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11.发明申请公开(公告)号：US20080000807A1
公开(公告)日：2008-01-03
申请号：US11477275
申请日：2006-06-28
申请人： Christopher Dean , Musaed Salem Musard Al-Ghamdi , Khurshid Alam , Mohammed Abdul Bari Siddioui , Shakeel Ahmed
发明人： Christopher Dean , Musaed Salem Musard Al-Ghamdi , Khurshid Alam , Mohammed Abdul Bari Siddioui , Shakeel Ahmed
CPC分类号： B01J29/088 , B01J20/0211 , B01J20/0244 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J21/066 , B01J21/16 , B01J23/06 , B01J29/084 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/30 , C10G11/05 , C10G11/18 , C10G2300/104 , C10G2300/202 , C10G2300/80
摘要： The present invention concerns a novel additive composition for reducing sulfur content of a catalytically cracked gasoline fraction. This additive composition comprises a support consisting of porous clay into which a first metal from group IV is incorporated and a second metal from group II is impregnated. Preferably, the first incorporated metal is zirconium and the second impregnated metal is zinc. The sulfur reduction additive is used in the form of a separate particle in combination with a conventional fluidized catalytic cracking catalyst in a fluid catalytic cracking process to convert hydrocarbon feed stocks into gasoline and other liquid products.
摘要翻译： 本发明涉及用于降低催化裂化汽油馏分的硫含量的新型添加剂组合物。 该添加剂组合物包括由多孔粘土组成的载体，其中掺入第IV族的第一种金属，并且浸渍来自II族的第二种金属。 优选地，第一掺入金属是锆，第二浸渍金属是锌。 硫化还原添加剂以流化催化裂化方法与常规流化催化裂化催化剂结合使用的单独颗粒的形式，以将烃原料转化为汽油和其它液体产物。
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公开(公告)号：US09714169B2
公开(公告)日：2017-07-25
申请号：US15082531
申请日：2016-03-28
申请人： Fahad Ibrahim Al-Muhaish , Shakeel Ahmed , Roberto Carlos Pontes Bittencourt , Mauri Jose Baldini Cardoso , Vivian Passos De Souza
发明人： Fahad Ibrahim Al-Muhaish , Shakeel Ahmed , Roberto Carlos Pontes Bittencourt , Mauri Jose Baldini Cardoso , Vivian Passos De Souza
CPC分类号： C01B3/36 , B01J21/10 , B01J23/894 , B01J23/8946 , B01J23/8986 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/1014 , B01J35/1038 , B01J35/1061 , B01J37/0207 , B01J37/0244 , C01B3/40 , C01B3/50 , C01B2203/0233 , C01B2203/0238 , C01B2203/0261 , C01B2203/047 , C01B2203/0811 , C01B2203/0844 , C01B2203/1017 , C01B2203/1047 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01B2203/1247 , C01B2203/1252 , Y02P20/142 , Y02P20/52
摘要： The invention relates to a four-component catalyst and a seven-component catalyst and refractory supports for use in the thermoneutral reforming of petroleum-based liquid hydrocarbon fuels.
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13.发明授权公开(公告)号：US08623199B2
公开(公告)日：2014-01-07
申请号：US12462338
申请日：2009-07-30
申请人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
发明人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
IPC分类号： C10G45/04
CPC分类号： B01J29/088 , B01J20/0211 , B01J20/0244 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J21/066 , B01J21/16 , B01J23/06 , B01J23/08 , B01J29/084 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/30 , C10G11/05 , C10G11/18
摘要： Compositions and processed for their use as additives for reducing the sulfur content of FCC gasoline employ a support material having deposited on its surface (a) a first metal component from Group IIB of the Periodic Table and (b) a second metal component from Group III or Group IV of the Periodic Table. The additive composition is preferably made of a montmorillonite clay support containing zinc and gallium, zinc and zirconium. Alternatively, the additive composition includes support material having deposited on its surface a metal component from Group III of the Periodic Table, preferably a montmorillonite clay support containing gallium. The clay is impregnated with the metal(s) using the known incipient wetness method and the dried powdered additive composition is preferably formed into shapes suitable for use in the FCC unit.
摘要翻译： 作为用于降低FCC汽油的硫含量的添加剂的组合物和其加工物使用沉积在其表面上的载体材料（a）来自元素周期表IIB族的第一金属组分和（b）来自III族的第二种金属组分 或周期表第IV组。 添加剂组合物优选由含有锌和镓，锌和锆的蒙脱石粘土载体制成。 或者，添加剂组合物包括在其表面上沉积了来自元素周期表III族的金属组分的载体材料，优选含有镓的蒙脱石粘土载体。 使用已知的初湿法将粘土浸渍有金属，干燥的粉末状添加剂组合物优选形成适合用于FCC装置的形状。
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14.发明授权公开(公告)号：US08409428B2
公开(公告)日：2013-04-02
申请号：US11477275
申请日：2006-06-28
申请人： Christopher F. Dean , Musaed Salem Musaed Al-Ghrami Al-Ghamdi , Khurshid K. Alam , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
发明人： Christopher F. Dean , Musaed Salem Musaed Al-Ghrami Al-Ghamdi , Khurshid K. Alam , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
IPC分类号： C10G25/05
CPC分类号： B01J29/088 , B01J20/0211 , B01J20/0244 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J21/066 , B01J21/16 , B01J23/06 , B01J29/084 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/30 , C10G11/05 , C10G11/18 , C10G2300/104 , C10G2300/202 , C10G2300/80
摘要： The present invention concerns a novel additive composition for reducing sulfur content of a catalytically cracked gasoline fraction. This additive composition comprises a support consisting of porous clay into which a first metal from group IVB is incorporated and a second metal from group IIB is impregnated. Preferably, the first incorporated metal is zirconium and the second impregnated metal is zinc. The sulfur reduction additive is used in combination with a conventional cracking catalyst in a fluidized catalytic cracking process to convert hydrocarbon feed stocks into gasoline having comparatively lower sulfur content and other liquid products.
摘要翻译： 本发明涉及用于降低催化裂化汽油馏分的硫含量的新型添加剂组合物。 这种添加剂组合物包括由多孔粘土组成的载体，其中掺入来自IVB族的第一种金属并且浸渍了IIB族的第二种金属。 优选地，第一掺入金属是锆，第二浸渍金属是锌。 硫化还原添加剂与流化催化裂化过程中的常规裂化催化剂组合使用，以将烃原料转化成具有相对较低硫含量的汽油和其它液体产物。
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公开(公告)号：US20100240522A1
公开(公告)日：2010-09-23
申请号：US12382737
申请日：2009-03-23
申请人： Tomoyuki Inui , Masayuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
发明人： Tomoyuki Inui , Masayuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
CPC分类号： B01J37/0201 , B01J21/16 , B01J23/652 , B01J23/89 , B01J23/8913 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J37/18 , C10G29/205 , C10G45/10 , C10G47/14
摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.
摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。
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16.发明申请公开(公告)号：US20100032343A1
公开(公告)日：2010-02-11
申请号：US12462338
申请日：2009-07-30
申请人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
发明人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
CPC分类号： B01J29/088 , B01J20/0211 , B01J20/0244 , B01J20/12 , B01J20/3204 , B01J20/3236 , B01J21/066 , B01J21/16 , B01J23/06 , B01J23/08 , B01J29/084 , B01J35/0006 , B01J35/0073 , B01J37/0205 , B01J37/0207 , B01J37/30 , C10G11/05 , C10G11/18
摘要： Compositions and processed for their use as additives for reducing the sulfur content of FCC gasoline employ a support material having deposited on its surface (a) a first metal component from Group IIB of the Periodic Table and (b) a second metal component from Group III or Group IV of the Periodic Table. The additive composition is preferably made of a montmorillonite clay support containing zinc and gallium, zinc and zirconium. Alternatively, the additive composition includes support material having deposited on its surface a metal component from Group III of the Periodic Table, preferably a montmorillonite clay support containing gallium. The clay is impregnated with the metal(s) using the known incipient wetness method and the dried powdered additive composition is preferably formed into shapes suitable for use in the FCC unit.
摘要翻译： 作为用于降低FCC汽油的硫含量的添加剂的组合物和其加工物使用沉积在其表面上的载体材料（a）来自元素周期表IIB族的第一金属组分和（b）来自III族的第二种金属组分 或周期表第IV组。 添加剂组合物优选由含有锌和镓，锌和锆的蒙脱石粘土载体制成。 或者，添加剂组合物包括在其表面上沉积了来自元素周期表III族的金属组分的载体材料，优选含有镓的蒙脱石粘土载体。 使用已知的初湿法将粘土浸渍有金属，干燥的粉末状添加剂组合物优选形成适合用于FCC装置的形状。
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公开(公告)号：US08008226B2
公开(公告)日：2011-08-30
申请号：US12660762
申请日：2010-03-03
申请人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
发明人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
IPC分类号： B01J23/10
CPC分类号： B01J23/8986 , B01J21/04 , B01J23/002 , B01J23/894 , B01J2523/00 , C01B3/382 , C01B2203/0238 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/06 , C01B2203/066 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1247 , C01B2203/1252 , Y02P20/52 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/74 , B01J2523/822 , B01J2523/828 , B01J2523/847
摘要： A method is provided for the thermo-neutral reforming of liquid hydrocarbon fuels which employs a Ni, Ce2O3, La2O3, Pt−ZrO2, Rh and Re catalyst having dual functionalities to achieve both combustion and steam reforming.
摘要翻译： 提供了一种采用具有双功能的Ni，Ce2O3，La2O3，Pt-ZrO2，Rh和Re催化剂的液体烃燃料的热中性重整方法，以实现燃烧和蒸汽重整。
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18.发明申请公开(公告)号：US20110120912A1
公开(公告)日：2011-05-26
申请号：US13055639
申请日：2009-07-30
申请人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
发明人： Abdennour Bourane , Omer Refa Koseoglu , Musaed Salem Al-Ghrami , Christopher F. Dean , Mohammed Abdul Bari Siddiqui , Shakeel Ahmed
CPC分类号： B01J23/06 , B01J21/16 , B01J23/08 , B01J29/084 , B01J35/0006 , B01J37/0201 , C10G11/02 , C10G11/18 , C10G2300/1044 , C10G2300/202
摘要： Compositions and processed for their use as additives for reducing the sulfur content of FCC gasoline employ a support material having deposited on its surface (a) a first metal component from Group IIB of the Periodic Table and (b) a second metal component from Group III or Group IV of the Periodic Table. The additive composition is preferably made of a montmorillonite clay support containing zinc and gallium, zinc and zirconium. Alternatively, the additive composition includes support material having deposited on its surface a metal component from Group III of the Periodic Table, preferably a montmorillonite clay support containing gallium. The clay is impregnated with the metal(s) using the known incipient wetness method and the dried powdered additive composition is preferably formed into shapes suitable for use in the FCC unit.
摘要翻译： 作为用于降低FCC汽油的硫含量的添加剂的组合物和其加工物使用沉积在其表面上的载体材料（a）来自元素周期表IIB族的第一金属组分和（b）来自III族的第二种金属组分 或周期表第IV组。 添加剂组合物优选由含有锌和镓，锌和锆的蒙脱石粘土载体制成。 或者，添加剂组合物包括在其表面上沉积了来自元素周期表III族的金属组分的载体材料，优选含有镓的蒙脱石粘土载体。 使用已知的初湿法将粘土浸渍有金属，干燥的粉末状添加剂组合物优选形成适合用于FCC装置的形状。
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公开(公告)号：US20100216633A1
公开(公告)日：2010-08-26
申请号：US12660762
申请日：2010-03-03
申请人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
发明人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
IPC分类号： B01J23/889 , B01J21/06 , B01J23/10
CPC分类号： B01J23/8986 , B01J21/04 , B01J23/002 , B01J23/894 , B01J2523/00 , C01B3/382 , C01B2203/0238 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/06 , C01B2203/066 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1247 , C01B2203/1252 , Y02P20/52 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/74 , B01J2523/822 , B01J2523/828 , B01J2523/847
摘要： A method is provided for the thermo-neutral reforming of liquid hydrocarbon fuels which employs a Ni,Ce2O3, La2O3, Pt−ZrO2, Rh and Re catalyst having dual functionalities to achieve both combustion and steam reforming.
摘要翻译： 提供了一种采用具有双重功能的Ni，Ce2O3，La2O3，Pt-ZrO2，Rh和Re催化剂的液体烃燃料的热中性重整方法，以实现燃烧和蒸汽重整。
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公开(公告)号：US20080152572A1
公开(公告)日：2008-06-26
申请号：US11645970
申请日：2006-12-26
申请人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
发明人： Tomoyuki Inui , Bashir Osama Dabbousi , Shakeel Ahmed , Fahad Ibrahim Al-Muhaish , Mohammed Abdul Bari Siddiqui
CPC分类号： B01J23/8986 , B01J21/04 , B01J23/002 , B01J23/894 , B01J2523/00 , C01B3/382 , C01B2203/0238 , C01B2203/0244 , C01B2203/0283 , C01B2203/0405 , C01B2203/043 , C01B2203/044 , C01B2203/0445 , C01B2203/047 , C01B2203/06 , C01B2203/066 , C01B2203/1058 , C01B2203/1064 , C01B2203/107 , C01B2203/1094 , C01B2203/1247 , C01B2203/1252 , Y02P20/52 , B01J2523/3706 , B01J2523/3712 , B01J2523/48 , B01J2523/74 , B01J2523/822 , B01J2523/828 , B01J2523/847
摘要： A method is provided for the thermo-neutral reforming of liquid hydrocarbon fuels which employs a Ni, Ce2O3, La2O3, Pt−ZrO2, Rh and Re catalyst having dual functionalities to achieve both combustion and steam reforming.
摘要翻译： 提供了一种用于液体烃燃料的热中性重整的方法，其使用Ni，Ce 2 O 3，N 2 O 3 具有双重功能以实现燃烧和蒸汽重整的Rh 3和Re 2，Rh和Re催化剂。
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