摘要:
The present invention relates to a process and a device for the production of a composite part by the sequential introduction of several fillings (consisting of at least one free-flowing reaction mixture, of which at least one forms a foamed material) into the hollow space of the mold of a closed form tool. A mixing device is attached to form tool. The mixer comprises injector nozzles for the reaction components pointing into a mixing chamber and an ejector piston for the cleaning of the mixer chamber. The ejector piston may be slid forward right up to the outlet orifice of the mixing chamber.
摘要:
The present invention relates to a process for the production of fluorocarbon-free, rigid polyurethane foam moldings having a gross density of at least 300 kg/m.sup.3 by in-mold foaming of a reaction mixture based on(a) a polyisocyanate component containing at least one aromatic polyisocyanate,(b) a polyhydroxyl component,(c) blowing agents,(d) catalysts and(e) zeolitic adsorbents,at an isocyanate index of about 75 to 150, characterized in that(b) an organic polyhydroxyl compound or a mixture of organic polyhydroxyl compounds having an (average) hydroxyl functionality of at least 2.2 and an (average) OH number of at least 300 mg KOH/g is used as the polyhydroxyl component,(c) water and/or carbon dioxide is/are used as the blowing agent and(e) the zeolitic adsorbents have a pore diameter of at least 0.7 nm.
摘要翻译:本发明涉及一种生产无碳氟化合物的硬质聚氨酯泡沫塑料模制品的方法,所述模塑制品的总密度至少为300kg / m 3,基于(a)至少包含至少 一种芳族多异氰酸酯,(b)多羟基组分,(c)发泡剂,(d)催化剂和(e)异氰酸酯指数为约75至150的沸石吸附剂,其特征在于(b)有机多羟基化合物或 使用(平均)羟基官能度为至少2.2的有机多羟基化合物和(平均)OH值为至少300mg KOH / g的有机多羟基化合物的混合物用作多羟基组分,(c)水和/或二氧化碳是 用作发泡剂,(e)沸石吸附剂的孔径至少为0.7nm。
摘要:
This invention relates to a process for the production of polyurethane urea products from isocyanate product blends and preferably less reactive, aromatic diamines, or solutions of aromatic diamines in relatively high molecular weight polyhydroxyl compounds, the reaction components being reacted in a casting process with commercially-reasonable casting times and comparatively short demolding times. For this purpose, relatively high-molecular weight polyhydroxyl compounds, optionally in the presence of low molecular weight diols are reacted with excess quantities of toluene, phenylene or hexamethylene diisocyanate to produce a substantially diisocyanate-free NCO-prepolymer. This NCO-prepolymer is mixed with from 0.1 to 25%, by weight, of less reactive, monomeric tetra-alkyl-diphenylmethane diisocyanates corresponding to the general formula: ##STR1## wherein R.sub.1 to R.sub.4, which may be the same or different, represent C.sub.1 -C.sub.4 alkyl radicals.These isocyanate blends may be easily processed into elastomer moldings having favorable properties in the casting process using moderately-reactive aromatic diamines from the series of di- to tetra-alkyl-diphenylmethane diamines and/or dialkyl-toluene diamines and/or using substituted 3,5-diamino-4-alkyl-benzoic acid alkyl esters, optionally dissolved in the relatively high molecular weight polyhydroxyl compounds.
摘要:
A pneumatic tire comprising an encircling tread and two side members, wherein each side member comprises a side wall having a bead ring and part of the tread backing, characterized in that said tread backing has the following features:(a) the tread backing is formed as a ring which extends to the center of the tire and is intimately joined to the side wall on the other side;(b) bands whose length is substantially equal to the width of said ring are fixed on the circumference of said ring in the center of the tread;(c) the width of said bands is approximately equal to the distance between said bands;(d) there are recesses in the part of said ring facing the tread, into which said bands of the other side fit during assembly, so that said tread backing has a substantially flush surface after assembly; and(e) there are beads on the end of said bands for clamping in the tread.
摘要:
Preparations of surface-deactivated solid isocyanates which are dispersed in finely particulate manner, with aqueous isocyanate-reactive polymer dispersions that include a) dispersed polymers having isocyanate-reactive groups, b) dispersed surface-deactivated oligomeric solid polyisocyanates, and c) at least one catalyst, where the catalyst or the totality of catalysts accelerates the reaction of the monomeric polyisocyanates which form by the thermal cleavage of the oligomeric polyisocyanates more strongly than the thermal cleavage itself. The preparations are prepared by mixing aqueous dispersions of at least one isocyanate-reactive polymer with at least one dispersed surface-deactivated oligomreric solid polyisocyanate and at least one catalyst. The preparations can be used in binders, films and powders for bonded joints, or coatings and to make a latently cross-linking adhesive layer. Substrates can be coated with layers obtainable with the above-described preparations.
摘要:
The invention relates to a process for bonding surfaces with isocyanate-containing prepolymers having an isocyanate group content of less than 1.8% by weight, based on the prepolymer, and an average molecular weight MW.sub.n of at least 4,500 in which (a) the prepolymers are prepared by the reaction of (i) polyester diols prepared from dodecanedioic acid and even-numbered alkane diols containing at least 6 carbon atoms and (ii) diisocyanates; (b) the prepolymer is applied as a hotmelt adhesive at a temperature of 80 to 160.degree. C. by spin-spraying onto at least one surface to be bonded; and (c) the treated surface is brought into intimate contact with a second surface to be bonded.
摘要:
Disclosed herein is a two-component polyurethane adhesive containing an isocyanate component a), an active hydrogen containing component which is stable against demixing b), optionally a catalyst for the reaction of a) with b) and optionally an auxiliary agent and an additive, characterized in that an active hydrogen containing component which is stable against demixing b) contains at least one hydroxyl group-containing low molecular weight chain lengthening agent having at least one C-C double bond or C-C triple bond and having a molecular weight of at least 86 and a functionality of at least 2 and containing no carboxyl groups.
摘要:
The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.The present invention also relates to a process for the preparation of optionally foamed polyurethane plastics containing isocyanurate groups comprising (1) mixing the components of such reactive systems at a temperature less than 60.degree. C. and (2) heating said reactive system to a temperature of at least 60.degree. C.
摘要:
This invention relates to crystalline, isocyanate group-containign hot melt adhesives based onfrom 70-95% by weight of a prepolymer A based on polyester diols having a molecular weight of from 1500 to 10,000 and melting points of from 50.degree. to 90.degree. C. and diisocyanates in a ratio of isocyanate groups of the diisocyanate to the hydroxyl groups of the polyester diol of from 3:1 to 1.2:1 andfrom 5-30% by weight of a component B having a molecular weight of from 1000 to 10,000 based on polyesters having melting points of from 60.degree. to 150.degree. C., in which component B contains at most 0.5 Zerewitinow active groups per molecule.
摘要:
Disclosed herein are two-component polyurethane reactive compositions containing polyisocyanates and components carrying active hydrogen which are stabilized against separation with a compound in solution containing a NH group or NH.sub.2 group and a C--N multiple bond or N--N multiple bond.