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    Polymerizable organosilicon nanocapsules
    12.
    发明申请
    Polymerizable organosilicon nanocapsules 失效
    可聚合的有机硅纳米胶囊

    公开(公告)号：US20060063002A1

    公开(公告)日：2006-03-23

    申请号：US11258025

    申请日：2005-10-26

    申请人： Roland Edelmann ,  Jaroslaw Monkiewicz

    发明人： Roland Edelmann ,  Jaroslaw Monkiewicz

    IPC分类号： B32B9/02

    CPC分类号： C08K9/06 ,  B01J13/02 ,  B82Y30/00 ,  C01P2004/64 ,  C01P2006/12 ,  C09C1/00 ,  C09C1/3081 ,  C09C1/3684 ,  C09C1/407 ,  C09C3/12 ,  Y10T428/2984

    摘要： The present invention provides a polymerizable organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle comprising at least one oxide or mixed oxide, KA-O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R   (Ia) wherein R is a vinyl or allyl group; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA-O)—, SiO— or -Z; wherein remaining free valences of Si′ are each independently (KA-O)—, SiO—, -R, or -Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.

    摘要翻译： 本发明提供了一种可聚合的有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种氧化物或混合氧化物的颗粒，KA-O，其至少一种金属或半金属选自包括主要 元素周期表第2至6组，周期表第1至8族，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（I）的有机硅化合物

    Fluoroalkyl-functional organopolysiloxane-containing compositions
    16.
    发明授权
    Fluoroalkyl-functional organopolysiloxane-containing compositions 失效
    含氟烷基官能的含有机聚硅氧烷的组合物

    公开(公告)号：US5863509A

    公开(公告)日：1999-01-26

    申请号：US94501

    申请日：1998-06-10

    申请人： Burkhard Standke ,  Roland Edelmann ,  Albert-Johannes Frings ,  Ralf Laven ,  Michael Horn ,  Peter Jenkner ,  Helmut Mack ,  Jaroslaw Monkiewicz

    发明人： Burkhard Standke ,  Roland Edelmann ,  Albert-Johannes Frings ,  Ralf Laven ,  Michael Horn ,  Peter Jenkner ,  Helmut Mack ,  Jaroslaw Monkiewicz

    IPC分类号： C09K3/00 ,  C03C17/30 ,  C03C25/40 ,  C04B41/49 ,  C08G77/22 ,  C08G77/24 ,  C08G77/26 ,  C08L83/08 ,  C09D5/00 ,  C09D183/08 ,  C09K3/18 ,  C14C9/00 ,  C23C30/00 ,  D06M15/657 ,  B05D7/00

    CPC分类号： C14C9/00 ,  C03C17/30 ,  C03C25/40 ,  C04B41/4961 ,  C08G77/22 ,  C08G77/24 ,  C08G77/26 ,  C09D183/08 ,  C09K3/18 ,  C23C30/00 ,  D06M15/657 ,  C23C2222/20 ,  D06M2101/06 ,  D06M2200/11 ,  D06M2200/12 ,  Y10T428/31663

    摘要： An aqueous alcoholic fluoroalkyl functional group containing organopolysiloxane-composition, comprising:organopolysiloxanes of formula I:RO�Si(A)(CH.sub.3).sub.z (OR).sub.1-z O!.sub.a �Si(B)(R.sup.2).sub.y (OR).sub.1-y O!.sub.b �Si(C)(CH.sub.3)O!.sub.c �Si(D)(OR)O!.sub.d R.multidot.(HX) (I)wherein A is an aminoalkyl radical derived from the compound of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II)wherein 0.ltoreq.f.ltoreq.6, 9=0 if f=0 and g=1 if f>0, 0.ltoreq.h.ltoreq.6 and 0.ltoreq.z.ltoreq.1, and B is a fluoroalkyl radical derived from the compound of formula III:R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y (III)wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sub.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltoreq.y.ltoreq.1, and C is an alkyl radical derived from the compound of formula IV:R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV)and D is also an alkyl radical derived from the compound of formula V:R.sup.3 --Si(OR).sub.3 (V)wherein R.sup.3 in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, R in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group, and HX is an acid, in which X is an inorganic or organic acid radical, and 0.ltoreq.y.ltoreq.1, 0.ltoreq.z.ltoreq.1, a>0, b>0, c.gtoreq.0, d.gtoreq.0, e.gtoreq.0 and (a+b+c+d).gtoreq.2.

    摘要翻译： 含有有机聚硅氧烷组合物的含水醇氟代烷基官能团包括：式I的有机聚硅氧烷：RO [Si（A）（CH3）z（OR）1-zO] a [Si（B）（R2）y（OR） yO] b [Si（C）（CH3）O] c [Si（D）（OR）O] dRx（HX）（I）其中A是衍生自式II化合物的氨基烷基：H 2 N（CH 2）f （NH）g（CH 2）h Si（OR）3-z（CH 3）z（II）其中0 0，则g = R =（Y） - （CH 2）2 Si（R 2）y（OR）3-y （III）其中R1是具有1-9个C原子的单，低聚或全氟烷基或单，低聚或全氟化的芳基，Y是CH 2，O或S基团，R 2是直链，支链 或具有1-8个碳原子或芳基且0≤y≤1的环状烷基，C是衍生自式IV化合物的烷基：R3-Si（CH3）（OR）2（ IV），D也是衍生自式V化合物的烷基：R3-Si（OR）3（V）其中前述通式中的R 3在每种情况下均为 或具有1-8个C原子的直链，支链或环状烷基，前述式中的R各自相同或不同，为具有1-8个C原子的直链，支链或环状烷基 或芳基，并且HX是酸，其中X是无机或有机酸基团，并且0≤y≤1,0≤z≤1，a> 0，b> 0 ，c> / = 0，d> / = 0，e> / = 0和（a + b + c + d）> / = 2。

    Organosilicon nanocapsules
    20.
    发明授权
    Organosilicon nanocapsules 失效
    有机硅纳米胶囊

    公开(公告)号：US06689468B2

    公开(公告)日：2004-02-10

    申请号：US09971146

    申请日：2001-10-05

    申请人： Roland Edelmann ,  Jaroslaw Monkiewicz

    发明人： Roland Edelmann ,  Jaroslaw Monkiewicz

    IPC分类号： C08K900

    CPC分类号： C09C3/006 ,  C01P2004/64 ,  C01P2006/12 ,  C08K9/06 ,  C09C1/3072 ,  C09C1/3081 ,  C09C1/309 ,  C09C3/10 ,  C09C3/12 ,  Y10T428/2991 ,  Y10T428/2993 ,  Y10T428/2995 ,  Y10T428/2996 ,  Y10T428/2998

    摘要： The present invention provides an organosilicon nanocapsule, which includes: a nanoscale core A, which includes: at least one particle including at least one oxide or mixed oxide, KA—O, of at least one metal or semimetal selected from the group including main groups 2 to 6 of the Periodic Table, transition groups 1 to 8 of the Periodic Table, lanthanides, and mixtures thereof; and an organosilicon shell B, which includes: at least one organosilicon compound having the formula (Ia): (Si′O—)xSi—R  (Ia) wherein R is a linear, branched, cyclic or substituted alkyl group having from 1 to 50 carbon atoms; wherein x is a number from 0 to 20; wherein remaining free valences of Si are each independently (KA—O)—, SiO— or —Z; wherein remaining free valences of Si′ are each independently (KA—O)—, SiO—, —R, or —Z; wherein the Z's are each independently hydroxyl or alkoxy radicals; and wherein each Si and Si′ in the shell B have not more than one R group attatched thereto.

    摘要翻译： 本发明提供了一种有机硅纳米胶囊，其包括：纳米级芯A，其包括：至少一种包含至少一种选自包括主要基团的金属或半金属的金属或半金属的氧化物或混合氧化物KA-O的颗粒 周期表的2至6，周期表的过渡组1至8，镧系元素及其混合物; 和有机硅壳B，其包括：至少一种具有式（Ia）的有机硅化合物：其中R是具有1至50个碳原子的直链，支链，环状或取代的烷基;其中x是0至20的数 ;其中Si的剩余游离价分别独立地为（KA-O） - ，SiO-或-Z;其中Si'的剩余游离价各自独立地为（KA-O） - ， - SiO-，-R或-Z; 其中Z各自独立地为羟基或烷氧基; 并且其中壳体B中的每个Si和Si'具有不多于一个R基团。