Abstract:
Provided are poly(AAG)-compositions, and corresponding coatings, foams, and coated articles. Also provided are methods for preparing the poly(AAG)-compositions and corresponding reagents including. e.g., polyol-AAG compositions. Coatings using the poly(AAG)-compositions may be useful for, e.g., replacing bisphenol-A cross-linked coatings used in food and beverage containers, coating metal articles, and the like.
Abstract:
A self-healing polymeric composition includes a polymer matrix and a plurality of functional microcapsules dispersed in the polymer matrix. The functional microcapsules include a core of a flowable material that can form film via coalescence, physical crosslinking and/or polymerization on contact with the substrate, and a polymer shell encapsulating the core. The functionality on the polymer shell is effective in complexing with the corrosion by-products, releasing the core material to repair the failure.
Abstract:
Coated seeds, plants, or soil are described. The seeds, plants or soil are coated with an encapsulated composition containing a plurality of capsules each comprising an amphiphilic material encapsulating an agrochemical, the encapsulated agrochemical having a release rate less than a release rate of unencapsulated agrochemical. The encapsulated agrochemical can be included in paint and applied to substrates such as concrete, polymer, polymer wood composites and metals for a slow release of insecticide.
Abstract:
Polymer matrix particles useful for inhibiting scale formation in oil and gas wells are described. The insoluble, porous, crosslinked polymer matrix includes a polymer backbone and ionic functional groups covalently bonded to the backbone, the ionic functional groups being capable of selectively attracting and binding salt scale-forming ions when in contact with a liquid containing such ions.
Abstract:
In a method of producing a polymer composite, a polymer is provided in a liquid state such as a molten state. A plant material, such as soymeal, is provided that includes protein and carbohydrate. The plant material has a particle size less than 50 microns. A reactive protein denaturant is also provided. A dispersion of the plant material and the reactive protein denaturant is formed in a matrix of the liquid polymer. The plant material is reacted to bond with the reactive protein denaturant, and the reactive protein denaturant is reacted to bond with the polymer. The polymer is solidified to produce the polymer composite.
Abstract:
Polymer matrix particles useful for inhibiting scale formation in oil and gas wells are described. The insoluble, porous, crosslinked polymer matrix includes a polymer backbone and ionic functional groups covalently bonded to the backbone, the ionic functional groups being capable of selectively attracting and binding salt scale-forming ions when in contact with a liquid containing such ions.
Abstract:
A cationic surfactant and a method of making the cationic surfactant are described. The method comprises reacting a lipophilic bio-based material having at least one epoxy functional group and a hydrophilic organic compound having at least one cationic functional group and at least one hydroxyl functional group to form a reaction product containing a stable ether linkage connecting the lipophilic bio-based material to the organic compound. At least a portion of the cationic functional groups is neutralized or ion exchanged with an organic acid. Incorporation of the simple organic acid reduces the surfactant's aquatic toxicity and acts as a substrate to encourage co-digestion of the surfactant molecule, making the compound more biodegradable.
Abstract:
A releasable encapsulation composition is described. The composition comprises a plurality of capsules, each capsule comprising an amphiphilic material encapsulating a substance, such as an active ingredient. The substance is releasable from encapsulation by a change in the amphiphilic material triggered by a change in the environment around the capsule.
Abstract:
Aqueous prepolymer dispersions are provided, as are methods for making aqueous prepolymer dispersions. For example, an aqueous polyurethane prepolymer dispersion may be prepared by a process. The process may include contacting a soybean oil polyester polyol and an isocyanate reactive monomer together in a first mixture. The isocyanate reactive monomer may be functionalized with a tertiary amine salt of an isocyanate-unreactive organic acid. The process may include contacting the first mixture with a diisocyanate to form a neutralized polyurethane prepolymer. The process may include contacting the neutralized polyurethane prepolymer with water to form the aqueous polyurethane prepolymer dispersion.
Abstract:
Processes for producing polymer microcapsules using vicinal functional oligomers are also described. The vicinal functional oligomers can be made by polymerizing an acrylate monomer, a styrene monomer, or both in the presence of a chain transfer agent. The vicinal functional oligomers can be reacted with epichlorohydrin to form vicinal epoxies. The vicinal epoxies can be reacted with polyamines to form epoxy polymer microspheres. The vicinal epoxies can be reacted with carbon dioxide in the presence of a catalyst to form vicinal cyclic carbonates. The vicinal cyclic carbonates can be reacted with polyamines to form isocyanate-free polymer microspheres. Polymer microspheres made by the processes are also described.