公开(公告)号：US20130338402A1

公开(公告)日：2013-12-19

申请号：US13916082

申请日：2013-06-12

Applicant: BASF SE

Inventor： Richard Dehn ,  Joaquim Henrique Teles ,  Michael Limbach ,  Stephan Deuerlein ,  Manuel Danz ,  Ralf Pelzer ,  Daniel Schneider

IPC: C07C45/68 ,  C07C49/547 ,  C07C49/527 ,  C07C45/67

CPC classification number: C07C45/68 ,  C07C45/673 ,  C07C49/527 ,  C07C49/547 ,  C07C2601/18 ,  C07C49/607 ,  C07C49/587

Abstract: The present invention relates to a process for preparing cyclic compounds having at least eight carbon atoms and at least one keto group, to the cyclic compounds obtained by this process and to the use thereof, in particular as fragrance or for providing a fragrance.

Abstract translation: 本发明涉及一种制备具有至少8个碳原子和至少一个酮基的环状化合物与通过该方法获得的环状化合物及其用途，特别是作为香料或提供香料的方法。

公开(公告)号：US10695750B2

公开(公告)日：2020-06-30

申请号：US16238659

申请日：2019-01-03

Applicant: BASF SE

Inventor： Stephan Deuerlein ,  Regine Helga Bebensee ,  Harald Würz ,  Denis Stella ,  Andreas Spiegel

IPC: B01J23/46 ,  B01J37/08 ,  B01J21/06 ,  B01J23/28 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J37/04 ,  B01J21/08 ,  B01J23/652 ,  B01D53/86 ,  B01J37/00 ,  B01J35/10

Abstract: The present invention relates to a catalyst for decomposition of nitrous oxide and also to its method of preparation and use.

公开(公告)号：US20190308358A1

公开(公告)日：2019-10-10

申请号：US16470590

申请日：2017-12-15

Applicant: BASF SE

Inventor： Monica Haag ,  Stephan Deuerlein ,  Holger Barthel ,  Volker Klock ,  Roland Krauss

IPC: B29C48/00 ,  B29B7/42 ,  B29C48/395 ,  B29C48/535 ,  B29C48/625 ,  B29C48/63 ,  B29C48/685 ,  C08J3/075 ,  C08L101/14 ,  B29C48/68

Abstract: A single-screw extruder for changing a morphology of a superabsorbent polymer, specifically a polymer gel. The single-screw extruder has an input aperture, a channel, a screw and an output aperture. The screw has a pitch value of a pitch of the screw flights along the conveying zone of the channel, where the channel has a mixing-element arrangement with at least one mixing element which protrudes into the channel of the single-screw extruder and which is configured for the mixing of the SAP polymer gel.

公开(公告)号：US20190134611A1

公开(公告)日：2019-05-09

申请号：US16238659

申请日：2019-01-03

Applicant: BASF SE

Inventor： Stephan Deuerlein ,  Regine Helga Bebensee ,  Harald Würz ,  Denis Stella ,  Andreas Spiegel

IPC: B01J23/46 ,  B01J37/08 ,  B01J21/06 ,  B01J23/28 ,  B01J35/00 ,  B01J35/02 ,  B01J37/02 ,  B01J37/04 ,  B01J21/08 ,  B01J23/652 ,  B01D53/86 ,  B01J37/00 ,  B01J35/10

CPC classification number: B01J23/464 ,  B01D53/8628 ,  B01D2255/1025 ,  B01D2255/20715 ,  B01D2255/20769 ,  B01D2255/30 ,  B01D2257/402 ,  B01J21/066 ,  B01J21/08 ,  B01J23/28 ,  B01J23/6525 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  B01J37/0009 ,  B01J37/0018 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/04 ,  B01J37/086 ,  B01J37/088 ,  Y02C20/10

Abstract: The present invention relates to a catalyst for decomposition of nitrous oxide and also to its method of preparation and use.

公开(公告)号：US10179185B2

公开(公告)日：2019-01-15

申请号：US15308383

申请日：2015-05-07

Applicant: BASF SE

Inventor： Markus Braun ,  Monica Haag ,  Stephan Deuerlein ,  Volker Klock ,  Roland Krauss

IPC: A61L15/24 ,  A61L15/60 ,  C08F2/00 ,  C08F2/10 ,  B01J20/26 ,  B01J20/28 ,  C08F220/06 ,  C08J3/24

Abstract: A process for producing water-absorbing polymer particles is provided, comprising a) a polymerization step in which an aqueous monomer solution comprising at least one ethylenically unsaturated monomer M which bears acid groups and may have been at least partly neutralized and at least one crosslinker is polymerized to obtain an aqueous polymer gel; b) a pelletization step in which the aqueous polymer gel having a solids content of 35 to 70% by weight and a temperature of 75 to 125° C. is forced from a high-pressure zone through a die plate into a low-pressure zone and pellets are obtained, the pressure differential between the high-pressure zone and the low-pressure zone being 4 to less than 14 bar and the orifice ratio of the die plate being 30 to 80%; c) a drying step in which the pellets are dried to a moisture content of less than 10% by weight; d) a grinding step and a classifying step to obtain water-absorbing polymer particles; and e) surface crosslinking of the water-absorbing polymer particles. The water-absorbing polymer particles have a high swell rate and a high retention capacity combined with a favorable ratio of permeability of the swollen gel bed SFC to centrifuge retention capacity CRC.

公开(公告)号：US10081580B2

公开(公告)日：2018-09-25

申请号：US14053634

申请日：2013-10-15

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Kathrin Wissel-Stoll ,  Jochen Bürkle ,  Albena Kostova ,  Markus Schmitt ,  Veronika Wloka ,  Stephan Deuerlein ,  Marco Bosch ,  Steffen Oehlenschläger ,  Michael Schreiber ,  Gauthier Luc Maurice Averlant ,  Joni Joni ,  Roman Prochazka ,  Martin Bock ,  Alois Kindler ,  Daniela Malkowsky ,  Katharina Spuhl ,  Stefan Bitterlich ,  Daniel Pfeiffer

IPC: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163

CPC classification number: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2601/14 ,  C07C13/10 ,  C07C13/18

Abstract: The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

公开(公告)号：US20170065739A1

公开(公告)日：2017-03-09

申请号：US15308383

申请日：2015-05-07

Applicant: BASF SE

Inventor： Markus Braun ,  Monica Haag ,  Stephan Deuerlein ,  Volker Klock ,  Roland Krauss

IPC: A61L15/24 ,  B01J20/28 ,  C08J3/24 ,  B01J20/26 ,  C08F220/06 ,  A61L15/60

CPC classification number: A61L15/24 ,  A61L15/60 ,  B01J20/267 ,  B01J20/28011 ,  C08F2/001 ,  C08F2/10 ,  C08F220/06 ,  C08J3/245 ,  C08J2333/02 ,  C08F2222/1026 ,  C08L33/02

Abstract: A process for producing water-absorbing polymer particles is provided, comprising a) a polymerization step in which an aqueous monomer solution comprising at least one ethylenically unsaturated monomer M which bears acid groups and may have been at least partly neutralized and at least one crosslinker is polymerized to obtain an aqueous polymer gel; b) a pelletization step in which the aqueous polymer gel having a solids content of 35 to 70% by weight and a temperature of 75 to 125° C. is forced from a high-pressure zone through a die plate into a low-pressure zone and pellets are obtained, the pressure differential between the high-pressure zone and the low-pressure zone being 4 to less than 14 bar and the orifice ratio of the die plate being 30 to 80%; c) a drying step in which the pellets are dried to a moisture content of less than 10% by weight; d) a grinding step and a classifying step to obtain water-absorbing polymer particles; and e) surface crosslinking of the water-absorbing polymer particles. The water-absorbing polymer particles have a high swell rate and a high retention capacity combined with a favorable ratio of permeability of the swollen gel bed SFC to centrifuge retention capacity CRC.

Abstract translation: 提供了一种生产吸水性聚合物颗粒的方法，该方法包括：a）聚合步骤，其中包含至少一种带有酸基团且至少部分中和的至少一种烯属不饱和单体M的单体水溶液和至少一种交联剂是 聚合得到聚合物水凝胶; b）造粒步骤，其中固体含量为35至70重量％，温度为75至125℃的聚合物凝胶水凝胶被迫从高压区通过模板进入低压区 得到颗粒，高压区与低压区之间的压力差为4〜14巴，模板的孔径比为30〜80％。 c）干燥步骤，其中将颗粒干燥至含水量小于10重量％; d）研磨步骤和分级步骤以获得吸水性聚合物颗粒; 和e）吸水性聚合物颗粒的表面交联。 吸水性聚合物颗粒具有高的溶胀速率和高的保留能力以及膨胀的凝胶床SFC的渗透性与离心保留容量CRC的良好比率。

公开(公告)号：US20150030515A1

公开(公告)日：2015-01-29

申请号：US14376700

申请日：2013-02-06

Applicant: BASF SE

Inventor： Stephan Deuerlein ,  Stefan Maurer

IPC: B01D53/94

Abstract: Described is a process for the treatment of a gas stream containing nitrogen oxides. The process comprises the steps of: (1) providing a gas stream containing one or more nitrogen oxides; (2) contacting the gas stream provided in step (1) with a transition metal containing zeolitic material having a BEA-type framework structure for reacting one or more of the nitrogen oxides; wherein the zeolitic material is obtainable from an organotemplate-free synthetic process. Also described is an apparatus for the treatment of a gas stream comprising containing nitrogen oxides.

Abstract translation: 描述了一种处理含有氮氧化物的气流的方法。 该方法包括以下步骤：（1）提供含有一种或多种氮氧化物的气流; （2）使步骤（1）中提供的气流与含有BEA型骨架结构的含过渡金属的沸石材料接触，使一种或多种氮氧化物反应; 其中所述沸石材料可以从无有机模板的合成方法获得。 还描述了一种用于处理包含氮氧化物的气流的装置。

公开(公告)号：US20140114099A1

公开(公告)日：2014-04-24

申请号：US14053634

申请日：2013-10-15

Applicant: BASF SE

Inventor： Steffen Tschirschwitz ,  Kathrin Wissel-Stoll ,  Jochen Bürkle ,  Albena Kostova ,  Markus Schmitt ,  Veronika Wloka ,  Stephan Deuerlein ,  Marco Bosch ,  Steffen Oehlenschläger ,  Michael Schreiber ,  Gauthier Luc Maurice Averlant ,  Joni Joni ,  Roman Prochazka ,  Martin Bock ,  Alois Kindler ,  Daniela Malkowsky ,  Katharina Spuhl ,  Stefan Bitterlich ,  Daniel Pfeiffer

IPC: C07C5/29

CPC classification number: C07C5/29 ,  C07C5/10 ,  C07C7/08 ,  C07C7/163 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/755 ,  C07C2527/11 ,  C07C2527/1206 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/135 ,  C07C2601/14 ,  C07C13/10 ,  C07C13/18

Abstract: The present invention relates to a process for preparing cyclohexane by isomerizing a hydrocarbon mixture (HM1) comprising methylcyclopentane (MCP) in the presence of a catalyst. The catalyst is preferably an acidic ionic liquid. The starting material used is a stream (S1) which originates from a steamcracking process. The hydrocarbon mixture (HM1) obtained from this stream (S1) in an apparatus for aromatics removal has a reduced aromatics content compared to stream (S1), and (HM1) may optionally also be (virtually) free of aromatics. Depending on the type and amount of the aromatics remaining in the hydrocarbon mixture (HM1), especially in the case that benzene is present, the isomerization may additionally be preceded by performance of a hydrogenation of (HM1). In addition, depending on the presence of other components of (HM1), further purification steps may optionally be performed prior to or after the isomerization or hydrogenation. High-purity (on-spec) cyclohexane is preferably isolated from the hydrocarbon mixture (HM2) obtained in the isomerization, the specifications being, for example, those applicable to the use of the cyclohexane for the preparation, known to those skilled in the art, of caprolactam.

Abstract translation: 本发明涉及通过在催化剂存在下异构化包含甲基环戊烷（MCP）的烃混合物（HM1）来制备环己烷的方法。 催化剂优选为酸性离子液体。 使用的起始材料是来自蒸汽裂化过程的流（S1）。 在与物流（S1）相比，用于除去芳烃的装置中从该料流（S1）获得的烃混合物（HM1）具有降低的芳族化合物含量，（HM1）也可任选地（实际上）不含芳族化合物。 取决于残留在烃混合物（HM1）中的芳族化合物的类型和量，特别是在存在苯的情况下，异构化可另外进行（HM1）的氢化。 此外，根据（HM1）的其它组分的存在，可以任选地在异构化或氢化之前或之后进行进一步的纯化步骤。 高纯度（特定）环己烷优选与在异构化中获得的烃混合物（HM2）分离，其规格是例如适用于本领域技术人员已知的用于制备环己烷的那些 的己内酰胺。