Abstract:
A filler, pigment or mineral powder surface treated with a silicon compound is described. The silicon compound is a polydiorganosiloxane having at least one terminal group of the formula —SiR″(OR′)2 or —Si(OR′)3, wherein R″ represents an alkyl, substituted alkyl, alkenyl or aryl group and each R′ represents an alkyl group having 1 to 4 carbon atoms. The filler, pigment or mineral powder treated is hydrophobic and is used in composites or industrial processes.
Abstract:
This invention relates to a method of functionalising a powdered substrate. The method comprises the following steps, which method comprises passing a gas into a means for forming excited and/or unstable gas species, typically an atmospheric pressure plasma or the like and treating the gas such that, upon leaving said means, the gas comprises excited and/or unstable gas species which are substantially free of electric charge. The gas comprising the excited and/or unstable gas species which are substantially free of electric charge is then used to treat a powdered substrate and a functionalising precursor in a downstream region external to the means for forming excited and/or unstable gas, wherein neither the powdered substrate nor the functionalising precursor have been subjected to steps (i) and (ii) and wherein said functionalising precursor is introduced simultaneously with or subsequent to introduction of the powdered substrate. Preferably the method takes place in a fluidised bed.
Abstract:
A method of forming a powder and/or discrete gel particles of a compound selected from the group of a metallic oxide, a metalloid oxide, a mixed oxide, an organometallic oxide, an organometalloid oxide, an organomixed oxide resin, and/or an organic resin from one or more respective organometallic precursor(s), organometalloid precursor(s) and/or organic precursors and mixtures thereof, comprising the steps of passing a gas into a means for forming excited and/or unstable gas species (1a), typically an atmospheric plasma generating means; treating said gas such that upon leaving said means the gas comprises excited and/or unstable gas species which are substantially free of electrical charges at a temperature of between 10° C. and 500° C. A gaseous and/or liquid precursor is then introduced (50a,50b) into said excited and unstable gas species in a downstream region external (20) to the means for forming excited and/or unstable gas. The interaction between the precursor and the excited and unstable gas species results in the formation of a powder and/or discrete gelled particles which are subsequently collected. The particles prepared by the method may be subsequently functionalised.
Abstract:
A curable silicone resin composition comprises (A) an uncured silicone resin having units of the formula (R*)a(R)bSiO(4−a−b)/2, where each R* is a functional group capable of reacting with Si—OH and/or Si-alkoxy groups and each R is a nonfunctional monovalent hydrocarbon group, a+b is from 1.0 to 3.0 and each molecule of uncured silicone resin contains an average of at least two groups R*, and (B) a silanol or hydrolysable compound of the formula (I) where R′ represents a hydroxyl group or a hydrolysable group; each R″ represents hydrogen, a monovalent hydrocarbon which optionally is substituted, or a group within the above definition of R′; and Ar is a substantially nonflexible linkage including at least one para-arylene moiety, so that the groups (R′)2R″Si— are spatially separated.
Abstract:
This invention relates to an aqueous coating composition, a greaseproof article and a process of forming a coating on a substrate. The aqueous coating composition comprises at least the following components: an organopolysiloxane (A) which is a polysiloxane compound having at least two alkenyl groups per molecule, an organohydrogenpolysiloxane (B) which is a polysiloxane compound comprising at least two Si H groups per molecule, an hydrosilylation catalyst (C) able to catalyse an hydrosilylation reaction between the organopolysiloxane compound (A) and the organohydrogenpolysiloxane compound (B), an organic copolymer (D) comprising at least two types of repeating units (i) and (ii): unit (i) which is an alkyl group comprising from 2 to 2 carbon atoms, unit (ii) which is an alkyl group comprising from 2 to 12 carbon atoms and having at least one pendant alcohol substituent, water, and the composition is able to form upon curing by hydrosilylation a coating on a substrate.
Abstract:
This invention relates to an aqueous coating composition, a greaseproof article and a process of forming a coating on a substrate. The aqueous coating composition comprises at least the following components: an organopolysiloxane (A) which is a polysiloxane compound having at least two alkenyl groups per molecule, an organohydrogenpolysiloxane (B) which is a polysiloxane compound comprising at least two Si H groups per molecule, an hydrosilylation catalyst (C) able to catalyse an hydrosilylation reaction between the organopolysiloxane compound (A) and the organohydrogenpolysiloxane compound (B), an organic copolymer (D) comprising at least two types of repeating units (i) and (ii): unit (i) which is an alkyl group comprising from 2 to 2 carbon atoms, unit (ii) which is an alkyl group comprising from 2 to 12 carbon atoms and having at least one pendant alcohol substituent, water, and the composition is able to form upon curing by hydrosilylation a coating on a substrate.
Abstract:
A sealed stopper for an opening in a tubing for joining a chamber and a piping including a fastening ring is provided. The stopper includes a rigid bearing plate and a sealing member carried by the bearing plate, and includes a seal having a planar and flexible central portion with a reduced thickness extending below the bearing plate and a peripheral portion radially deformable by a central expander of the peripheral portion against the inner surface of the fastening ring.
Abstract:
The invention provides a process for improving the fire resistance of a thermoplastic or thermoset organic polymer composition, characterised in that an alkoxysilane containing at least one organic nitrogen-containing group and an alkoxysilane or silicone resin containing at least one group selected from phosphonate and phosphinate groups are added to a thermoplastic or thermosetting organic polymer composition and heated in the presence of moisture to cause hydrolysis and siloxane condensation of the alkoxysilane or alkoxysilanes. The alkoxysilanes, or alkoxysilane(s) and silicone resin, of the invention are particularly effective in increasing the fire resistance of polycarbonates and blends of polycarbonate with other resins such as polycarbonate/ABS blends.
Abstract:
A silicone resin, curable to a resin of low coefficient of thermal expansion, high glass transition temperature and high modulus, has the empirical formula (R3SiO2)a(R2SiO2/2)b(RsiO3/2)c(SiO4/2)d wherein each R is a hydrocarbon or substituted hydrocarbon group or a hydrogen atom; and a=0.02 to 0.8; b=0 to 0.4; and c+d=0.2 to 0.98, where a+b+c+d=1.0, characterized in that at least 2 mole % of the siloxane units in the resin are of the formula R′3SiO1/2 RR′2Sio1/2 or R′2SiO2/2 wherein each R′ is an alkenyl group.
Abstract translation:可固化成低热膨胀系数的树脂,高玻璃化转变温度和高模量的硅树脂具有经验式(R 3 SiO 2 SiO 2) (R 2 O 2/2/2)b(R 3 O 3/2 2)
Abstract:
A phenolic resin based laminate material which can be cross-linked by acid catalysis, endowed with a reinforcement, comprising at least two surfaces and having on at least one of its two surfaces at least one additional nonphenolic resin-based layer is disclosed.In accordance with the invention, the additional layer in contact with the phenolic resin is obtained from a formula comprising an unsaturated polyester resin, a cross-linking solvent of said resin, possibly one or several other additives, at least one of the main components having a formula comprising hydrophilic centers in a number at least equal to the number of non-saturation centers in the polymeric chain of the resin.