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20 条记录 (耗时 0.022 秒)

    Catalyst exhibiting hydrogen spillover effect
    7.
    发明授权
    Catalyst exhibiting hydrogen spillover effect 失效
    催化剂表现出氢气溢出效应

    公开(公告)号：US08785340B2

    公开(公告)日：2014-07-22

    申请号：US13278130

    申请日：2011-10-20

    申请人： Takuma Kimura ,  Mohammad Abdullah Al-Saleh ,  Halim Hamid Redhwi ,  Mohammad Ashraf Ali ,  Shakeel Ahmed ,  Masayuki Inui

    发明人： Tomoyuki Inui ,  Takuma Kimura ,  Mohammad Abdullah Al-Saleh ,  Halim Hamid Redhwi ,  Mohammad Ashraf Ali ,  Shakeel Ahmed

    IPC分类号： B01J31/00 ,  C07C27/00

    CPC分类号： B01J37/0201 ,  B01J21/16 ,  B01J23/652 ,  B01J23/89 ,  B01J23/8913 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/1038 ,  B01J35/1042 ,  B01J37/0205 ,  B01J37/18 ,  C10G29/205 ,  C10G45/10 ,  C10G47/14

    摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.

    摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。

    Process for production of high-purity mullites
    9.
    发明授权
    Process for production of high-purity mullites 失效
    生产高纯度莫来石的方法

    公开(公告)号：US5338707A

    公开(公告)日：1994-08-16

    申请号：US886551

    申请日：1992-05-20

    申请人： Tomoyuki Inui ,  Masashi Inoue

    发明人： Tomoyuki Inui ,  Masashi Inoue

    IPC分类号： C04B35/18 ,  C01B33/26 ,  C04B35/10 ,  C04B35/185 ,  C03C3/00

    CPC分类号： C04B35/185 ,  C01B33/26

    摘要： A process is disclosed for the production of high purity mullites. The process involves reacting a mixture of aluminum alkoxide and silicon alkoxide with an atomic ratio (weight) of Al/Si in the range of 2-7 in an aromatic hydrocarbon solvent at a temperature of 200.degree.-350.degree. C. and calcining the resulting reaction product at a temperature above 900.degree. C. The mullite product obtained finds wide application as a high temperature service structural material such as for automotive engines and turbines as well as a support for combustion catalyst.

    摘要翻译： 公开了用于生产高纯度莫来石的方法。 该方法包括在200-350℃的温度下，使芳族烃溶剂中的铝/醇铝混合物与Al / Si的原子比（重量）在2-7范围内反应，并煅烧所得到的 反应产物在高于900℃的温度下获得。所得到的莫来石产品作为高温服务结构材料，例如用于汽车发动机和涡轮机以及用于燃烧催化剂的支撑物被广泛应用。

    Crystalline aluminosilicate zeolite catalyst and the method for manufacturing thereof
    10.
    发明授权
    Crystalline aluminosilicate zeolite catalyst and the method for manufacturing thereof 失效
    结晶硅铝酸盐沸石催化剂及其制造方法

    公开(公告)号：US4400328A

    公开(公告)日：1983-08-23

    申请号：US312496

    申请日：1981-10-19

    申请人： Yoshinobu Takegami ,  Tomoyuki Inui ,  Takayuki Ishihara ,  Eiichi Araki ,  Toshihiro Kanie

    发明人： Yoshinobu Takegami ,  Tomoyuki Inui ,  Takayuki Ishihara ,  Eiichi Araki ,  Toshihiro Kanie

    IPC分类号： B01J29/70 ,  C01B39/30 ,  C07F5/06

    CPC分类号： C01B39/305 ,  B01J29/70

    摘要： The present invention relates to provide new crystalline zeolite catalyst (ZKU-catalyst) having the superior catalytic activity and selectivity and the long period of the catalytic life.One of the method of said catalyst (ZKU-2 catalyst) lies in crystallizing the starting zeolite preparation in the presence of the crystallization conditioning agent of crystallization of tetraalkyl (methyl or ethyl or combination thereof) ammonium cation.Another method of said catalyst (ZKU-3, 4 catalysts) lies in crystallizing the starting zeolite preparation in the presence of both said conditioning agent of crystallization and the substance capable of forming the seed and/or the skelton of crystal. The ZKU-3 catalyst is manufactured using the seed of crystal, while the ZKU-4 catalyst is manufactured using the seed and the skelton of crystal.The seed of crystal is useful for the promoter of the crystallization rate and the improvement of the catalytic activity, the skelton of crystal is useful for so-called "skelton" which is of use for the improvement of the mechanical strength, the dimentional stability and the conditioning of the pore structure of crystal in the molded catalyst and also for the improvement of uniformly dispersing the components of the catalytic composition.The characteristic feature of the ZKU-2, 3 and 4 catalysts of the present invention has been compared with that of the ZSM-34 catalyst.

    摘要翻译： 本发明涉及提供具有优异的催化活性和选择性以及长期催化寿命的新型结晶沸石催化剂（ZKU-催化剂）。 所述催化剂（ZKU-2催化剂）的方法之一在于在四烷基（甲基或乙基或其组合）铵阳离子结晶的结晶调节剂存在下使起始沸石制剂结晶。 所述催化剂（ZKU-3,4催化剂）的另一种方法在于在所述结晶调理剂和能够形成晶种的物质和/或晶体的晶体存在下，使起始沸石制剂结晶。 ZKU-3催化剂使用晶体晶种制造，而ZKU-4催化剂使用晶种和晶体晶体制造。 晶体种子对于结晶速率的促进剂和催化活性的提高是有用的，晶体的碳化硅可用于所谓的“skelton”，其用于改善机械强度，尺寸稳定性和 调节成型催化剂中晶体的孔结构，以及改进均匀分散催化剂组合物的组分。 本发明的ZKU-2,3和4催化剂的特征与ZSM-34催化剂的特征进行了比较。