Wang , Jie Liu , Anchuan Wang , Nitin K. Ingle , Jeffrey W. Anthis , Benjamin Schmiege
IPC分类号: C03C15/00 , C23F1/12 , H01J37/32 , H01L21/3213
CPC分类号: C23F1/12 , H01J37/32091 , H01J37/32357 , H01J37/32422 , H01J37/3244 , H01J2237/327 , H01J2237/334 , H01J2237/3341 , H01L21/32135 , H01L21/32138
摘要: Methods are described herein for etching metal films which are difficult to volatize. The methods include exposing a metal film to a chlorine-containing precursor (e.g. Cl2). Chlorine is then removed from the substrate processing region. A carbon-and-nitrogen-containing precursor (e.g. TMEDA) is delivered to the substrate processing region to form volatile metal complexes which desorb from the surface of the metal film. The methods presented remove metal while very slowly removing the other exposed materials. A thin metal oxide layer may be present on the surface of the metal layer, in which case a local plasma from hydrogen may be used to remove the oxygen or amorphize the near surface region, which has been found to increase the overall etch rate.
摘要翻译: 本文描述了用于蚀刻难以挥发的金属膜的方法。 这些方法包括将金属膜暴露于含氯前体(例如Cl 2)。 然后从基板处理区域除去氯。 将含碳和氮的前体(例如TMEDA)输送到基底加工区域以形成从金属膜的表面解吸的挥发性金属络合物。 所提供的方法去除金属,同时非常缓慢地除去其它暴露的材料。 金属层的表面上可能存在薄的金属氧化物层,在这种情况下,可以使用来自氢的局部等离子体来除去氧或使近表面区域非晶化,这已经被发现增加了整个蚀刻速率。
-
公开(公告)号:US09299575B2
公开(公告)日:2016-03-29
申请号:US14215701
申请日:2014-03-17
发明人: Seung Park , Xikun Wang , Jie Liu , Anchuan Wang , Sang-jin Kim
IPC分类号: H01L21/302 , H01L21/3065
CPC分类号: H01L21/3065 , H01J37/32357 , H01J2237/334 , H01L21/32136
摘要: Methods of evenly etching tungsten liners from high aspect ratio trenches are described. The methods include a remote plasma etch using plasma effluents formed from a fluorine-containing precursor and a high flow of helium. Plasma effluents from the remote plasma are flowed into a substrate processing region where the plasma effluents react with tungsten coating a patterned substrate having high aspect ratio trenches. The plasmas effluents react with exposed surfaces and evenly remove tungsten from outside the trenches and on the sidewalls of the trenches. The plasma effluents pass through an ion suppression element positioned between the remote plasma and the substrate processing region. Optionally, the methods may include concurrent ion bombardment of the patterned substrate to help remove potentially thicker horizontal tungsten regions, e.g., at the bottom of the trenches or between trenches.
摘要翻译: 描述了从高纵横比沟槽均匀地蚀刻钨衬垫的方法。 这些方法包括使用由含氟前体形成的等离子体流出物和大量氦气的远程等离子体蚀刻。 来自远程等离子体的等离子体流出物流入衬底处理区域,其中等离子体流出物与钨涂覆具有高纵横比沟槽的图案化衬底。 等离子体流出物与暴露的表面反应,并从沟槽的外部和沟槽的侧壁均匀地除去钨。 等离子体流出物通过位于远程等离子体和基板处理区域之间的离子抑制元件。 可选地,所述方法可以包括图案化衬底的同时离子轰击,以帮助去除潜在的较厚的水平钨区域,例如在沟槽的底部或沟槽之间。
-
公开(公告)号:US20160032460A1
公开(公告)日:2016-02-04
申请号:US14793977
申请日:2015-07-08
发明人: Benjamin Schmiege , Nitin K. Ingle , Srinivas D. Nemani , Jeffrey W. Anthis , Xikun Wang , Jie Liu , David Benjaminson
CPC分类号: C23F1/12 , C23F4/00 , C30B33/12 , H01J37/32009 , H01J2237/334
摘要: Provided are methods for etching films comprising transition metals which help to minimize higher etch rates at the grain boundaries of polycrystalline materials. Certain methods pertain to amorphization of the polycrystalline material, other pertain to plasma treatments, and yet other pertain to the use of small doses of halide transfer agents in the etch process.
摘要翻译: 提供了用于蚀刻包含过渡金属的膜的方法,其有助于最小化在多晶材料的晶界处的较高蚀刻速率。 某些方法涉及多晶材料的非晶化,其它方法涉及等离子体处理,而另一些方法涉及在蚀刻工艺中使用小剂量的卤化物转移剂。
-
-
-
-
-
-
-
-
-