Partial oxidation process with production of power
    11.
    发明授权
    Partial oxidation process with production of power 失效
    部分氧化工艺生产电源

    公开(公告)号:US5345756A

    公开(公告)日:1994-09-13

    申请号:US139367

    申请日:1993-10-20

    摘要: A highly efficient partial oxidation process with the production of power comprising the steps of producing fuel gas by the partial oxidation of hydrocarbonaceous fuel, cooling said fuel gas at high pressure by quenching in water to produce quenched fuel gas and by indirect heat exchange with BFW to maximize the production of IP and MP steam, cleaning said fuel gas, preheating scrubbing water comprising process condensate and make-up water by direct contact and direct heat exchange with clean fuel gas and using said preheated scrubbing water in the cleaning of said fuel gas, reducing the pressure of said cooled fuel gas stream prior to heating water for fuel gas saturation, cooling the process fuel gas stream in stages and condensing water for use as said scrubbing water, purifying the process fuel gas and saturating it with water, and burning said purified and saturated fuel gas in the combustor of a power-producing gas turbine along with saturated nitrogen to produce exhaust gas with a reduced NO.sub.x. In one embodiment, the hot exhaust gas from the gas turbine is passed through a HRSG to superheat the process steam. The superheated process steam is then used as part of the working fluid in an expansion turbine for the production of power. Steam condensate may be converted into high pressure (HP) steam and superheated in the HRSG. The power generation steam cycle is optimized to assist in maximizing the process steam which can be used most efficiently in the cycle.

    摘要翻译: 一种生产动力的高效部分氧化过程包括以下步骤:通过烃类燃料的部分氧化生产燃料气体,通过在水中淬火冷却所述燃料气体以产生淬火的燃料气体,并通过与BFW的间接热交换 最大化IP和MP蒸汽的生产,清洁所述燃料气体,通过直接接触和与清洁燃料气体直接热交换并使用所述预热的洗涤水来清洁所述燃料气体,将包含工艺冷凝物和补充水的预热洗涤水, 在加热用于燃料气体饱和的水之前降低所述冷却的燃料气体流的压力,分阶段冷却过程燃料气体流并冷凝水以用作所述洗涤水,净化工艺燃料气体并使其用水饱和,并燃烧所述 在发电燃气轮机的燃烧器中与饱和氮气一起产生净化和饱和的燃料气体以产生废气 减少NOx。 在一个实施例中,来自燃气轮机的热废气通过HRSG以过程蒸汽过热。 然后将过热蒸汽作为用于生产电力的膨胀涡轮机中的工作流体的一部分。 蒸汽冷凝物可以转化成高压(HP)蒸汽并在HRSG中过热。 优化发电蒸汽循环以帮助最大限度地提高循环中最有效的过程蒸汽。

    Partial oxidation process
    12.
    发明授权
    Partial oxidation process 失效
    部分氧化工艺

    公开(公告)号:US4547203A

    公开(公告)日:1985-10-15

    申请号:US595103

    申请日:1984-03-30

    IPC分类号: C10J3/46

    摘要: A process is provided for the partial oxidation of a high metals or ash containing liquid hydrocarbonaceous fuel or a slurry of solid carbonaceous fuel to simultaneously produce saturated and unsaturated raw streams of synthesis gas, reducing gas, or fuel gas. Two continuous partial oxidation reactions in two separate reaction zones go on simultaneously. The fuel feed to the first partial oxidation zone is said fresh high metals or ash containing fuel. The raw product gas stream from the first partial oxidation zone is split into first and second split gas streams. The first split gas stream may be cooled in a radiant and/or convection type gas cooler without fouling heat exchange surfaces. The fuel feed to the second partial oxidation zone is a pumpable slurry which is prepared from the entrained matter that is separated from said gas streams during quench cooling and cleaning operations and which contains a comparatively high amount of metals and/or ash. The partial oxidation reaction takes place in the second partial oxidation zone in a reducing atmosphere that includes the second split raw product gas stream from the first partial oxidation zone. By the subject process, there is a reduction in the unconverted carbon produced without any significant loss in efficiency. Further, the life of the cooler for the raw product gas stream is increased.

    摘要翻译: 提供了用于部分氧化高金属或灰分的液体烃类燃料或固体碳质燃料的浆料以同时产生饱和和不饱和的原料合成气流,还原气体或燃料气体的方法。 两个不同反应区的两次连续部分氧化反应同时进行。 向第一部分氧化区的燃料进料是所述新鲜的高金属或含灰分的燃料。 来自第一部分氧化区的原料气流被分成第一和第二分离气流。 第一分流气流可以在辐射和/或对流型气体冷却器中冷却,而不会污染热交换表面。 到第二部分氧化区域的燃料进料是可泵送的浆料,其由在淬火冷却和清洁操作期间与所述气流分离并且含有相对高量的金属和/或灰分的夹带物质制备。 部分氧化反应在包括来自第一部分氧化区的第二裂解原料气流的还原气氛中在第二部分氧化区进行。 通过主题过程,未转化的碳的产生减少,效率没有明显的损失。 此外,原料气流的冷却器的寿命增加。

    Combination with a high temperature combustion chamber and top burner
    13.
    发明授权
    Combination with a high temperature combustion chamber and top burner 失效
    与高温燃烧室和顶部燃烧器组合

    公开(公告)号:US4547145A

    公开(公告)日:1985-10-15

    申请号:US473470

    申请日:1983-03-09

    IPC分类号: C10J3/48 G01J5/04 F23D5/12

    摘要: In the combination of a high temperature combustion chamber which has a burner at the top, there is a radiant energy conduit that is associated with the burner so as to receive radiant energy from the interior of the combustion chamber. The burner introduces the constituents of a synthesis gas generation process. The radiant energy conduit is cooled by its association with the burner, and its purpose is for making temperature measurements inside the chamber.

    摘要翻译: 在顶部具有燃烧器的高温燃烧室的组合中,存在与燃烧器相关联的辐射能导管,以便从燃烧室的内部接收辐射能。 燃烧器引入合成气生成过程的成分。 辐射能量管道通过与燃烧器的关联而被冷却,其目的是在室内进行温度测量。

    Removal of soot in gasification system
    14.
    发明授权
    Removal of soot in gasification system 有权
    气化系统除尘

    公开(公告)号:US06623537B1

    公开(公告)日:2003-09-23

    申请号:US09786788

    申请日:2001-03-09

    IPC分类号: B01D4700

    摘要: The raw syngas generated in a partial oxidation gasifier also includes carbon soot which is removed and recovered from the syngas by scrubbing with water. The scrubbing water contains one or more high temperature surfactants which allow greater soot concentrations in the water-scrubbing quench zone of the gasifier. The carbon soot is separated from the scrubbing water with the aid of a scrubbing oil. The separation of the carbon soot from the scrubbing water is enhanced with the aid of one or more surfactants that render the soot particles hydrophobic and oleophilic. The recovered carbon soot is ultimately recycled to the gasifier to recover the energy value of the carbon during the partial oxidation reaction. The overall energy efficiency of the gasification process can be increased by removing all or a significant portion of the water from the soot mixture before recycling the soot. Separating the soot from the water allows for independent regulation of the soot and water recycle streams, depending on the reaction conditions in the gasifier.

    摘要翻译: 在部分氧化气化器中产生的原始合成气还包括碳烟,其通过用水洗涤从合成气中除去和回收。 洗涤水含有一种或多种高温表面活性剂,其允许在气化器的水洗涤骤冷区域中具有更大的烟灰浓度。 借助于洗涤油将碳烟从洗涤水中分离出来。 借助一种或多种使烟灰颗粒疏水和亲油的表面活性剂,碳烟从洗涤水中分离得到增强。 回收的碳烟灰最终再循环到气化器中以在部分氧化反应期间回收碳的能量值。 在回收烟灰之前,可以通过从烟灰混合物中除去所有或大部分的水来提高气化过程的整体能量效率。 根据气化器中的反应条件,将烟灰与水分离允许烟灰和水循环物流的独立调节。

    Gas cooler for production of superheated steam
    18.
    发明授权
    Gas cooler for production of superheated steam 失效
    用于生产过热蒸汽的气体冷却器

    公开(公告)号:US4488513A

    公开(公告)日:1984-12-18

    申请号:US527458

    申请日:1983-08-29

    IPC分类号: F22B1/18 F28D7/02 F22B1/02

    摘要: A gas cooler and process are provided for the efficient extraction of heat from a hot raw gas stream containing entrained matter from the partial oxidation of a hydrocarbonaceous or carbonaceous fuel, and the simultaneous production of a separate stream of superheated steam. The gas cooler comprises a closed vertical pressure vessel with an upper central outlet through which the superheated steam is removed. A refractory lined hot gas inlet chamber is attached to the bottom of the pressure vessel. A plurality of bundles of helical tubes through which the hot gas flows are spaced in the vessel. The hot gas enters at the bottom of the vessel and the cooled gas leaves at the bottom of the helical coil. A portion of the vessel is filled with boiler feed water so that the bundles of helical tubes are partially submerged. Concurrent and countercurrent indirect heat exchange between boiler feed water and the gas stream takes place in the evaporator section to produce saturated steam. Concurrent and countercurrent indirect heat exchange between the saturated steam and the partially cooled gas stream then takes place in the superheater section to produce superheated steam. Advantageously, the gas cooler may be easily turned up or down with load by opening or closing off at least one of the helical tubes. This may be done by valving located downstream from the gas cooler at the cold end of the gas path.

    摘要翻译: 提供了一种气体冷却器和方法,用于从含烃物质或含碳燃料的部分氧化的含有夹带物质的热原料气流中有效地提取热量,同时生产单独的过热蒸汽流。 气体冷却器包括具有上部中心出口的封闭的垂直压力容器,通过该上部中心出口去除过热蒸汽。 耐火材料衬里的热气体入口室附接到压力容器的底部。 热气体流过的多个螺旋管束在容器中间隔开。 热气体进入容器的底部,冷却的气体离开螺旋线圈的底部。 容器的一部分填充有锅炉给水,使得螺旋管束被部分浸没。 锅炉给水和气体流之间的并流逆流间接热交换发生在蒸发器部分以产生饱和蒸汽。 然后在过热器部分中进行饱和蒸汽和部分冷却的气流之间的并流和逆流间接热交换以产生过热蒸汽。 有利地,气体冷却器可以通过打开或关闭至少一个螺旋管而容易地向上或向下翻转。 这可以通过位于气体通道的冷端处的气体冷却器的下游的阀门来完成。

    Fluidized catalytic cracking process with improved intermediate cycle
gas oil stripping
    20.
    发明授权
    Fluidized catalytic cracking process with improved intermediate cycle gas oil stripping 失效
    流化催化裂化过程与改进的中间循环瓦斯油汽提

    公开(公告)号:US4033856A

    公开(公告)日:1977-07-05

    申请号:US642870

    申请日:1975-12-22

    IPC分类号: C10G7/00 C10G37/00

    CPC分类号: C10G7/00

    摘要: The present application discloses a fluidized catalytic cracking process wherein intermediate cycle gas oil is stripped of light cycle gas oil components employing reboiled intermediate cycle gas oil as stripping vapor for improving light cycle gas oil yield, reducing feed preheat requirements, and reducing sour water production from a fluidized catalytic cracking unit.

    摘要翻译: 本申请公开了一种流化催化裂化方法,其中将中间循环瓦斯油汽提到使用再沸腾的中间循环瓦斯油的轻循环瓦斯油组分作为汽提蒸气,以改善轻循环瓦斯油产量,降低进料预热要求,并减少酸水产生 流化催化裂化装置。