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    Molecular sieve compositions
    11.
    发明授权
    Molecular sieve compositions 失效
    分子筛组成

    公开(公告)号：US4956165A

    公开(公告)日：1990-09-11

    申请号：US196541

    申请日：1988-05-20

    申请人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Stephen T. Wilson ,  Edith M. Flanigen

    发明人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Stephen T. Wilson ,  Edith M. Flanigen

    IPC分类号： B01J29/84 ,  B01J29/85 ,  C01B25/45 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/22 ,  C07C5/27 ,  C07C5/41

    CPC分类号： C07C5/41 ,  B01J29/84 ,  B01J29/85 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/224 ,  C07C5/2716 ,  C01B39/00 ,  C07C2527/173 ,  C07C2529/84

    摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MO.sub.2.sup.n, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and/or titanium, and at least one of cobalt, magnesium, manganese and zinc; "n" is 0, -1 or -2; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

    摘要翻译： 公开了具有MO2n，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和/或钛，以及钴，镁，锰和锌中的至少一种; “n”为0，-1或-2; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。

    Molecular sieve compositions
    12.
    发明授权
    Molecular sieve compositions 失效
    分子筛组成

    公开(公告)号：US4952384A

    公开(公告)日：1990-08-28

    申请号：US197407

    申请日：1988-05-20

    申请人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Stephen T. Wilson ,  Edith M. Flanigen

    发明人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Stephen T. Wilson ,  Edith M. Flanigen

    IPC分类号： B01J29/84 ,  B01J29/85 ,  C01B25/45 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/22 ,  C07C5/27 ,  C07C5/41

    CPC分类号： C07C5/41 ,  B01J29/84 ,  B01J29/85 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/224 ,  C07C5/2716 ,  C01B39/00 ,  C07C2527/173 ,  C07C2529/84

    摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MO.sub.2.sup.n, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR : (M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and/or titanium, and at least one of cobalt, magnesium, manganese and zinc; "n" is O, -1 or -2; "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represent the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

    摘要翻译： 公开了具有MO2n，AlO2和PO2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和/或钛，以及钴，镁，锰和锌中的至少一种; “n”为O，-1或-2; “m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。

    Iron-titanium-aluminum-phosphorus-oxide molecular sieve compositions
    13.
    发明授权
    Iron-titanium-aluminum-phosphorus-oxide molecular sieve compositions 失效
    铁 - 钛 - 铝 - 氧化磷分子筛组成

    公开(公告)号：US4917876A

    公开(公告)日：1990-04-17

    申请号：US195474

    申请日：1988-05-17

    申请人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Edith M. Flanigen

    发明人： Brent M. T. Lok ,  Bonita K. Marcus ,  Celeste A. Messina ,  Edith M. Flanigen

    IPC分类号： B01J29/84 ,  C01B25/45

    CPC分类号： B01J29/84 ,  C01B39/00

    摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of FeO.sub.2, TiO.sub.2, AlO.sub.2, and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR:(M.sub.x Al.sub.y P.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "M" represents iron and titanium, "m" represents the molar amount of "R" present per mole of (M.sub.x Al.sub.y P.sub.z)O.sub.2 ; and "x", "y" and "z" represnt the mole fractions of "M", aluminum and phosphorus, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

    摘要翻译： 公开了具有FeO 2，TiO 2，AlO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，由下式表示：mR：（MxAlyPz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “M”表示铁和钛，“m”表示每摩尔（M×AlyPz）O 2存在的“R”摩尔量; 和“x”，“y”和“z”分别表示作为四面体氧化物存在的“M”，铝和磷的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。

    Manganese-aluminum-phosphorus-silicon-oxide Molecular sieves
    14.
    发明授权
    Manganese-aluminum-phosphorus-silicon-oxide Molecular sieves 失效
    锰 - 铝 - 磷 - 氧化硅分子筛

    公开(公告)号：US4846956A

    公开(公告)日：1989-07-11

    申请号：US250407

    申请日：1988-09-28

    申请人： Brent M. Lok ,  Bonita K. Marcus ,  Edith M. Flanigen

    发明人： Brent M. Lok ,  Bonita K. Marcus ,  Edith M. Flanigen

    IPC分类号： B01J29/85 ,  C01B37/08 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/22 ,  C07C5/27 ,  C07C5/41

    CPC分类号： C07C5/41 ,  B01J29/85 ,  C01B37/08 ,  C07C2/12 ,  C07C2/54 ,  C07C5/02 ,  C07C5/224 ,  C07C5/2716 ,  C07C2527/173 ,  C07C2529/84

    摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of MnO.sub.2, AlO.sub.2, SiO.sub.2 and PO.sub.2 tetrahedral oxide units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Mn.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of manganese, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents, catalysts, etc. is also disclosed.

    摘要翻译： 公开了具有MnO 2，AlO 2，SiO 2和PO 2四面体氧化物单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有无水基础上的经验化学组成，其由下式表示：mR：（MnwAlxPySiz）O 2其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（MnwAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的锰，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂，催化剂等的用途。

    Catalytic uses of crystalline metallophosphate compositions
    16.
    发明授权
    Catalytic uses of crystalline metallophosphate compositions 失效
    结晶金属磷酸盐组合物的催化用途

    公开(公告)号：US4898660A

    公开(公告)日：1990-02-06

    申请号：US544080

    申请日：1983-10-20

    申请人： Stephen T. Wilson ,  Brent M. Lok ,  Edith M. Flanigen

    发明人： Stephen T. Wilson ,  Brent M. Lok ,  Edith M. Flanigen

    IPC分类号： B01D15/00 ,  B01D53/28 ,  B01J27/18 ,  B01J29/84 ,  C01B37/04 ,  C07C2/54 ,  C07C5/02 ,  C07C5/22 ,  C07C5/27

    CPC分类号： C07C5/224 ,  B01D15/00 ,  B01D53/28 ,  B01J20/0292 ,  B01J20/08 ,  B01J27/18 ,  B01J29/84 ,  C01B37/04 ,  C07C2/54 ,  C07C5/02 ,  C07C5/2716 ,  C07C2529/83

    摘要： A novel family of crystalline, microporus aluminophosphate compositions is synthesized by hydrothermal crystallization at elevated temperatures of aluminophosphate gels containing a molecular structure forming template. The family comprises a number of distinct species, each with a unique crystal structure. Calcination removes volatile extraneous matter from the intracrystalline void space and yields microporus crystalline adsorbents with uniform pores, the dimensions of which vary, among the individual species, from about 3A to 10A diameter. The composition exhibit properties somewhat analogous to zeolitic molecular sieves which render them useful as catalysts or catalyst bases in chemical reactions such as hydrocarbon conversions.

    摘要翻译： 通过在含有分子结构形成模板的磷酸铝凝胶的升高的温度下通过水热结晶合成了一种新型的晶体，微孔磷酸铝组合物。 家庭包括许多不同的物种，每个都有独特的晶体结构。 煅烧从晶体间隙空间中去除挥发性外来物质，并产生具有均匀孔隙的微孔结晶吸附剂，其尺寸在单个物种之间变化，从约3A至10A直径。 该组合物显示出与沸石分子筛有些类似的性质，使得它们可用作化学反应如烃转化中的催化剂或催化剂碱。

    Acetylene vessel filler composition
    19.
    发明授权
    Acetylene vessel filler composition 失效
    乙炔容器填料组成

    公开(公告)号：US4129450A

    公开(公告)日：1978-12-12

    申请号：US849896

    申请日：1977-11-09

    申请人： Edith M. Flanigen ,  Brent M. Lok ,  Norbert R. Mumbach

    发明人： Edith M. Flanigen ,  Brent M. Lok ,  Norbert R. Mumbach

    IPC分类号： C04B28/20 ,  C10L3/04 ,  F17C11/00 ,  C04B7/34

    CPC分类号： F17C11/002 ,  C04B28/18 ,  C10L3/04

    摘要： An aqueous slurry composition which is curable at saturated steam pressure and temperature of 360.degree. to 400.degree. F to form a hard porous mass suitable for containing dissolved acetylene gas solutions, comprising lime, crystalline silica, and a thickening agent selected from the group consisting of (a) polyethylene oxide, (b) amorphous glassy silica, (c) a soluble salt of phosphate and a soluble salt of calcium and (d) a soluble salt of phosphate and a neutralizing acid.

    摘要翻译： 一种含水浆料组合物，其在饱和蒸汽压力和360°至400°F的温度下可固化，以形成适于含有溶解的乙炔气体溶液的硬质多孔体，其包含石灰，结晶二氧化硅和选自以下的增稠剂： （a）聚环氧乙烷，（b）无定形玻璃状二氧化硅，（c）可溶性磷酸盐和钙的可溶性盐，和（d）磷酸盐和中和酸的可溶性盐。