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11.发明授权公开(公告)号：US11332576B2
公开(公告)日：2022-05-17
申请号：US13639662
申请日：2011-04-05
申请人： Frederic Malet , Guillaume Le , Julien Jouanneau
发明人： Frederic Malet , Guillaume Le , Julien Jouanneau
IPC分类号： C08G65/26 , C08G69/40 , C08G63/672 , C12P7/10 , C12P5/02 , C08L71/02 , C07D301/02 , C08G18/48
摘要： The invention relates to a block copolymer derived from at least one ethylene oxide and/or propylene oxide monomer containing 14C.
The present invention also relates to a method for preparing such a block copolymer.-
12.发明授权公开(公告)号：US08338549B2
公开(公告)日：2012-12-25
申请号：US13119863
申请日：2009-09-22
CPC分类号： C11C3/12 , C08F210/16 , C08K5/092 , C08L23/02 , C08L23/04 , C08L23/20 , C11C3/00 , C11C3/003 , C08F2/00 , C08L2666/04 , C08F210/14
摘要： The invention relates to a polymer obtained by polymerizing olefins having 6 to 9 carbon atoms and partially derived from renewable resources. In particular, the polymer according to the invention can be derived from vegetable oil or animal fat. The invention also relates to the method for producing the polymer.
摘要翻译： 本发明涉及通过聚合具有6至9个碳原子且部分衍生自可再生资源的烯烃获得的聚合物。 特别地，根据本发明的聚合物可以衍生自植物油或动物脂肪。 本发明还涉及聚合物的制造方法。
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13.发明申请COMPOSITION CONTAINING POLYPROPYLENE AND/OR A PROPYLENE COPOLYMER OBTAINED FROM RENEWABLE MATERIALS, AND USES THEREOF 审中-公开含有聚丙烯和/或由可再生材料获得的丙烯共聚物的组合物及其用途公开(公告)号：US20110305900A1
公开(公告)日：2011-12-15
申请号：US13131347
申请日：2009-12-02
申请人： Samuel Devisme , Fabrice R. Chop , Jean-Laurent Pradel , Guillaume Le , Thomas Roussel , Jean-Luc Dubois
发明人： Samuel Devisme , Fabrice R. Chop , Jean-Laurent Pradel , Guillaume Le , Thomas Roussel , Jean-Luc Dubois
IPC分类号： B32B7/12 , B32B27/08 , C09J151/06 , B32B15/08 , C08F255/02 , C08L51/06
CPC分类号： C08F255/04 , B32B7/12 , B32B27/08 , C08F255/02 , C08L51/06 , C08L2666/02 , C09J151/06 , Y10T428/2804 , Y10T428/2891 , Y10T428/31511 , Y10T428/31522 , Y10T428/31678 , Y10T428/31725 , Y10T428/31855 , Y10T428/31859
摘要： The present application relates to a method for manufacturing a propylene polymer, including: a) fermenting and optionally purifying first renewable materials to produce an alcohol or an alcohol mixture, the alcohol or alcohol mixture including at least isopropanol and/or at least a mixture of ethanol and 1-butanol; b) dehydrating the resulting alcohol or the alcohol mixture to produce an alkene or alkene mixture in a first series of reactors, the alkene or alkene mixture containing at least propylene; c) polymerizing the propylene in a second reactor, optionally in the presence of a comonomer, so as to produce a propylene polymer; d) isolating the propylene polymer obtained in step c); and e) grafting the propylene polymer obtained from step d). The invention also relates to the grafted propylene polymer capable of being obtained by the method, to the compositions containing the polymer, as well as to the uses of the polymer.
摘要翻译： 本申请涉及一种用于制备丙烯聚合物的方法，包括：a）发酵和任选地净化第一可再生材料以产生醇或醇混合物，所述醇或醇混合物至少包括异丙醇和/或至少一种 乙醇和1-丁醇; b）使所得醇或醇混合物脱水以在第一系列反应器中产生烯烃或烯烃混合物，所述烯烃或烯烃混合物至少含有丙烯; c）任选地在共聚单体存在下，在第二反应器中聚合丙烯，以产生丙烯聚合物; d）分离步骤c）中获得的丙烯聚合物; 和e）接枝由步骤d）得到的丙烯聚合物。 本发明还涉及能够通过该方法获得的接枝丙烯聚合物，含有聚合物的组合物以及聚合物的用途。
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14.发明申请公开(公告)号：US20110189419A1
公开(公告)日：2011-08-04
申请号：US13002792
申请日：2009-07-06
申请人： Guillaume Le , Julien Jouanneau , Thierry Briffaud
发明人： Guillaume Le , Julien Jouanneau , Thierry Briffaud
CPC分类号： C08G69/26 , B32B27/20 , B32B27/22 , B32B27/285 , B32B27/34 , B32B27/36 , B32B2307/306 , B32B2307/702 , B32B2307/704 , B32B2439/00 , B32B2457/00 , B32B2535/00 , B32B2605/08 , C08G69/14 , C08G69/265 , C08G69/36 , C08J5/18 , C08J2377/06 , C08L77/00 , C08L77/06 , C08L77/12 , C08L2205/02 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , C08L2666/20
摘要： The invention relates to a polyamide comprising at least two units having the following general formula: 4.Y in which: 4 denotes butanediamine, and Y represents a dicarboxylic acid chosen from a linear or branched aliphatic dicarboxylic acid, a cycloaliphatic diacid and an aromatic diacid, the dicarboxylic acid containing from 7 to 11 carbon atoms, the butanediamine contains carbon of renewable origin, except for the fact that when the polyamide is a copolyamide, it cannot contain 100% by mass of organic carbon derived from renewable raw materials relative to the total mass of polyamide carbon. The invention also relates to a composition comprising this polyamide and the use of this polyamide and of such a composition.
摘要翻译： 本发明涉及一种包含至少两个具有以下通式的单元的聚酰胺：4.Y其中：4表示丁二胺，Y表示选自直链或支链脂族二羧酸，脂环族二酸和芳族二酸的二羧酸 ，含有7-11个碳原子的二羧酸，丁二胺含有可再生原料的碳，除了当聚酰胺为共聚酰胺时，不能含有100质量％的源自可再生原料的有机碳相对于 聚酰胺碳的总质量。 本发明还涉及包含该聚酰胺的组合物以及该聚酰胺和这种组合物的用途。
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15.发明授权公开(公告)号：US08865806B2
公开(公告)日：2014-10-21
申请号：US13643831
申请日：2011-04-18
IPC分类号： C08K5/3445 , C08K5/435 , C08K5/34 , C08K5/00
CPC分类号： C08K5/3445 , C08K5/0016 , C08K5/34 , C08K5/435
摘要： The invention relates to the field of plasticizers, compounds used as additives in polymers for facilitating the transformation thereof or modifying the mechanical properties thereof, especially rigidity.
摘要翻译： 本发明涉及增塑剂领域，在聚合物中用作促进其变性或改变其机械性能，特别是刚性的添加剂的化合物。
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16.发明申请BLOCK COPOLYMER DERIVED FROM RENEWABLE MATERIALS AND METHOD FOR MAKING SUCH A BLOCK COPOLYMER 审中-公开可再生材料获得的嵌段共聚物和制备这种嵌段共聚物的方法公开(公告)号：US20130022771A1
公开(公告)日：2013-01-24
申请号：US13639662
申请日：2011-04-05
申请人： Frederic Malet , Guillaume Le , Julien Jouanneau
发明人： Frederic Malet , Guillaume Le , Julien Jouanneau
CPC分类号： C08G69/40 , C07D301/02 , C08G18/48 , C08G63/672 , C08L71/02 , C12P5/026 , C12P7/10 , Y02E50/16 , Y10T428/139 , Y10T428/249921 , Y10T442/30 , Y10T442/60 , C08L75/04 , C08L67/00 , C08L77/00
摘要： The invention relates to a block copolymer derived from at least one ethylene oxide and/or propylene oxide monomer containing 14C.The present invention also relates to a method for preparing such a block copolymer.
摘要翻译： 本发明涉及衍生自含有14 C的至少一种环氧乙烷和/或环氧丙烷单体的嵌段共聚物。 本发明还涉及制备这种嵌段共聚物的方法。
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17.发明申请公开(公告)号：US20060014910A1
公开(公告)日：2006-01-19
申请号：US10534120
申请日：2003-11-03
申请人： Reinhard Linemann , Guillaume Le
发明人： Reinhard Linemann , Guillaume Le
CPC分类号： C08G63/005 , C08F4/00
摘要： The invention concerns a cationic catalyst system comprising an initiator (I), a catalyst (K) and a cocatalyst (CoK). The cocatalyst (CoK) is an agent releasing the active polymerizing center of its counter anion generated by the reaction between the catalyst (K) and the initiator (I). Said cocatalyst is characterized by the existence of a double bond electron-depleted by an electroattractive group. It is selected, for example, from the group consisting of the following complexing agents including o-chloranyl (3,4,5,6-tetrachloro-1,2-benzoquinone), p-chloranyl (2,3,5,6-tetrachloro-1,4-benzoquinone), nitrobenzene, trinitrobenzene, or tetracyanoethylene.
摘要翻译： 本发明涉及包含引发剂（I），催化剂（K）和助催化剂（CoK）的阳离子催化剂体系。 助催化剂（CoK）是释放由催化剂（K）和引发剂（I）之间的反应产生的其抗衡阴离子的活性聚合中心的试剂。 所述助催化剂的特征在于存在由电吸收基团电子耗尽的双键。 例如可以选自以下络合剂：邻氯苯基（3,4,5,6-四氯-1,2-苯醌），对氯苯基（2,3,5,6-四氢 - 四氯-1,4-苯醌），硝基苯，三硝基苯或四氰基乙烯。
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18.发明授权Production of grafted polyethylene from renewable materials, the obtained polyethylene and uses thereof 有权从可再生材料生产接枝聚乙烯，获得的聚乙烯及其用途公开(公告)号：US09045577B2
公开(公告)日：2015-06-02
申请号：US13055857
申请日：2009-07-27
IPC分类号： C08F8/46 , C08F255/02 , C08F10/02 , C08F110/02 , B32B27/32 , C08F210/16 , C08L51/06
CPC分类号： C08F255/02 , B32B7/12 , B32B15/08 , B32B27/08 , B32B27/18 , B32B27/30 , B32B27/32 , B32B27/327 , B32B27/34 , B32B27/36 , B32B2270/00 , B32B2307/558 , C08F8/46 , C08F10/02 , C08F110/02 , C08F210/16 , C08L51/06 , C08F2/00 , C08L2666/02 , C08F210/06 , C08F2500/12 , C08F2500/08 , C08F210/14
摘要： The invention relates to a method for production of grafted polyethylene comprising the following steps: a) fermentation of primary renewable material with optional purification to give at least one alcohol chosen from ethanol or a mixture of alcohols comprising ethanol; b) dehydration of the alcohol obtained to give in a first reactor at least one alkene selected from ethylene and mixtures of alkenes containing ethylene and optional purification of the alkene to give ethylene; c) polymerization, in a second reactor, of the ethylene to give polyethylene; d) isolation of the polyethylene obtained in step c); e) grafting the polyethylene with at least one grafting monomer selected from the unsaturated carboxylic acids or theifunctional derivatives thereof, the unsaturated dicarboxylic acids having 4-10 carbon atoms and the functional derivatives thereof being C1-C8 alkyl esters or glycidyl ester derivatives of the unsaturated carboxylic acids and the metal salts of the unsaturated carboxylic acids. The invention further relates to the grafted polyethylene obtained by said method, the copolymers and compositions comprising said polyethylene and the use of said polyethylene.
摘要翻译： 本发明涉及生产接枝聚乙烯的方法，包括以下步骤：a）可任选地纯化初级可再生材料发酵，得到至少一种选自乙醇或包含乙醇的醇的混合物的醇; b）在第一反应器中获得的醇的脱水得到至少一种选自乙烯的烯烃和含乙烯的烯烃的混合物和任选的烯烃纯化以得到乙烯; c）在第二反应器中聚合乙烯，得到聚乙烯; d）分离步骤c）中获得的聚乙烯; e）用至少一种选自不饱和羧酸或其官能衍生物的接枝单体，具有4-10个碳原子的不饱和二羧酸接枝聚乙烯，其官能衍生物是不饱和羧酸或其不饱和羧酸的缩水甘油酯衍生物 羧酸和不饱和羧酸的金属盐。 本发明还涉及通过所述方法获得的接枝聚乙烯，所述共聚物和组合物包含所述聚乙烯和所述聚乙烯的用途。
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公开(公告)号：US20130210972A1
公开(公告)日：2013-08-15
申请号：US13643831
申请日：2011-04-18
IPC分类号： C08K5/3445
CPC分类号： C08K5/3445 , C08K5/0016 , C08K5/34 , C08K5/435
摘要： The invention relates to the field of plasticisers, compounds used as additives in polymers for facilitating the transformation thereof or modifying the mechanical properties thereof, especially rigidity.
摘要翻译： 本发明涉及增塑剂领域，用作聚合物中的添加剂以促进其变性或改变其机械性能，特别是刚性的化合物领域。
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20.发明授权Method of preparing dimethylcetene and, subsequently, polydimethylcetene from isobutyric anhydride 失效从异丁酸酐制备二甲基十六烯，然后制备聚二甲基鲸烯的方法公开(公告)号：US07435856B2
公开(公告)日：2008-10-14
申请号：US10545977
申请日：2004-02-20
IPC分类号： C07C45/87
摘要： The present invention relates to a process for the preparation of dimethylketene (DMK) and then of polydimethylketene (PDMK) by polymerization of DMK. More specifically, the DMK is obtained by pyrolysis by isobutyric anhydride (IBAN), the latter decomposing under the effect of heat (pyrolysis) to give isobutyric acid (IBA) and DMK. One mole of pyrolyzed IBAN gives one mole of IBA and one mole of DMK.
摘要翻译： 本发明涉及通过DMK的聚合制备二甲基烯酮（DMK），然后制备聚二甲基烯酮（PDMK）的方法。 更具体地说，DMK是通过异丁酸酐（IBAN）的热解得到的，后者在热（热解）的作用下分解，得到异丁酸（IBA）和DMK。 1摩尔热解的IBAN得到1摩尔IBA和1摩尔DMK。
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