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公开(公告)号：US20140037837A1
公开(公告)日：2014-02-06
申请号：US13995695
申请日：2011-12-20
IPC分类号： C08F22/10
摘要： A process for preparing vinyl polymer beads said process comprising aqueous suspension polymerisation of olefinically unsaturated monomers using a free-radical initiator, wherein at least 20 wt % of the olefinically unsaturated monomers used is derived from at least one bio-renewable olefinically unsaturated monomer.
摘要翻译： 一种制备乙烯基聚合物珠粒的方法，所述方法包括使用自由基引发剂的烯属不饱和单体的水性悬浮聚合，其中使用至少20wt％的烯属不饱和单体衍生自至少一种生物可再生烯属不饱和单体。
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公开(公告)号：US20130065070A1
公开(公告)日：2013-03-14
申请号：US13516452
申请日：2010-12-17
IPC分类号： C09D135/02
CPC分类号： C09D135/02 , C08F212/08 , C08F220/18 , C08F222/14 , C08F265/04 , C08F267/06 , C08F2220/1808 , C08F2220/1825 , C08F2220/1833 , C08L35/02 , Y10T428/31935 , C08L2666/04 , C08L2666/02
摘要： The invention relates to an aqueous emulsion comprising at least a vinyl polymer, said vinyl polymer comprising: a) 45 to 99 wt % of itaconate ester monomers having formula (I), wherein R and R′ are independently an alkyl or an aryl group; b) 0.1 to 15 wt % of ionic or potentially ionic unsaturated monomers; c) 0 to 54 wt % of unsaturated monomers, different from a) and b); and 0.9 to 54.9 wt % by weight of total monomers of a chaser monomer composition added subsequently and polymerised after the polymerisation of monomers a), b) and c); wherein a)+b)+c) and the chaser monomer composition add up to 100%; and wherein the aqueous emulsion contains less than 0.5 wt % free itaconate ester monomers of formula I based on the total weight of the aqueous emulsion.
摘要翻译： 本发明涉及包含至少一种乙烯基聚合物的水乳液，所述乙烯基聚合物包含：a）45至99重量％的具有式（I）的衣康酸酯单体，其中R和R'独立地为烷基或芳基; b）0.1至15重量％的离子或潜在的不饱和单体; c）0至54重量％的不饱和单体，不同于a）和b）; 和0.9至54.9重量％的随后加入的追踪单体组合物的单体的总量，并且在单体a），b）和c）的聚合之后聚合。 其中a）+ b）+ c）和所述追踪单体组合物总计高达100％; 并且其中基于所述水性乳液的总重量，所述水性乳液含有小于0.5重量％的式I的游离的衣康酸酯单体。
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公开(公告)号：US20110196084A1
公开(公告)日：2011-08-11
申请号：US12306204
申请日：2007-06-19
IPC分类号： C08L51/06 , C09D151/06 , C08F2/22 , C09D11/10 , C09J151/06
CPC分类号： C08F265/06 , C08F265/00 , C08F265/04 , C08F290/04 , C08F291/00 , C08L51/003 , C09D151/003 , C08L2666/02 , C08L2666/14
摘要： An aqueous composition comprising: A) a crosslinkable vinyl graft copolymer comprising 30 to 85 wt % of a polymeric backbone; and 70 to 15 wt % of at least one macromonomer grafted to the polymeric backbone, where the Tg of the macromonomer is in the range of from 15 to 140° C.; where the Tg of the polymeric backbone is ≦40° C.; where the vinyl graft copolymer comprises 0.6 to 10 wt % of at least one carbonyl functional vinyl monomer; where the polymeric backbone contains ≧75% of the carbonyl functional vinyl monomers in the vinyl graft copolymer; and B) a hydrazide functional compound; where the ratio of hydrazide functional groups to carbonyl functional groups in the vinyl graft copolymer is in the range of from 0.1 to 1.5; and where the composition comprises ≦50 wt % of organic co-solvent by weight of the vinyl graft copolymer.
摘要翻译： 一种水性组合物，其包含：A）包含30至85重量％的聚合物主链的可交联乙烯基接枝共聚物; 和70至15wt％的至少一种接枝到聚合物主链上的大分子单体，其中大分子单体的Tg在15至140℃的范围内; 其中聚合物主链的Tg为40℃; 其中乙烯基接枝共聚物包含0.6至10重量％的至少一种羰基官能的乙烯基单体; 其中聚合物主链在乙烯基接枝共聚物中含有≥75％的羰基官能乙烯基单体; 和B）酰肼官能化合物; 其中乙烯基接枝共聚物中酰肼官能团与羰基官能团的比例在0.1至1.5的范围内; 并且其中组合物包含按重量计的乙烯基接枝共聚物的50重量％的有机共溶剂。
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公开(公告)号：US20110118394A1
公开(公告)日：2011-05-19
申请号：US12919322
申请日：2009-03-31
申请人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Richard George Coogan
发明人： Ilse Van Casteren , Gerardus Cornelis Overbeek , Ronald Tennebroek , Tijs Nabuurs , Richard George Coogan
IPC分类号： C09D123/30 , C08F10/00 , C08K5/3415 , B05D3/00
CPC分类号： C09D133/14 , C08G18/283 , C08G18/4211 , C08G18/423 , C08G18/4233 , C08G18/606 , C08G18/755 , C09D167/08 , C09D175/04 , C09D177/12 , Y10T428/31511
摘要： An aqueous solution coating composition comprising an autoxidisable polyvinyl polymer having ≧20% of fatty acid residue by weight of polymer; Tg from −60 to +15° C.; acid value of 15 to 75 mg KOH/g, Mw from 2500 to 100000 g/mol; polydispersity ≦30, said composition having ≦25% co-solvent by weight of solids, ≧30% solids by weight of composition; said composition when in the form of a coating having a telegraphing value defined as the difference in gloss at a 20° angle of between a film cast on rough PVC and a film cast on smooth PVC of 10 gloss units.
摘要翻译： 一种水溶液涂料组合物，其包含具有≥20％的聚合物重量的脂肪酸残基的可自动氧化的聚乙烯基聚合物; Tg从-60到+ 15℃。 酸值为15至75mg KOH / g，Mw为2500至100000g / mol; 多分散性; 30，所述组合物具有＆lt; NlE; 25重量％的固体重量的共溶剂，≥30重量％组合物的固体; 所述组合物当以具有透光值形式的涂层的形式时，所述透射值定义为在粗糙PVC上铸造的膜和在10个光泽单元的光滑PVC上浇铸的膜之间的20°角的光泽差。
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公开(公告)号：US20080249242A1
公开(公告)日：2008-10-09
申请号：US12066537
申请日：2006-09-13
IPC分类号： C08L51/06
CPC分类号： C09D5/02 , C08F285/00 , C08F287/00 , C09D11/107 , C09D11/30
摘要： An aqueous composition comprising at least one vinyl graft copolymer (A) and at least one vinyl polymer (B) obtained by a process comprising steps a) polymerising at least one vinyl monomer to obtain at least one macromonomer with a Tg1>15° C.; b) polymerising at least one vinyl monomer in the presence of the macromonomer prepared in step a) to form a polymeric backbone of said vinyl graft copolymer (A); c) polymerising at least one vinyl monomer in the presence of the vinyl graft copolymer (A) prepared in step b), to form said vinyl polymer (B); and where vinyl polymer (B) has a Tg2 lower than the Tg1 of the macromonomer.
摘要翻译： 一种水性组合物，其包含至少一种乙烯基接枝共聚物（A）和至少一种乙烯基聚合物（B），所述乙烯基聚合物（B）通过以下方法获得，所述方法包括以下步骤：a）聚合至少一种乙烯基单体以获得至少一种具有Tg 1的大分子单体， / SUP >> 15°C。 b）在步骤a）中制备的大分子单体的存在下聚合至少一种乙烯基单体以形成所述乙烯基接枝共聚物（A）的聚合物骨架; c）在步骤b）中制备的乙烯基接枝共聚物（A）的存在下聚合至少一种乙烯基单体以形成所述乙烯基聚合物（B）; 并且其中乙烯基聚合物（B）具有低于大分子单体的Tg <1的Tg <2。
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公开(公告)号：US09458346B2
公开(公告)日：2016-10-04
申请号：US13995660
申请日：2011-12-20
IPC分类号： C09J151/06 , C08L51/06 , C09D133/06 , C09D11/106 , C09D151/06 , C09D133/12 , C08F265/06 , C08L33/12 , C09D5/02
CPC分类号： C09D133/06 , C08F265/06 , C08L33/12 , C08L51/06 , C08L2201/06 , C09D5/02 , C09D11/106 , C09D133/12 , C09D151/06 , C09J151/06 , Y10T428/31692 , Y10T428/31855 , Y10T428/31895 , C08L2666/04 , C08F2/08
摘要： An aqueous polymer dispersion comprising a vinyl polymer with at least two phases comprising: A) 40 to 90 wt % of a vinyl polymer A having a glass transition temperature in the range of from −50 to 30° C.; and B) 10 to 60 wt % of a vinyl polymer B having a glass transition temperature the range of from 50 to 130° C.; wherein vinyl polymer A comprises 0.1 to 10 wt % of at least one acid-functional olefinically unsaturated monomer, wherein at least 20 wt % of the monomer composition used to form vinyl polymer A and vinyl polymer B is derived from at least one bio-renewable olefinically unsaturated monomer.
摘要翻译： 一种包含具有至少两相的乙烯基聚合物的含水聚合物分散体，其包含：A）40至90重量％的玻璃化转变温度为-50至30℃的乙烯基聚合物A; 和B）10〜60重量％的玻璃化转变温度为50〜130℃的乙烯基聚合物B。 其中乙烯基聚合物A包含0.1至10重量％的至少一种酸官能的烯属不饱和单体，其中用于形成乙烯基聚合物A和乙烯基聚合物B的单体组合物的至少20重量％衍生自至少一种生物可再生的 烯属不饱和单体。
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17.发明申请MACROMONOMERS AND GRAFT COPOLYMERS PREPARED BY EMULSION POLYMERIZATION WITH A COBALT CHELATE CHAIN TRANSFER AGENT 审中-公开通过与钴盐链转移剂的乳液聚合制备的大分子和共聚物公开(公告)号：US20120035316A1
公开(公告)日：2012-02-09
申请号：US13276196
申请日：2011-10-18
申请人： Saskia Carolien VAN DER SLOT , Tijs Nabuurs , Alfred Jean Paul BÜCKMANN , Gerardus Cornelis Overbeek
发明人： Saskia Carolien VAN DER SLOT , Tijs Nabuurs , Alfred Jean Paul BÜCKMANN , Gerardus Cornelis Overbeek
IPC分类号： C09D133/24 , C08F216/04 , C08F222/20 , C08F216/14 , C09D133/14 , C09D135/02 , C09J133/24 , C09J133/14 , C09J135/02 , C08F216/36 , C08F293/00 , B82Y30/00
CPC分类号： C08F4/26 , C08F2/22 , C08F2/38 , C08F220/14 , C08F265/06 , C08F290/062 , C09D151/00 , C09J151/00 , C08F2220/1825 , C08F220/06 , C08F220/58
摘要： Process for preparing a macromonomer using free radical-initiated aqueous emulsion polymerisation in a polymerisation reactor of at least one olefinically unsaturated monomer, which process employs a hydrophobic Co chelate complex as a CTA, a stabilising substance(s) for the emulsion polymerisation process and a monomer feed stage MF;wherein an aqueous pre-emulsified mixture A, comprising at least part of the Co chelate(s) employed, at least part of the stabilising substance(s) employed, and (i) a non-polymerisable organic solvent(s) and/or (ii) a polymerisable monomer(s) in unpolymerised or at least partially polymerised form, is contacted in the reactor with monomer(s) of feed stage MF at the beginning of and/or during the course of feed stage MF; and wherein in mixture A the weight ratio of (i) and/or (ii) to the stabilising substance(s) is in the range of from 10/1 to 1/10.
摘要翻译： 在至少一种烯属不饱和单体的聚合反应器中使用自由基引发的水性乳液聚合制备大分子单体的方法，该方法使用疏水性Co螯合物络合物作为CTA，用于乳液聚合方法的稳定物质和 单体进料级MF; 其中包含至少部分所述Co螯合物的至少一部分所用稳定物质的水性预乳化混合物A和（i）不可聚合的有机溶剂和/或 （ii）未聚合或至少部分聚合形式的可聚合单体在反应器中在进料阶段MF的开始和/或期间在进料阶段MF的单体接触; 并且其中在混合物A中，（i）和/或（ii）与稳定物质的重量比在10/1至1/10的范围内。
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18.发明授权Polymer composition comprising a polymer having a gradient polymeric morphology 有权包含具有梯度聚合物形态的聚合物的聚合物组合物公开(公告)号：US07173083B2
公开(公告)日：2007-02-06
申请号：US10488698
申请日：2002-09-27
IPC分类号： C09J11/08 , C09J133/00 , C09J133/08 , C08J201/00
CPC分类号： C08L101/00 , C09D201/00 , C08L2666/04
摘要： An aqueous composition comprising components: (A) 50 to 99 wt. % of a vinyl polymer(s) having a gradient polymeric morphology; and (B) 1 to 50 wt. % of at least one polymer not having a gradient polymeric morphology, wherein components (A) and (B) add up to 100%.
摘要翻译： 一种水性组合物，其包含组分：（A）50至99重量％ ％的具有梯度聚合物形态的乙烯基聚合物; 和（B）1〜50wt。 至少一种不具有梯度聚合物形态的聚合物的％，其中组分（A）和（B）加起来达100％。
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公开(公告)号：US06730733B2
公开(公告)日：2004-05-04
申请号：US10220141
申请日：2002-08-28
IPC分类号： C08F2018
CPC分类号： C09D175/16 , C08G18/0823 , C08G18/12 , C08G18/672 , C08G18/3231 , C08G18/0828
摘要： Aqueous polymer composition suitable for coating which comprises the following components dispersed in water: (1) a combination of an acrylic polymer(s) A and an acrylic polymer(s) B where polymer(s) A has a Tg of not more than 30° C. and polymer(s) B has a Tg of at least 35° C., more preferably at least 45° C., which is at least 25° C. higher than the Tg of polymer(s) A, and wherein one or both of polymers A and B bear crosslinker functional groups capable of imparting ambient-temperature crosslinkability to component (1) in a coating formed from the composition via the formation of non-radically-formed covalent bonds; and (2) a self-dispersible, ionically stabilised polymer having olefinically unsaturated bond functionality capable of imparting radiation-curability (preferably uv-radiation curability) thereto in a coating formed from the composition.
摘要翻译： 适用于涂料的水性聚合物组合物，其包含分散在水中的以下组分：（1）丙烯酸类聚合物A和丙烯酸类聚合物B的组合，其中聚合物A的Tg不大于30 ℃，并且聚合物B具有比聚合物A的Tg高至少35℃，更优选至少45℃的Tg，并且其中 聚合物A和B中的一种或两种具有能够通过形成非自由基形成的共价键在由组合物形成的涂层中赋予组分（1）环境温度交联性的交联剂官能团; 和（2）能够在由该组合物形成的涂层中赋予辐射固化性（优选紫外辐射固化性）的具有烯属不饱和键官能度的自分散性离子稳定聚合物。
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20.发明授权公开(公告)号：US07247671B2
公开(公告)日：2007-07-24
申请号：US10485572
申请日：2002-07-22
CPC分类号： C09D175/04 , C08G18/4833 , C08G18/6279 , C08G18/706 , C08L61/20 , C09D133/16 , C08L2666/14
摘要： Aqueous crosslinkable coating composition suitable for anti-graffiti and heavy duty applications comprising: (A) an aqueous polymer emulsion comprising at least one vinyl fluoropolymer which comprises as a polymerized constituent monomer thereof (i) a fluoromonomer(s) having the formula (1) wherein R1 is CH3 or H, R2 is a per-fluorinated C1-5 alkyl group and n is 1, 2, 3 or 4, (ii) a hydroxyl functional monomer(s) and (iii) a carboxylic acid-functional monomer(s) where the vinyl fluoropolymer has a glass transition temperature Tg within the range of from −50 to 90° C. and (B) at least one hydroxyl-reactive crosslinker material
摘要翻译： 适用于防涂鸦和重载应用的水性交联涂料组合物包括：（A）包含至少一种乙烯基含氟聚合物的水性聚合物乳液，其包含作为其聚合构成单体的（i）具有式（1）的含氟单体， 其中R 1是CH 3或H，R 2是全氟化的C 1-5烷基 和n为1,2,3或4，（ii）羟基官能单体和（iii）羧酸官能单体，其中所述乙烯基含氟聚合物的玻璃化转变温度Tg为 - 50至90℃，和（B）至少一种羟基反应性交联剂材料
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