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    Poly(ether-ester) polyols and processes for their production
    11.
    发明授权
    Poly(ether-ester) polyols and processes for their production 有权
    聚（醚 - 酯）多元醇及其生产方法

    公开(公告)号：US07687599B2

    公开(公告)日：2010-03-30

    申请号：US11375939

    申请日：2006-03-15

    申请人： Klaus Lorenz ,  Jorg Hofmann ,  Hartmut Nefzger

    发明人： Klaus Lorenz ,  Jorg Hofmann ,  Hartmut Nefzger

    IPC分类号： C08G59/00

    CPC分类号： C08G18/4887 ,  C08G65/2615 ,  C08G65/3311

    摘要： The invention is directed to novel poly(ether-ester)polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.

    摘要翻译： 本发明涉及新的聚（醚 - 酯）多元醇，其由具有一个或多个结合的聚醚链的单羧酸酯或多元羧酸酯生产的方法。 本发明还涉及其中异氰酸酯反应性组分包含这些聚（醚 - 酯）多元醇的聚氨酯材料的生产。

    Process for producing polyester polyols having secondary OH end groups
    16.
    发明授权
    Process for producing polyester polyols having secondary OH end groups 有权
    制备具有次级OH端基的聚酯多元醇的方法

    公开(公告)号：US09193822B2

    公开(公告)日：2015-11-24

    申请号：US13318157

    申请日：2010-05-04

    申请人： Hartmut Nefzger ,  Erika Bauer ,  Jörg Hofmann ,  Klaus Lorenz ,  Bert Klesczewski

    发明人： Hartmut Nefzger ,  Erika Bauer ,  Jörg Hofmann ,  Klaus Lorenz ,  Bert Klesczewski

    IPC分类号： C07C69/675 ,  C08G63/91 ,  C08G18/42 ,  C08G63/87

    CPC分类号： C08G63/914 ,  C08G18/4261 ,  C08G63/87

    摘要： The invention relates to a process for producing polyester polyols with secondary hydroxyl end groups, including the step of the reaction of a polyester including carboxyl end groups with an epoxide of the general formula (1): wherein R1 stands for an alkyl residue or an aryl residue and the reaction is carried out in the presence of a catalyst that includes at least one nitrogen atom per molecule. The process is distinguished in that the polyester including carboxyl end groups exhibits an acid value from ≧25 mg KOH/g to ≦400 mg KOH/g and a hydroxyl value from ≦5 mg KOH/g and in that the polyester including carboxyl end groups is produced by ≧1.03 mol to ≦1.90 mol carboxyl groups or carboxyl-group equivalents of an acid component being employed per mol hydroxyl groups of an alcohol. The polyester polyols obtained, including secondary hydroxyl end groups, can be used for the purpose of producing polyurethane polymers.

    摘要翻译： 本发明涉及一种生产具有仲羟基端基的聚酯多元醇的方法，包括包括羧基端基的聚酯与通式（1）的环氧化物反应的步骤：其中R1代表烷基或芳基 残基，反应在每分子包含至少一个氮原子的催化剂存在下进行。 该方法的区别在于包括羧基端基的聚酯显示出≥25mgKOH / g至≥1000的KOH值，400mg KOH / g的酸值和来自＆lt; NEE的5K KOH / g的羟值，并且包括羧基的聚酯 端基是由醇的每摩尔羟基使用的≥1.03摩尔至1升; 1.90摩尔羧基或酸组分的羧基当量。 得到的聚酯多元醇（包括仲羟基端基）可用于制备聚氨酯聚合物。

    Polyurea-based fabric glue
    17.
    发明授权
    Polyurea-based fabric glue 有权
    聚脲基织物胶

    公开(公告)号：US09051410B2

    公开(公告)日：2015-06-09

    申请号：US13384295

    申请日：2010-07-06

    申请人： Heike Heckroth ,  Hartmut Nefzger ,  Christoph Eggert

    发明人： Heike Heckroth ,  Hartmut Nefzger ,  Christoph Eggert

    IPC分类号： C08L75/02 ,  C08L75/04 ,  C09D175/02 ,  C08G18/10 ,  A61L24/04 ,  C08G18/18 ,  C09J175/12

    CPC分类号： A61L24/046 ,  C08G18/10 ,  C08G18/18 ,  C09J175/02 ,  C09J175/12 ,  C08G18/3821 ,  C08L75/04

    摘要： The present invention relates to a polyurea system, the use of such a polyurea system for sealing, linking, gluing, or covering of cellular tissue, and a dosing system having two chambers for a polyurea system such as this. The polyurea system comprises as components: A) an isocyanate-functioning prepolymer, which can be derived by reacting aliphatic isocyanates with polyoles, and B) an amino-functioning ester of aspartic acid. According to the invention, water and/or tertiary amine is added to the system, in order to increase the reacting speed of the prepolymer with the amino-functioning ester of aspartic acid while decreasing the setting time at the same time.

    摘要翻译： 本发明涉及聚脲系统，这种聚脲体系用于密封，连接，胶合或覆盖细胞组织，以及具有用于这种聚脲系统的两个室的计量系统。 聚脲体系包含如下组分：A）异氰酸酯官能的预聚物，其可以通过使脂族异氰酸酯与多元醇反应得到，和B）天冬氨酸的氨基官能化酯。 根据本发明，向系统中加入水和/或叔胺，以便增加预聚物与天冬氨酸的氨基官能酯的反应速度，同时同时降低凝固时间。

    REACTION SYSTEM FOR PREPARING POLYURETHANE MICROCELLULAR FOAM, A POLYURETHANE MICROCELLULAR FOAM AND THE USE THEREOF
    20.
    发明申请
    REACTION SYSTEM FOR PREPARING POLYURETHANE MICROCELLULAR FOAM, A POLYURETHANE MICROCELLULAR FOAM AND THE USE THEREOF 审中-公开
    聚氨酯微球泡沫的制备方法，聚氨酯微孔泡沫及其用途

    公开(公告)号：US20130210950A1

    公开(公告)日：2013-08-15

    申请号：US13813441

    申请日：2011-08-01

    申请人： Hartmut Nefzger ,  Zhiping Zhou ,  John Zhang ,  Jingui Shi

    发明人： Hartmut Nefzger ,  Zhiping Zhou ,  John Zhang ,  Jingui Shi

    IPC分类号： C08G18/42 ,  C08J9/04

    CPC分类号： C08G18/4236 ,  C08G18/10 ,  C08G18/4202 ,  C08G18/425 ,  C08G18/725 ,  C08G18/7671 ,  C08G18/797 ,  C08G2101/0008 ,  C08G2101/0066 ,  C08G2101/0083 ,  C08G2410/00 ,  C08J9/04 ,  C08J9/12 ,  C08J2205/044 ,  C08J2375/04 ,  C08G18/664

    摘要： The present invention relates to a reaction system for preparing polyurethane microcellular foam, a polyurethane microcellular foam and the use thereof. The reaction system for preparing polyurethane microcellular foam comprises isocyanate prepolymer, polyols, catalysts and chain extenders. The isocyanate prepolymer is a reaction product of polyisocyanates and polyester polyols, wherein the polyester polyols comprise 10-60 wt. % succinic acid units, based on 100 wt. % of the polyester polyols, the NCO content of the isocyanate prepolymer is 13-30 wt. %, based on 100 wt. % of isocyanate prepolymer. By using the reaction components provided in the present invention, the demould time for preparing the polyurethane microcellular foam can be reduced. The obtained polyurethane microcellular foam, which possesses good physical and mechanical properties, is particularly suitable to prepare shoes.

    摘要翻译： 本发明涉及一种制备聚氨酯微孔泡沫的反应体系，一种聚氨酯微孔泡沫及其用途。 用于制备聚氨酯微孔泡沫的反应体系包括异氰酸酯预聚物，多元醇，催化剂和扩链剂。 异氰酸酯预聚物是多异氰酸酯和聚酯多元醇的反应产物，其中聚酯多元醇包含10-60wt。 ％琥珀酸单位，基于100重量％ ％的聚酯多元醇，异氰酸酯预聚物的NCO含量为13-30wt。 ％，基于100wt。 ％异氰酸酯预聚物。 通过使用本发明提供的反应组分，可以减少制备聚氨酯微孔泡沫的脱模时间。 获得的具有良好物理和机械性能的聚氨酯微孔泡沫体特别适用于制备鞋子。