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    NI(0) -CONTAINING CATALYST SYSTEM
    11.
    发明申请
    NI(0) -CONTAINING CATALYST SYSTEM 有权
    NI（0）-CONTAINING催化剂体系

    公开(公告)号：US20080071105A1

    公开(公告)日：2008-03-20

    申请号：US11860972

    申请日：2007-09-25

    申请人： Michael BARTSCH ,  Robert Baumann ,  Dagmar Kumsmann-Keitel ,  Gerd Haderlein ,  Tim Jungkamp ,  Marco Altmayer ,  Wolfgang Siegel

    发明人： Michael BARTSCH ,  Robert Baumann ,  Dagmar Kumsmann-Keitel ,  Gerd Haderlein ,  Tim Jungkamp ,  Marco Altmayer ,  Wolfgang Siegel

    IPC分类号： C07C253/00

    CPC分类号： B01J31/185 ,  B01J23/755 ,  B01J31/1865 ,  B01J31/1875 ,  B01J2231/323 ,  B01J2531/847 ,  C07C253/10 ,  C07C255/07 ,  C07C255/04

    摘要： A system comprising a) Ni(0) b) from 4 to 10 mol per mol of Ni(0) in a) of a compound (I) of the formula P(X1R1)(X2R2)(X3R3)   (I) where X1, X2, X3 are each, independently of one another, oxygen or a single bond, R1, R2, R3 are, independently of one another, identical or different organic radicals and c) from 1 to 4 mol per mol of Ni(0) in a) of a compound (II) of the formula where X11, X12, X13 X21, X22, X23 are each, independently of one another, oxygen or a single bond, R11, R12 are identical or different, individual or bridged organic radicals, R21, R22 are identical or different, individual or bridged organic radicals and Y is a bridging group is suitable as catalyst for preparing mixtures of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds by hydrocyanation of a 1,3-butadiene-containing hydrocarbon mixture and for preparing a dinitrile by hydrocyanation of a mixture of monoolefinic C5 mononitriles having nonconjugated C═C and C═N bonds.

    摘要翻译： 一种系统，其包含a）式（I）中的式（ⅰ）中的每一摩尔Ni（0）中的Ni（0）b）4至10摩尔的式（ⅰ）的线性式描述=“在线式” 结束=“铅”→P（X 1> 1 ）（X 2 2 R 2）（X （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中X <1> 2，R 3彼此独立地为相同或不同的有机基团，c）1至4摩尔每摩尔a）化合物中的Ni（0） II），其中X 11，X 12，X 13，X 21，X 22 X 23，X 23各自彼此独立地为氧或单键，R 11，R 12和R 12相同或相同， 不同的单个或桥连的有机基团，R 21，R 22和R 22相同或不同，单个或桥接的有机基团和 Y是桥联基团，适合作为通过含1,3-丁二烯的烃混合物的氢氰化制备具有非共轭CC和CN键的单烯键式C 5 H 5单体的混合物的催化剂，并通过氢氰化制备二腈 的具有非共轭CC和CN键的单烯烃C 5 H 5单体的混合物。

    Method for the production of trioxime derivatives
    12.
    发明授权
    Method for the production of trioxime derivatives 失效
    生产三肟衍生物的方法

    公开(公告)号：US06906223B2

    公开(公告)日：2005-06-14

    申请号：US10332046

    申请日：2001-07-04

    申请人： Andreas Kramer ,  Matthias Kiefer ,  Michael Henningsen ,  Wolfgang Siegel ,  Jochen Schröder

    发明人： Andreas Kramer ,  Matthias Kiefer ,  Michael Henningsen ,  Wolfgang Siegel ,  Jochen Schröder

    IPC分类号： C07B61/00 ,  C07C249/06 ,  C07C249/08 ,  C07C251/40 ,  C07C251/58 ,  C07C49/12 ,  C07C251/60

    CPC分类号： C07C249/06 ,  C07C249/08 ,  C07C251/40

    摘要： The present invention relates to a process for preparing trioxime derivatives of the formula I in which the substituents R1 and R2 are identical or different and each is cyano, alkyl, haloalkyl or cycloalkyl, and R3 and R4 are identical or different and each is alkyl, haloalkyl, cycloalkyl, alkylcarbonyl or arylalkyl, by the following reaction steps in water without isolation of the intermediates: A) nitrosation of 1,3-diketones of the formula II  to give monooximes of the formula III, B) oximation of III with hydroxylamine derivatives of the formula IV H2N—OR3′  IV  in which R3′ is hydrogen or a group R3 to give bisoximes of the formula V, C) alkylation of V with alkylating agents or acylation of V with acylating agents to give compounds of the formula VI and D) subsequent oximation of VI with hydroxylamine to give compounds of the formula I.

    摘要翻译： 本发明涉及一种制备式I的三肟衍生物的方法，其中取代基R 1和R 2是相同或不同的，并且各自为氰基，烷基，卤代烷基 或环烷基，R 3和R 4相同或不同，并且各自为烷基，卤代烷基，环烷基，烷基羰基或芳烷基，通过以下反应步骤在水中不分离 中间体：A）式II的1,3-二酮的亚硝化，得到式III的单肟，B）III式与Ⅳ的羟胺衍生物的肟化，其中式Ⅳ的线性公式描述=“在线式 “end =”lead“？> H 2 N-OR 3”在线公式描述=“在线公式”end =“tail” 其中R 3'是氢或基团R 3'，得到式V的双肟，C）用烷基化剂烷基化V或用酰化酰化V 试剂得到式VI化合物和D）随后的肟基 VI与羟胺的离子，得到式I的化合物。

    Display with a heater
    13.
    发明授权
    Display with a heater 失效
    显示加热器

    公开(公告)号：US06723958B2

    公开(公告)日：2004-04-20

    申请号：US09991562

    申请日：2001-11-20

    申请人： Peter Brandt ,  Wolfgang Siegel

    发明人： Peter Brandt ,  Wolfgang Siegel

    IPC分类号： H05B100

    CPC分类号： G02F1/133382 ,  G05D23/2401

    摘要： Display with a heater, a) the display having at least one display glass, b) the heater having an electrically operated heating element connected to a voltage supply (UB, GND), c) the heating element comprising a thin layer, d) the layer being made of a material forming an electrical resistance, and e) the layer being applied over a surface area to the at least one display glass or being embedded over a surface area in the display. f) A first measuring instrument (4) is provided, which determines the resistance value of the heating element, g) a second measuring instrument (5) is provided, which determines the level of the voltage present at the heating element, h) a third measuring instrument (3) is provided, which senses the current ambient temperature at the display, i) a memory (7) is provided, which stores the determined resistance value of the heating element, j) a logic unit (6) is provided, which determines for the stored resistance value in accordance with the determined voltage and the determined ambient temperature a current-supplying period for the heating element necessary to produce that heat output which will heat up the display to a certain operating temperature within a predetermined time, and k) a switching element (8) actuated by the logic unit (6) is provided, which regulates the current flow through the heating element connected to the voltage supply (UB, GND) for the current-supplying period determined.

    摘要翻译： 显示器具有加热器，a）具有至少一个显示玻璃的显示器，b）加热器具有连接到电压源（UB，GND）的电动加热元件，c）加热元件包括薄层，d） 层由形成电阻的材料制成，以及e）该层被施加到至少一个显示玻璃的表面区域上，或被嵌入在显示器的表面区域上。 f）提供第一测量仪器（4），其确定加热元件的电阻值，g）设置第二测量仪器（5），其确定存在于加热元件上的电压的电平，h）a 提供第三测量仪器（3），其感测显示器上的当前环境温度，i）提供存储器（7），其存储所确定的加热元件的电阻值，j）提供逻辑单元（6） 其根据所确定的电压和所确定的环境温度来确定用于产生在预定时间内将显示器加热到某一工作温度的热输出所必需的加热元件的电流供应周期， 并且k）设置由逻辑单元（6）启动的开关元件（8），其调节通过连接到用于供电周期的电压源（UB，GND）的加热元件的电流 决心。

    Continuous preparation of dimethylvinylcarbinol by isomerizing prenol
    15.
    发明授权
    Continuous preparation of dimethylvinylcarbinol by isomerizing prenol 失效
    通过异构化prenol连续制备二甲基乙烯基甲醇

    公开(公告)号：US06180839B2

    公开(公告)日：2001-01-30

    申请号：US09265923

    申请日：1999-03-10

    申请人： Matthias Kiefer ,  Wolfgang Siegel ,  Jörg Therre ,  Melanie Pahl ,  Werner Aquila ,  Ulrich Sch{umlaut over (a)}fer-L{umlaut over (u)}derssen

    发明人： Matthias Kiefer ,  Wolfgang Siegel ,  Jörg Therre ,  Melanie Pahl ,  Werner Aquila ,  Ulrich Sch{umlaut over (a)}fer-L{umlaut over (u)}derssen

    IPC分类号： C07C2700

    CPC分类号： C07C29/56 ,  C07C33/03

    摘要： A process is described for the continuous preparation of dimethylvinylcarbinol (DMVC) by continuously reacting prenol with the aqueous solution of a protic acid in the still or in the lower part of a rectification column while distilling off the DMVC formed in the form of an azeotropic mixture with water, which comprises a) during the reaction ensuring that as far as possible no liquid two-phase mixture forms in the reaction mixture, b) distilling off the DMVC which forms at a reflux ratio of at least 2, as a result of which there is virtually no more prenol present in the distillate from the column, and c) setting the reaction volume and/or the amount of prenol added per hour and/or the concentration of protons in the reaction mixture in such a manner that the quotient, defined as residence time concentration coefficient, of the reaction volume and the volume of prenol added per hour multiplied by the concentration of protons in the reaction mixture has a value between 0.001 h·mol/l and 1 h·mol/l. In this connection, the formation of a liquid two-phase mixture in the reaction mixture is prevented, in addition to avoiding too large a prenol excess, by continuously taking from the reaction mixture a partial stream, passing it over a phase separation vessel, completely or at least largely removing there the small quantities, formed in the course of the reaction, of organic by-products which are insoluble or only partially soluble in water, and returning the aqueous phase to the reaction volume.

    摘要翻译： 描述了通过在精馏塔的静止或下部连续地反应预先醇与质子酸的水溶液连续反应制备二甲基乙烯基甲醇（DMVC）的方法，同时蒸馏出以共沸混合物形式形成的DMVC 在反应过程中包含a）的水，确保尽可能在反应混合物中形成液体两相混合物，b）蒸发形成回流比至少为2的DMVC，结果是在那里 在柱的馏出物中基本上没有更多的prenol存在，并且c）使反应体积和/或每小时加入的prenol的量和/或反应混合物中的质子浓度设定为使得定义为 停留时间浓度系数，反应体积和每小时加入的prenol体积乘以反应混合物中质子浓度的值为0.001 h.mol / l和 1 h.mol / l。在这方面，防止反应混合物中的液体两相混合物的形成，除了避免过多的过量的过量以外，通过连续取出反应混合物的一部分流，将其通过 在相分离容器中，完全或至少大部分在反应过程中形成的少量去除不溶或仅部分溶于水的有机副产物，并将水相返回到反应体积中。

    Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation
    16.
    发明授权
    Method for producing mixtures of monoolefinic C5-mononitriles by catalytic hydrocyanation 失效
    通过催化氢化法生产单烯烃C5-单腈混合物的方法

    公开(公告)号：US06169198A

    公开(公告)日：2001-01-02

    申请号：US09463820

    申请日：2000-02-01

    申请人： Jakob Fischer ,  Wolfgang Siegel

    发明人： Jakob Fischer ,  Wolfgang Siegel

    IPC分类号： C07C25310

    CPC分类号： C07C253/10 ,  C07C255/04 ,  C07C255/07

    摘要： A process for preparing mixtures of monoolefinic C5 mononitriles with nonconjugated C═C and C≡N bonds by catalytic hydrocyanation of 1,3-butadiene or a 1,3-butadiene-containing hydrocarbon mixture, wherein the hydrocyanation takes place in the presence of a catalyst which comprises at least one metallocene-phosphorus(III)-nickel(0) complex which comprises at least one monodentate or bidentate metallocene-phosphorus(III) ligand of the formula I or salts and mixtures thereof.

    摘要翻译： 通过1,3-丁二烯或含1,3-丁二烯的烃混合物的催化氢化制备单烯烃C5单腈与非共轭C = C和C = N键的混合物的方法，其中氢氰化在 催化剂，其包含至少一种茂金属 - 磷（III） - 镍（0）络合物，其包含至少一种式I或其盐及其混合物的单齿或二齿茂金属 - 磷（III）配体。

    Process for the preparation of substituted anthraquinones
    19.
    发明授权
    Process for the preparation of substituted anthraquinones 失效
    制备取代蒽醌的方法

    公开(公告)号：US6127580A

    公开(公告)日：2000-10-03

    申请号：US200936

    申请日：1998-11-30

    申请人： Wolfgang Siegel ,  Andreas Kramer

    发明人： Wolfgang Siegel ,  Andreas Kramer

    IPC分类号： C07C46/02 ,  C07C45/00

    CPC分类号： C07C46/02

    摘要： Process for the preparation of anthraquinones of the general formula I ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4, which can be identical or different, are hydrogen, a C.sub.1 -C.sub.8 -alkyl or C.sub.2 -C.sub.8 -alkenyl radical, in which 1,4-naphthoquinone is reacted with a 1,3-diene of the general formula II ##STR2## in a cycloaddition step to give the corresponding tetrahydroanthraquinone and the tetrahydroanthraquinone is oxidized with oxygen in the presence of a basic catalyst to give the anthraquinone, in which both the cycloaddition step and the oxidation step are carried out in the presence of an aqueous diluent.Preferably, the cycloaddition step and oxidation step are carried out at a reaction temperature between 90 and 110.degree. C. and at atmospheric pressure.

    摘要翻译： 用于制备通式I的蒽醌的方法，其中可以相同或不同的R 1，R 2，R 3和R 4是氢，C 1 -C 8 - 烷基或C 2 -C 8 - 烯基，其中1,4 萘醌在环加成步骤中与通式II的1,3-二烯反应，得到相应的四氢蒽醌，四氢蒽醌在碱性催化剂存在下用氧氧化得到蒽醌，其中环加成步骤 并且氧化步骤在水性稀释剂的存在下进行。 优选环加成步骤和氧化步骤在90-110℃的反应温度和大气压下进行。