Low volatiles coatings, sealants and binders from renewable oils
    11.
    发明授权
    Low volatiles coatings, sealants and binders from renewable oils 有权
    低挥发性涂料,密封剂和可再生油的粘合剂

    公开(公告)号:US08486526B2

    公开(公告)日:2013-07-16

    申请号:US12597061

    申请日:2008-04-10

    摘要: A composition comprises (a) a binder component which comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) a crosslinking component reactive with hydroxyl groups. Furthermore, a process for producing a coating, adhesive, binder or combination thereof on the surface of a substrate, comprises in any order: (a) admixing binder and crosslinking components of a composition to form an admixture, wherein a binder component comprises (1) 5 to 100 weight percent of at least one natural oil derived polyol having at least about 50 percent primary hydroxyl groups and (2) sufficient additional polyol different from a natural oil derived polyol to make 100 percent wherein the natural oil derived polyol has an average of from 1.5 to 3 hydroxyl groups per molecule and an equivalent weight of from 200 to 5000; and (b) applying a layer of said admixture on said surface. The invention includes coatings, adhesives, binders and combinations thereof prepared from any composition of the invention, substrates coated by the process of the invention or coated using a composition of the invention and articles, including laminates, comprising a coating, adhesive, binder or combination thereof of the invention.

    摘要翻译: 组合物包含(a)粘合剂组分,其包含(1)5至100重量%的至少一种具有至少约50%伯羟基的天然油衍生的多元醇和(2)与天然油衍生的多元醇不同的足够的另外的多元醇 以制备100%,其中天然油衍生的多元醇的平均值为每分子1.5至3个羟基,当量为200至5000; 和(b)与羟基反应的交联组分。 此外,在基材表面上制备涂料,粘合剂,粘合剂或其组合的方法包括以下任意顺序:(a)混合粘合剂和组合物的交联组分以形成混合物,其中粘合剂组分包含(1 )5至100重量%的至少一种具有至少约50%伯羟基的天然油衍生的多元醇,和(2)与天然油衍生的多元醇不同的足够额外的多元醇以制备100%,其中天然油衍生的多元醇具有平均值 每个分子为1.5至3个羟基,当量为200至5000; 和(b)在所述表面上施加一层所述混合物。 本发明包括由本发明的任何组合物制备的涂料,粘合剂,粘合剂及其组合,通过本发明的方法涂覆的基材或使用本发明的组合物涂覆的基材和包括层压材料的制品,其包括涂料,粘合剂,粘合剂或组合 的本发明。

    Room temperature curable polymers and precursors thereof
    13.
    发明授权
    Room temperature curable polymers and precursors thereof 有权
    室温固化聚合物及其前体

    公开(公告)号:US08178645B2

    公开(公告)日:2012-05-15

    申请号:US12668609

    申请日:2008-07-10

    IPC分类号: C08G18/42 C08G63/00 C08G18/71

    摘要: A polyester polyol, referred to hereinafter as a MHMS polyol comprises fatty acid based mer units wherein at least about 80 weight percent of the fatty acid based mer units are from methyl 9 (10) hydroxymethylstearate, or is prepared from an oil having fatty acids or fatty acid esters which are at least about 80 weight percent oleic acid or esters thereof and which has an average hydroxyl functionality of from 1.5 to 4. A reaction product, referred to herein after as MHMS alkoxysilane prepolymer, is produced from at least one such MHMS polyol and at least one isocyanate functional silane. This prepolymer is moisture cured to form a silylated MHMS polymer.

    摘要翻译: 以下称为MHMS多元醇的聚酯多元醇包括脂肪酸基mer单元,其中至少约80重量%的脂肪酸​​基mer单元为9(10)羟甲基硬脂酸甲酯,或由具有脂肪酸或 至少约80重量%的油酸或其酯,并且其平均羟基官能度为1.5-4的脂肪酸酯。本文中称为MHMS烷氧基硅烷预聚物的反应产物由至少一种这样的MHMS 多元醇和至少一种异氰酸酯官能的硅烷。 将该预聚物水分固化以形成甲硅烷基化的MHMS聚合物。

    CURABLE SILYL POLYMERS
    15.
    发明申请
    CURABLE SILYL POLYMERS 审中-公开
    可固化的SILYL聚合物

    公开(公告)号:US20130096251A1

    公开(公告)日:2013-04-18

    申请号:US13700961

    申请日:2011-06-21

    IPC分类号: C08G18/83 C08G18/12

    摘要: Embodiments of the invention relate to crosslinkable silyl group-containing polymers and methods of producing them. In one embodiment a method of producing a silyl polymer is provided. The method includes reacting at least one natural oil based polyol with at least one isocyanate to form at least one prepolymer having at least one NCO group. The at least one natural oil based polyol includes the reaction product of hydroxymethylated fatty acids or esters thereof and at least one polyol initiator. The prepolymer having at least one NCO group is reacted with at least one amino functional alkoxy silane to form the silyl polymer, such that the silyl polymer includes at least one crosslinkable silyl group, at least one urethane group, and at least one urea group in each molecule.

    摘要翻译: 本发明的实施方案涉及可交联的含甲硅烷基的聚合物及其制备方法。 在一个实施方案中,提供了产生甲硅烷基聚合物的方法。 所述方法包括使至少一种天然油基多元醇与至少一种异氰酸酯反应以形成至少一种具有至少一个NCO基团的预聚物。 所述至少一种天然油基多元醇包括羟甲基化脂肪酸或其酯与至少一种多元醇引发剂的反应产物。 具有至少一个NCO基团的预聚物与至少一个氨基官能的烷氧基硅烷反应以形成甲硅烷基聚合物,使得甲硅烷基聚合物包括至少一个可交联甲硅烷基,至少一个氨基甲酸酯基和至少一个脲基 每个分子。

    POLYESTER COIL COATING FORMULATION
    17.
    发明申请
    POLYESTER COIL COATING FORMULATION 有权
    聚酯线圈涂层配方

    公开(公告)号:US20100076154A1

    公开(公告)日:2010-03-25

    申请号:US12523333

    申请日:2008-01-29

    IPC分类号: C09D167/00 C09D167/02

    CPC分类号: C09D167/00 C08G63/199

    摘要: In a curable coil coating composition comprising a mixture of: (a) a curable polyester that is a liquid at room temperature, (b) a cross-linking agent; and (c) a solvent; the improvement comprising preparing the polyester from a composition comprising a mixture of 1,3- and 1,4-cyclohexane dimethanol wherein the molar ratio of the 1, 3 isomer to the 1, 4 isomer is from about 60:40 to about 5:95. Cured coil coatings prepared from these compositions exhibit an excellent combination of flexibility and hardness.

    摘要翻译: 一种可固化线圈涂料组合物,其包含以下混合物:(a)在室温下为液体的可固化聚酯,(b)交联剂; 和(c)溶剂; 改进包括由包含1,3-和1,4-环己烷二甲醇的混合物的组合物制备聚酯,其中1,3异构体与1,4异构体的摩尔比为约60:40至约5: 95。 由这些组合物制备的固化线圈涂层显示出柔韧性和硬度的优异组合。

    Moisture-curable silicone corrosion resistant coatings
    18.
    发明授权
    Moisture-curable silicone corrosion resistant coatings 失效
    水分可固化硅树脂耐腐蚀涂料

    公开(公告)号:US5162460A

    公开(公告)日:1992-11-10

    申请号:US778049

    申请日:1991-10-17

    IPC分类号: C09D183/04 C09D183/08

    CPC分类号: C09D183/04 C09D183/08

    摘要: A method for imparting corrosion resistance to a metal substrate comprising coating said substrate with a moisture-curable silicone composition is disclosed. The composition consists essentially of a tetrafunctional or hexafunctional silicone polymer (I) which is modified with a liquid organohydrogenpolysiloxane (II) such that, when the functional groups of (I) are alkoxy radicals, the organohydrogenpolysiloxane contains at least 4 silicon hydride groups per molecule and when the functional groups of (I) are oxime groups, the organohydrogenpolysiloxane contains at least 5 silicon hydride groups per molecule.

    摘要翻译: 公开了一种赋予金属基材耐腐蚀性的方法,包括用可湿气固化的硅氧烷组合物涂覆所述基材。 该组合物基本上由四官能或六官能硅氧烷聚合物(I)组成,其用液体有机氢聚硅氧烷(II)改性,使得当(I)的官能团为烷氧基时,有机氢聚硅氧烷每分子含有至少4个氢化硅基团 当(I)的官能团为肟基时,有机氢聚硅氧烷每分子含有至少5个氢化硅基团。

    Compositions and antireflective coatings for photolithography
    19.
    发明授权
    Compositions and antireflective coatings for photolithography 有权
    用于光刻的组合物和抗反射涂层

    公开(公告)号:US09011591B2

    公开(公告)日:2015-04-21

    申请号:US13596191

    申请日:2012-08-28

    IPC分类号: C08G77/22 G03F7/075 G03F7/09

    摘要: Compositions for use in microelectronic applications: Ra comprises one or more multiple bonds, provided that, if Ra comprises more than one multiple bond, these multiple bonds are not in a conjugated configuration; and R1, R2, R3 are independently selected from alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and Rb is selected from H or a saturated group comprising alkyl, alkylene, or alkylidene; and R4, R5, R6 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and Rc comprises more than one multiple bond, and these multiple bonds are in a conjugated configuration; and R7, R8, R9 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl; and R10, R11, R12, R13 are independently alkoxyl, hydroxyl, halide, OC(O)R, OC(O)OR, wherein R is alkyl or a substituted alkyl.

    摘要翻译: 用于微电子应用的组合物:Ra包括一个或多个多重键,条件是如果Ra包含多于多个键,则这些多重键不是共轭构型; R 1,R 2,R 3独立地选自烷氧基,羟基,卤素,OC(O)R,OC(O)OR,其中R是烷基或取代的烷基; 并且R b选自H或包含烷基,亚烷基或亚烷基的饱和基团; 和R 4,R 5,R 6独立地是烷氧基,羟基,卤素,OC(O)R,OC(O)OR,其中R是烷基或取代的烷基; 并且R c包含多于一个多重键,并且这些多重键是共轭构型; 并且R 7,R 8,R 9分别是烷氧基,羟基,卤素,OC(O)R,OC(O)OR,其中R是烷基或取代的烷基; R 10,R 11,R 12,R 13分别是烷氧基,羟基,卤素,OC(O)R,OC(O)OR,其中R是烷基或取代的烷基。