摘要:
A process for preparing aqueous polymer dispersions comprises first of all subjecting ethylenically unsaturated monomers to free-radical aqueous emulsion polymerization to prepare an aqueous dispersion of a polymer 1 having a glass transition temperature Tg1, then dissolving further, comparatively hard monomers in the dispersed particles of the polymer 1, and subsequently carrying out free-radical polymerization of the monomers dissolved in the particles.
摘要:
Polymers composed of at least >80% by weight of monomers of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.3 -alkyl,R.sup.4 is C.sub.1 -C.sub.5 -alkyl andX is 0 or NH,are used as assistants in the drying of aqueous polymer dispersions and, in the case of a weight average relative molecular weight of from 5000 to 35,000, additionally as protective colloid for the preparation of aqueous polymer dispersions by the free radical aqueous emulsion polymerization method.
摘要:
Polymers I comprising from 15 to 80% by weight of monomers of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.3 -alkyl, R.sup.4 is C.sub.1 -C.sub.5 -alkyl and X is O or NH, andfrom 20 to 85 % by weight of other monomers capable of undergoing free radical copolymerizationare used as assistants in the spray drying of aqueous dispersions of polymers II which differ from the polymers I.
摘要:
The present invention provides aqueous emulsion polymers comprising (A) monomers A (B) at least one (meth)acrylate with olefinically unsaturated side groups (monomers B), and (C) at least one photoinitiator, and also the use thereof in coating materials, more particularly in exterior architectural paints.
摘要:
The present invention relates to polymer dispersions which comprise highly branched polycarbonates, to a process for preparing them, and to their use.
摘要:
A compound needle includes a shank having an end; a hook formed on the shank at the shank end and having a hook tip; and a closing element slot provided in the shank and being defined by two parallel shank flanks. The closing element slot extends from a location adjacent the hook in a direction away therefrom. The compound needle further has an elongated closing element received in the closing element slot for longitudinal sliding motions therein. The closing element has a hook-closing position in which the closing element is situated in an immediate vicinity of the hook tip. The closing element is composed of at least two side-by-side disposed, resilient closing element parts each having a free terminal leg oriented toward the hook. The terminal legs are bent away from one another to define a relatively narrow funnel having an open end oriented toward the hook and a beginning spaced from the open funnel end. The closing element parts are bent away from one another from the beginning of the funnel in a rearward direction away from the hook for resiliently contacting respective slot flanks at contact locations. The contact locations are situated adjacent the beginning of the closing element slot when the closing element is in its hook-closing position.
摘要:
Polymers I comprising from 15 to 80% by weight of monomers of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.3 -alkyl, R.sup.4 is C.sub.1 -C.sub.3 -alkyl and X is O or NH, and from 20 to 85% by weight of other monomers capable of undergoing free radical copolymerization are used as assistants in the spray drying of aqueous dispersions of polymers II which differ from the polymers I. The resultant powders are added to mineral binders.
摘要:
Microcapsules comprise a polymeric wall material and a polymeric core material which is suitable as a leveling agent for film formation by film-forming oligomers and polymers.
摘要:
The invention relates to copolymers containinga) 20-90% of 2-acrylamido-2-methylpropanesulfonic acid, sulfoethyl or sulfopropyl (meth) acrylate or vinylsulfonic acid,b) 0-50% of a vinylic acid,c) 0-70% of methyl or ethyl acrylate or methacrylate, C.sub.2 --C.sub.4 -hydroxyalkyl acrylate or N-vinylpyrrolidone andd) 0.1-10% of styrene or C.sub.4 --C.sub.18 -alkyl acrylate or C.sub.4 --C.sub.18 -alkyl methacrylate.The copolymers according to the invention are particularly suitable as protective colloids for microencapsulation.
摘要:
The invention also relates to a method to increase stain resistance and penetration resistance of aqueous coating compositions which method comprises providing a coating composition which contain at least one pigment, at least one film-forming polymer in the form of an aqueous polymer dispersion and at least one anionic surfactant, wherein the anionic surfactant comprises at least 85% by weight, preferably at least 90% by weight, more preferably at least 95% by weight, based on the total weight of anionic surfactant in the coating composition, of at least one anionic surfactant S, which is selected from semi-esters of sulfuric acid or phosphoric acid with an alcohol, which alcohol carries at least one alkyl radical having from 8 to 30 carbon atoms or an alkyl substituted phenyl radical wherein alkyl has from 4 to 30 carbon atoms and which alcohol may carry an oligo-C2-C3-alkylene-ether group provided that the number of repeating units in the oligo-C2-C3-alkylene-ether group is at most 15, or a salt thereof.