公开(公告)号：US08314040B2

公开(公告)日：2012-11-20

申请号：US10706809

申请日：2003-11-12

申请人： C. Allen Smith ,  Kenneth B. Close ,  Richard C. Beck ,  Jay S. Shultz ,  David J. Baer ,  Susan E. Shawver ,  Paul W. Estey ,  Deepak R. Parikh ,  Kenneth B. Stewart, Jr.

发明人： C. Allen Smith ,  Kenneth B. Close ,  Richard C. Beck ,  Jay S. Shultz ,  David J. Baer ,  Susan E. Shawver ,  Paul W. Estey ,  Deepak R. Parikh ,  Kenneth B. Stewart, Jr.

IPC分类号： D04H3/00

CPC分类号： B32B27/12 ,  B32B5/26 ,  B32B27/32 ,  B32B2262/0253 ,  B32B2305/20 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2432/00 ,  C08L23/0815 ,  C08L23/10 ,  C08L2205/02 ,  D04H1/559 ,  D04H1/56 ,  Y10T442/601 ,  Y10T442/602 ,  Y10T442/607 ,  Y10T442/66 ,  Y10T442/664 ,  Y10T442/674 ,  Y10T442/678 ,  Y10T442/68 ,  Y10T442/681 ,  Y10T442/696 ,  Y10T442/697 ,  C08L2666/04

摘要： A nonwoven web made from a polymeric fiber blend comprising at least one elastomeric polyolefin and at least one nonelastomeric polyolefin useful as the elastic base sheet for a nonwoven laminate is disclosed. Preferably, the polymeric blend will comprise a nonelastomeric resin in the range of from about 10 to about 90 percent by weight, and an elastomeric resin of from about 90 to about 10 percent by weight. The elastomeric polyolefin will have a density of less than about 0.885 g/cm3 and the nonelastomeric polyolefin will have a density of at least about 0.890 g/cm3. In one particular embodiment, the polymeric blend may comprise about 50 percent to about 90 percent by weight of a narrow molecular weight distribution polyethylene and about 50 percent to about 10 percent by weight of a nonelastomeric polyolefin such as a linear low density polyethylene.

摘要翻译： 公开了一种由包含至少一种弹性体聚烯烃和至少一种非弹性聚烯烃制成的非织造纤维网，该非弹性聚烯烃可用作非织造层压材料的弹性基片。 优选地，聚合物共混物将包含约10-约90重量％范围内的非弹性体树脂和约90至约10重量％的弹性体树脂。 弹性体聚烯烃的密度小于约0.885g / cm 3，非弹性聚烯烃的密度至少约为0.890g / cm3。 在一个具体实施方案中，聚合共混物可以包含约50重量％至约90重量％的窄分子量分布聚乙烯和约50重量％至约10重量％的非弹性聚烯烃，例如线性低密度聚乙烯。

公开(公告)号：US08045918B2

公开(公告)日：2011-10-25

申请号：US10934912

申请日：2004-09-02

申请人： Deepak R. Parikh ,  Joseph R. Cleveland ,  Purva R. Rajkotia

发明人： Deepak R. Parikh ,  Joseph R. Cleveland ,  Purva R. Rajkotia

IPC分类号： H04B7/15

CPC分类号： H04W88/04 ,  H04B7/155 ,  H04W88/02

摘要： A proxy mobile station for retransmitting reverse channel signals from a mobile station to a base station of a wireless network. The proxy mobile station comprises: 1) a controller for receiving reverse channel data to be transmitted to the base station and transmitting the reverse channel data using an assigned mobile station identifier associated with the mobile station; and 2) a radio frequency transceiver for up-converting the encoded reverse channel data for transmission to the base station. The assigned mobile station is modifiable and may be modified by an external control device.

摘要翻译： 一种用于从移动台向无线网络的基站重传反向信道信号的代理移动站。 代理移动台包括：1）控制器，用于接收要发送到基站的反向信道数据，并使用与移动台相关联的分配的移动台标识符发送反向信道数据; 以及2）射频收发器，用于对编码的反向信道数据进行上变频以传输到基站。 分配的移动台是可修改的，并且可以由外部控制设备修改。

公开(公告)号：US06916883B2

公开(公告)日：2005-07-12

申请号：US10931821

申请日：2004-09-01

申请人： Deepak R. Parikh ,  Brian W. S. Kolthammer ,  Robert S. Cardwell

发明人： Deepak R. Parikh ,  Brian W. S. Kolthammer ,  Robert S. Cardwell

IPC分类号： C08F4/642 ,  C08F4/60 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F297/08 ,  C08L23/08 ,  C08F8/00 ,  C08F210/00 ,  C08L23/00 ,  C08L23/04

CPC分类号： C08F297/08 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/06 ,  C08F4/65916 ,  C08F2/34 ,  C08F2500/12 ,  C08F2500/03 ,  C08L2666/04

摘要： A new process of interpolymerizing ethylene interpolymer products having improved properties, such as increased onset of crystallization temperature, is disclosed. Preferably, the process comprises interpolymerizing a first homogeneous ethylene/alpha-olefin interpolymer and at least one second homogeneous ethylene/alpha-olefin interpolymer using at least two constrained geometry catalysts having different reactivities such that the first ethylene/alpha-olefin interpolymer has a narrow molecular weight distribution (NMWD) with a very high comonomer content and relatively high molecular weight and the second ethylene/alpha-olefin interpolymer has a NMWD with a low comonomer content and a molecular weight lower than that of the first interpolymer. The resultant first homogeneous interpolymer is combined with the resultant second homogeneous interpolymer in appropriate weight ratios resulting in the desired finished polymer structure. The first interpolymer and the second interpolymer can be polymerized in a single reactor or they can be polymerized in separate reactors operated in parallel or series.

摘要翻译： 公开了具有改进性能的乙烯互聚物产物的新聚合方法，例如结晶温度的开始增加。 优选地，该方法包括使用具有不同反应性的至少两种约束几何催化剂使第一均匀乙烯/α-烯烃互聚物和至少一种第二均相乙烯/α-烯烃互聚物互聚，使得第一乙烯/α-烯烃互聚物具有窄的 具有非常高的共聚单体含量和相对高分子量的分子量分布（NMWD），第二乙烯/α-烯烃互聚物具有低共聚单体含量低于第一互聚物的分子量的NMWD。 将所得第一均匀互聚物与所得的第二均相互聚物以适当的重量比组合，得到所需的最终聚合物结构。 第一互聚物和第二互聚物可以在单个反应器中聚合，或者它们可以在并行或串联操作的分离的反应器中聚合。

公开(公告)号：US06566446B1

公开(公告)日：2003-05-20

申请号：US08932771

申请日：1997-09-18

申请人： Deepak R. Parikh ,  Robert S. Cardwell ,  Brian W. S. Kolthammer

发明人： Deepak R. Parikh ,  Robert S. Cardwell ,  Brian W. S. Kolthammer

IPC分类号： C08F4642

CPC分类号： C08F297/08 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2308/00 ,  C08L2314/06 ,  C08L2666/06 ,  C08F4/65916 ,  C08F2/34 ,  C08F2500/12 ,  C08F2500/03 ,  C08L2666/04

摘要： A new process of interpolymerizing ethylene interpolymer products having improved properties, such as increased onset of crystallization temperature, is disclosed. Preferably, the process comprises interpolymerizing a first homogeneous ethylene/alpha-olefin interpolymer and at least one second homogeneous ethylene/alpha-olefin interpolymer using at least two constrained geometry catalysts having different reactivities such that the first ethylene/alpha-olefin interpolymer has a narrow molecular weight distribution (NMWD) with a very high comonomer content and relatively high molecular weight and the second ethylene/alpha-olefin interpolymer has a NMWD with a low comonomer content and a molecular weight lower than that of the first interpolymer. The resultant first homogeneous interpolymer is combined with the resultant second homogeneous interpolymer in appropriate weight ratios resulting in the desired finished polymer structure. The first interpolymer and the second interpolymer can be polymerized in a single reactor or they can be polymerized in separate reactors operated in parallel or series.

公开(公告)号：US06545088B1

公开(公告)日：2003-04-08

申请号：US08679538

申请日：1996-07-12

申请人： Brian W. S. Kolthammer ,  Robert S. Cardwell ,  Deepak R. Parikh ,  Morris S. Edmondson ,  Stanley W. Smith

发明人： Brian W. S. Kolthammer ,  Robert S. Cardwell ,  Deepak R. Parikh ,  Morris S. Edmondson ,  Stanley W. Smith

IPC分类号： C08F214

CPC分类号： C08F297/08 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  C08F210/18 ,  C08L23/0815 ,  C08L23/16 ,  C08F2/14 ,  C08F2/001 ,  C08F2/00 ,  C08F210/06 ,  C08F2500/25 ,  C08F4/65916 ,  C08F2/34 ,  C08L2666/04 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2/06

摘要： Ethylene, an &agr;-olefin and, optionally, a diene monomer are polymerized in a process comprising the step of contacting (1) ethylene, (2) at least one C3-C20 aliphatic &agr;-olefin, (3) optionally, at least one C4-C20 diene, (4) a catalyst comprising (a) a metallocene complex, and (b) an activator, and (5) a solvent. The process is conducted in either a single reactor or in multiple reactors, the latter configured either in series or parallel. Solvent is removed from the polymer stream in an anhydrous, first stage solvent recovery operation such that the solids concentration of the product stream is increased by at least 100 percent. Additional solvent is removed in an anhydrous, second stage solvent recovery operation from the product of the first stage solvent recovery operation such that the solids concentration of the product stream is in excess of 65 weight percent.

摘要翻译： 乙烯，α-烯烃和任选的二烯单体在包括使（1）乙烯，（2）至少一种C 3 -C 20脂族α-烯烃，（3）任选的至少一种 C4-C20二烯，（4）包含（a）茂金属络合物和（b）活化剂的催化剂，和（5）溶剂。 该方法在单个反应器或多个反应器中进行，后者配置为串联或并联。 在无水的第一阶段溶剂回收操作中从聚合物流中除去溶剂，使得产物流的固体浓度增加至少100％。 在第一阶段溶剂回收操作的产物的无水第二阶段溶剂回收操作中除去另外的溶剂，使得产物流的固体浓度超过65重量％。

公开(公告)号：US06420507B1

公开(公告)日：2002-07-16

申请号：US09070957

申请日：1998-05-01

申请人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

发明人： Lawrence T. Kale ,  Daniel D. Vanderlende ,  Peter N. Nickias ,  Jasson T. Patton ,  James C. Stevens ,  Deepak R. Parikh ,  Debra J. Mangold

IPC分类号： C08F1000

CPC分类号： C08F210/18 ,  C07F17/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/19 ,  C08F210/06 ,  C08F236/20 ,  C08F2500/25 ,  C08F2500/20

摘要： The subject invention is directed to an olefin polymer produced by polymerizing at least one &agr;-olefin in the presence of a Group 4 metal complex comprising an indenyl group substituted in the 2 or 3 position with at least one group selected from hydrocarbyl, perfluoro-substituted hydrocarbyl, silyl, germyl and mixtures thereof, said indenyl group further being covalently bonded to the metal by means of a divalent ligand group, wherein the divalent ligand comprises nitrogen or phosphorus having an aliphatic or alicyclic hydrocarby group covalently bonded thereto via a primary or secondary carbon. Preferred olefin polymers of the invention will be characterized as having a high molecular weight, narrow molecular weight distribution, high vinyl content, and a bimodal DSC melting curve or a deconvoluted ATREF or GPC curve which shows at least two distinct narrow peaks. The olefin polymer will have utility in a variety of applications, including but not limited to films, fibers, foams, molded parts, and as components of formulations such as adhesives, sealants, coatings, caulks, and asphalt.

摘要翻译： 本发明涉及通过在包含在2或3位被取代的茚基的第4族金属络合物与至少一种选自烃基，全氟取代基的基团的存在下聚合至少一种α-烯烃制备的烯烃聚合物 烃基，甲硅烷基，甲基和其混合物，所述茚基还通过二价配体基团与金属共价结合，其中二价配体包含具有通过伯或仲二价共价键合的脂族或脂环族烃基的氮或磷 碳。 本发明优选的烯烃聚合物的特征在于具有高分子量，窄分子量分布，高乙烯基含量和双峰DSC熔解曲线或解卷积的ATREF或GPC曲线，其显示出至少两个不同的窄峰。 烯烃聚合物可用于各种应用，包括但不限于薄膜，纤维，泡沫，模制部件，以及作为配方的组分，例如粘合剂，密封剂，涂料，填缝剂和沥青。

公开(公告)号：US06403710B1

公开(公告)日：2002-06-11

申请号：US09690039

申请日：2000-10-16

申请人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

发明人： Wasif K. Ahmed ,  Stephen R. Betso ,  Antonio Batistini ,  Martin J. Guest ,  Thoi H. Ho ,  Deepak R. Parikh ,  George W. Knight ,  Rajen M. Patel

IPC分类号： C08L900

CPC分类号： C09D153/02 ,  C08L23/0815 ,  C08L53/02 ,  C08L2314/06 ,  C08L2666/02 ,  C08L2666/04 ,  C09J153/02

摘要： The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.

摘要翻译： 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物，其中组合物与组合物未未改性的未稀释（纯）嵌段共聚物部分具有基本上相同的比较弹性，高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性，并且非常适用于制造弹性模制品，薄膜和纤维，以及用沥青，粘合剂和密封剂配制。 新型热塑性弹性体组合物包含（a）约50至约99重量％的至少一种嵌段共聚物和（b）约1至约50重量％的至少一种乙烯互聚物，其密度约为0.855克/ cc至约0.905g / cc，其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂，组合物进一步表征为具有： 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2，ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4，和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。

公开(公告)号：US06723810B2

公开(公告)日：2004-04-20

申请号：US10026158

申请日：2001-12-21

申请人： Malcolm F. Finlayson ,  Craig C. Garrison ,  Ralph E. Guerra ,  Martin J. Guest ,  Brian W. S. Kolthammer ,  Deepak R. Parikh ,  Steven M. Ueligger

发明人： Malcolm F. Finlayson ,  Craig C. Garrison ,  Ralph E. Guerra ,  Martin J. Guest ,  Brian W. S. Kolthammer ,  Deepak R. Parikh ,  Steven M. Ueligger

IPC分类号： C08F444

CPC分类号： C08F10/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/02 ,  C08F210/16 ,  Y10S526/901 ,  Y10S526/943 ,  C08F210/14 ,  C08F2500/08 ,  C08F2500/03 ,  C08F2500/12 ,  C08F2500/02 ,  C08F2500/01

摘要： Process for making a non-pourable ultra-low molecular weight ethylene polymer composition and blends thereof. Such polymer compositions tend to have longer lamella and a greater degree of crystalline organization than corresponding higher molecular weight materials at an equivalent density.

摘要翻译： 制备不可倾倒的超低分子量乙烯聚合物组合物及其共混物的方法。 这种聚合物组合物倾向于具有比等效密度的相应较高分子量材料更长的层片和更大程度的结晶组织。

公开(公告)号：US06680265B1

公开(公告)日：2004-01-20

申请号：US09511403

申请日：2000-02-21

申请人： C. Allen Smith ,  Kenneth B. Close ,  Richard C. Beck ,  Jay S. Shultz ,  David J. Baer ,  Susan E. Shawver ,  Paul W. Estey ,  Deepak R. Parikh ,  Kenneth B. Stewart, Jr.

发明人： C. Allen Smith ,  Kenneth B. Close ,  Richard C. Beck ,  Jay S. Shultz ,  David J. Baer ,  Susan E. Shawver ,  Paul W. Estey ,  Deepak R. Parikh ,  Kenneth B. Stewart, Jr.

IPC分类号： D04H316

CPC分类号： B32B27/12 ,  B32B5/26 ,  B32B27/32 ,  B32B2262/0253 ,  B32B2305/20 ,  B32B2323/046 ,  B32B2323/10 ,  B32B2432/00 ,  C08L23/0815 ,  C08L23/10 ,  C08L2205/02 ,  D04H1/559 ,  D04H1/56 ,  Y10T442/601 ,  Y10T442/602 ,  Y10T442/607 ,  Y10T442/66 ,  Y10T442/664 ,  Y10T442/674 ,  Y10T442/678 ,  Y10T442/68 ,  Y10T442/681 ,  Y10T442/696 ,  Y10T442/697 ,  C08L2666/04

摘要： A nonwoven web made from a polymeric fiber blend comprising at least one elastomeric polyolefin and at least one nonelastomeric polyolefin useful as the elastic base sheet for a nonwoven laminate is disclosed. Preferably, the polymeric blend will comprise a nonelastomeric resin in the range of from about 10 to about 90 percent by weight, and an elastomeric resin of from about 90 to about 10 percent by weight. The elastomeric polyolefin will have a density of less than about 0.885 g/cm3 and the nonelastomeric polyolefin will have a density of at least about 0.890 g/cm3. In one particular embodiment, the polymeric blend may comprise about 50 percent to about 90 percent by weight of a narrow molecular weight distribution polyethylene and about 50 percent to about 10 percent by weight of a nonelastomeric polyolefin such as a linear low density polyethylene.

摘要翻译： 公开了一种由包含至少一种弹性体聚烯烃和至少一种非弹性聚烯烃制成的非织造纤维网，该非弹性聚烯烃可用作非织造层压材料的弹性基片。 优选地，聚合物共混物将包含约10-约90重量％范围内的非弹性体树脂和约90至约10重量％的弹性体树脂。 弹性体聚烯烃的密度小于约0.885g / cm 3，非弹性聚烯烃的密度至少约为0.890g / cm 3。 在一个具体实施方案中，聚合共混物可以包含约50重量％至约90重量％的窄分子量分布聚乙烯和约50重量％至约10重量％的非弹性聚烯烃，例如线性低密度聚乙烯。

公开(公告)号：US06462161B1

公开(公告)日：2002-10-08

申请号：US09180414

申请日：1998-11-06

申请人： Larry D. Cady ,  Christopher J. Frye ,  Philip Howard ,  Teresa P. Karjala ,  Peter J. Maddox ,  Ian M. Munro ,  Deepak R. Parikh ,  S. Roy Partington ,  Kevin P. Peil ,  Lee Spencer ,  William R. Van Volkenburgh ,  Peter S. Williams ,  David R. Wilson ,  J. Mark Winter

发明人： Larry D. Cady ,  Christopher J. Frye ,  Philip Howard ,  Teresa P. Karjala ,  Peter J. Maddox ,  Ian M. Munro ,  Deepak R. Parikh ,  S. Roy Partington ,  Kevin P. Peil ,  Lee Spencer ,  William R. Van Volkenburgh ,  Peter S. Williams ,  David R. Wilson ,  J. Mark Winter

IPC分类号： C08F1002

CPC分类号： C08F210/00 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65927 ,  C08F210/16 ,  C08F2410/02 ,  C08J5/18 ,  C08J2323/08 ,  C08L23/06 ,  C08L23/0815 ,  C08L2205/02 ,  C08L2205/025 ,  C08L2207/07 ,  C08L2308/00 ,  C08L2314/06 ,  Y10S526/901 ,  Y10S526/916 ,  Y10S526/943 ,  C08L2666/06 ,  C08F210/14 ,  C08F2500/09 ,  C08F2500/20 ,  C08L2666/04

摘要： The invention relates to a polyolefin copolymer composition produced with a catalyst having a metallocene, complex in a single reactor for the polymer of an &agr;-olefin monomer with one or more olefin comonomers, and a molecule weight maximum which occurs in that 50 percent by weight of the composition which has the highest weight percent comonomer content. Preferably, the composition has a comonomer partitioning fact Cpf which is equal to or greater than 1.10 or molecule weight partitioning fact Mpf which is equal to or greater than 1.15. Preferred composition also have at least 0.01 long chain branches per 1000 carbon atoms along the polymer backbone. These compositions with reverse molecular engineering have. superior properties and are easily processable due to the simultaneous presence of the association of high molecular weight with high comonomer content and of long chain branching.

摘要翻译： 本发明涉及一种聚烯烃共聚物组合物，该聚烯烃共聚物组合物由具有茂金属的催化剂制备，在具有一种或多种烯烃共聚单体的α-烯烃单体的聚合物的单个反应器中为复合物，分子量最大值为50重量％ 具有最高重量百分比共聚单体含量的组合物。 优选地，组合物具有等于或大于1.10的共聚单体分配事实Cpf或等于或大于1.15的分子量分配事实Mpf。 优选的组合物也沿着聚合物主链每1000个碳原子具有至少0.01个长链分支。 这些具有反向分子工程的组合物具有。 优异的性能并且由于高分子量与高共聚单体含量和长链支化的结合的同时存在而容易加工。