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公开(公告)号:US5705456A
公开(公告)日:1998-01-06
申请号:US758537
申请日:1996-11-29
IPC分类号: A01N43/36 , A01N43/44 , A01N43/74 , A01N43/76 , A01N43/78 , C07D207/26 , C07D207/273 , C07D263/28 , C07D277/18 , C07D403/04 , C07D413/04 , C07D417/04 , A01N43/50
CPC分类号: C07D207/273 , A01N43/44 , A01N43/74 , C07D263/28 , C07D277/18 , C07D403/04 , C07D413/04 , C07D417/04
摘要: Compounds of formula I: ##STR1## where n is 0 or an integer from 1 to 5; X is halogen, nitro or cyano, or C.sub.1-10 hydrocarbyl or C.sub.1-10 hydrocarbyloxy, either of which may be substituted with one or more halogen atoms; Y is CH.sub.2, O or S; and R.sup.1 and R.sup.2 independently represent hydrogen, C.sub.1-6 alkyl, C.sub.1-6 haloalkyl, C.sub.2-6 alkenyl, C.sub.2-6 alkynyl or halogen; Processes for the preparation of compounds of formula I, herbicidal compositions and methods utilising them are also disclosed.
摘要翻译: 式I化合物:其中n为0或1至5的整数; X是卤素,硝基或氰基,或C 1-10烃基或C 1-10烃氧基,其可以被一个或多个卤素原子取代; Y是CH 2,O或S; 并且R 1和R 2独立地表示氢,C 1-6烷基,C 1-6卤代烷基,C 2-6烯基,C 2-6炔基或卤素; 还公开了制备式I化合物的方法,除草组合物和利用它们的方法。
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公开(公告)号:US5426091A
公开(公告)日:1995-06-20
申请号:US102004
申请日:1993-08-04
申请人: John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
发明人: John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
IPC分类号: A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/92 , A47J37/12 , C07C45/51 , C07C45/54 , C07C45/60 , C07C45/67 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/32 , C07D207/333 , C07D207/34 , C07D207/36 , C07D209/12 , C07D215/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D231/20 , C07D231/22 , C07D233/84 , C07D237/12 , C07D237/28 , C07D237/30 , C07D239/26 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/54 , C07D263/56 , C07D277/20 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/20 , C07D403/06 , C07D223/06
CPC分类号: C07D207/333 , A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/78 , A01N43/80 , A47J37/1266 , C07C45/512 , C07C45/54 , C07C45/60 , C07C45/673 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/36 , C07D209/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D233/84 , C07D237/12 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/56 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/1917 , G05D23/20
摘要: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen, R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要翻译: 式(I)的化合物:其中,酰化物,磺酸盐,氨基甲酸酯或醚衍生物;或其盐,烯胺等; 其中X,X 1和X 2独立地是氧或硫,R 1是任选取代的杂环或环烷基,Y是任选被氧原子插入的任选取代的C 2 -C 4亚烷基, 图像>或任选单取代的氮原子,其中p为0,1或2,s为0或1,Rb为烷基或烷氧基; 条件是当X,X 1和X 2是氧时,R 1不是吡啶基或嘧啶基。 还描述和要求保护这些化合物和含有它们的除草组合物的制备方法。
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公开(公告)号:US5250501A
公开(公告)日:1993-10-05
申请号:US819080
申请日:1992-01-10
申请人: John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
发明人: John E. D. Barton , David Cartwright , John M. Cox , Glynn Mitchell , Charles G. Carter , David L. Lee , Francis H. Walker , Frank X. Woolard
IPC分类号: A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/12 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/76 , A01N43/78 , A01N43/80 , A01N43/92 , A47J37/12 , C07C45/51 , C07C45/54 , C07C45/60 , C07C45/67 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/32 , C07D207/333 , C07D207/34 , C07D207/36 , C07D209/12 , C07D215/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D231/20 , C07D231/22 , C07D233/84 , C07D237/12 , C07D237/28 , C07D237/30 , C07D239/26 , C07D239/74 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/54 , C07D263/56 , C07D277/20 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/20 , C07D275/02
CPC分类号: C07D207/333 , A01N35/06 , A01N37/08 , A01N43/08 , A01N43/10 , A01N43/30 , A01N43/32 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/50 , A01N43/56 , A01N43/58 , A01N43/60 , A01N43/78 , A01N43/80 , A47J37/1266 , C07C45/512 , C07C45/54 , C07C45/60 , C07C45/673 , C07C45/72 , C07C49/403 , C07C49/713 , C07C49/792 , C07C49/813 , C07C49/835 , C07D207/36 , C07D209/12 , C07D215/14 , C07D215/36 , C07D231/12 , C07D231/16 , C07D233/84 , C07D237/12 , C07D241/12 , C07D241/16 , C07D241/42 , C07D261/08 , C07D263/56 , C07D277/24 , C07D277/32 , C07D277/36 , C07D307/70 , C07D307/71 , C07D317/52 , C07D317/62 , C07D319/08 , C07D319/18 , C07D333/22 , C07D333/28 , C07D333/62 , C07D409/04 , C07D417/04 , C07F9/6568 , G05D23/1917 , G05D23/20
摘要: A compound of formula (I): ##STR1## or a salt, enamine or the like, acylate, sulphonate, carbamate or ether derivative thereof; wherein X, X.sup.1 and X.sup.2 are independently oxygen or sulphur, R.sup.1 is an optionally substituted heterocyclic or cycloalkyl group, and Y is an optionally substituted C.sub.2 -C.sub.4 alkylene group which is optionally interposed by an oxygen atom, a group ##STR2## or an optionally mono-substituted nitrogen atom, wherein p is 0, 1 or 2, s is 0 or 1 and R.sup.b is alkyl or alkoxy; provided that when X, X.sup.1 and X.sup.2 are oxygen R.sup.1 is not pyridyl or pyrimidinyl. Processes for the preparation of these compounds and herbicidal compositions containing them are also described and claimed.
摘要翻译: 式(I)的化合物:其中,酰化物,磺酸盐,氨基甲酸酯或醚衍生物;或其盐,烯胺等; 其中X,X 1和X 2独立地是氧或硫,R 1是任选取代的杂环或环烷基,Y是任选被取代的C 2 -C 4亚烷基,其任选被氧原子插入, 单取代氮原子,其中p为0,1或2,s为0或1,Rb为烷基或烷氧基; 条件是当X,X 1和X 2为氧时,R 1不是吡啶基或嘧啶基。 还描述和要求保护这些化合物和含有它们的除草组合物的制备方法。
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公开(公告)号:US08642836B2
公开(公告)日:2014-02-04
申请号:US12111364
申请日:2008-04-29
申请人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
发明人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
CPC分类号: C12N9/0024 , C12N9/18 , C12N15/8287 , C12N15/8289 , C12N15/829 , C12P13/04 , C12P41/007
摘要: A method of producing male or female sterile plants comprising the steps of transforming plant material with a polynucleotide which encodes at least one enzyme which reacts with a non-phytotoxic substance to produce a phytotoxic one, and regenerating the thus transformed material into a plant, wherein the said non-phytotoxic substance is applied to the plant up to the time of male or female gamete formation and/or maturation, so that the non-phytotoxic substance provides for the production of a phytotoxic one which selectively prevents the formation of or otherwise renders the said gametes non-functional, wherein the enzyme is expressed preferentially in either male or female reproductive structures, characterized in that (i) the non-phytotoxic substance is a D-alpha amino acid, and (ii) the enzyme is a D-amino acid oxidase.
摘要翻译: 一种产生雄性或雌性不育植物的方法,包括以编码与非植物毒性物质反应产生植物毒性物质的至少一种酶的多核苷酸转化植物材料并将由此转化的材料再生成植物的步骤,其中 所述非植物毒性物质直到雄性或雌性配子形成和/或成熟时被施用于植物,使得非植物毒性物质提供了用于选择性地防止形成或以其它方式形成的植物毒性物质 所述配子是非功能性的,其中所述酶优先在雄性或雌性生殖结构中表达,其特征在于(i)非植物毒性物质是D-α氨基酸,和(ii)所述酶是D- 氨基酸氧化酶。
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公开(公告)号:US20120094833A1
公开(公告)日:2012-04-19
申请号:US13263248
申请日:2010-03-31
申请人: Roger Salmon , Glynn Mitchell , James Alan Morris
发明人: Roger Salmon , Glynn Mitchell , James Alan Morris
IPC分类号: A01N25/32 , A01P13/00 , A01N43/90 , A01N43/42 , C07D471/04 , C07D215/227
CPC分类号: C07D471/04 , A01N43/42 , A01N43/90 , C07D215/227
摘要: The present invention relates to novel herbicidal oxopyridine and thionopyridine derivatives of Formula (I), or an agronomically acceptable salt of said compound wherein R1, R5, R6, R7, X1, X2 and Q are as defined herein. The invention further relates to processes and intermediates for the preparation of the oxopyridine derivatives, to compositions which comprise the herbicidal compounds, and to their use for controlling weeds, in particular in crops of useful plants.
摘要翻译: 本发明涉及式(I)的新型除草氧代吡啶和噻吩并吡啶衍生物,或其中R 1,R 5,R 6,R 7,X 1,X 2和Q如本文所定义的所述化合物的农艺学上可接受的盐。 本发明还涉及用于制备氧代吡啶衍生物的方法和中间体,包含除草化合物的组合物及其用于防治杂草的用途,特别是在有用植物的作物中。
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公开(公告)号:US07939709B2
公开(公告)日:2011-05-10
申请号:US10504784
申请日:2003-02-14
申请人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
发明人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
CPC分类号: C12N9/0024 , C12N9/18 , C12N15/8287 , C12N15/8289 , C12N15/829 , C12P13/04 , C12P41/007
摘要: A method of producing male or female sterile plants comprising the steps of transforming plant material with a polynucleotide which encodes at least one enzyme which reacts with a non-phytotoxic substance to produce a phytotoxic one, and regenerating the thus transformed material into a plant, wherein the said non-phytotoxic substance is applied to the plant up to the time of male or female gamete formation and/or maturation, so that the non-phytotoxic substance provides for the production of a phytotoxic one which selectively prevents the formation of or otherwise renders the said gametes non-functional, wherein the enzyme is expressed preferentially in either male or female reproductive structures, characterised in that (i) the non-phytotoxic substance is a D-alpha amino acid, and (ii) the enzyme is a D-amino acid oxidase.
摘要翻译: 一种产生雄性或雌性不育植物的方法,包括以编码与非植物毒性物质反应产生植物毒性物质的至少一种酶的多核苷酸转化植物材料并将由此转化的材料再生成植物的步骤,其中 所述非植物毒性物质直到雄性或雌性配子形成和/或成熟时被施用于植物,使得非植物毒性物质提供了用于选择性地防止形成或以其它方式形成的植物毒性物质 所述配子是非功能性的,其中所述酶优先在雄性或雌性生殖结构中表达,其特征在于(i)非植物毒性物质是D-α氨基酸,和(ii)所述酶是D- 氨基酸氧化酶。
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公开(公告)号:US20100291643A1
公开(公告)日:2010-11-18
申请号:US12818548
申请日:2010-06-18
申请人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
发明人: Timothy Robert Hawkes , Glynn Mitchell , Stephen Thomas Hadfield , Paul Anthony Thompson , Russell Viner , Yan Zhang
IPC分类号: C12P9/00
CPC分类号: C12N9/0024 , C12N9/18 , C12N15/8287 , C12N15/8289 , C12N15/829 , C12P13/04 , C12P41/007
摘要: A method of producing enantimoerically pure D-Phosphinothricin (D-PPT) by providing a mixture of D and L PPT, N-acetylating L-PPT and then recovering and purifying D-PPT.
摘要翻译: 通过提供D和L PPT,N-乙酰化L-PPT的混合物,然后回收和纯化D-PPT,制备具有同义词的纯D - 膦丝菌素(D-PPT)的方法。
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公开(公告)号:US20050150013A1
公开(公告)日:2005-07-07
申请号:US10504784
申请日:2003-02-14
申请人: Timothy Hawkes , Glynn Mitchell , Stephen Hadfield , Paul Thompson , Russell Viner , Yan Zhang
发明人: Timothy Hawkes , Glynn Mitchell , Stephen Hadfield , Paul Thompson , Russell Viner , Yan Zhang
IPC分类号: A01H1/00 , A01N37/34 , A01N37/44 , A01N39/02 , A01N43/40 , A01N43/60 , A01N43/76 , A01N57/20 , A01N63/00 , C07F9/38 , C12N9/06 , C12N9/18 , C12N15/09 , C12N15/82 , C12P9/00 , C12P13/04 , C12P41/00
CPC分类号: C12N9/0024 , C12N9/18 , C12N15/8287 , C12N15/8289 , C12N15/829 , C12P13/04 , C12P41/007
摘要: A method of producing male or female sterile plants comprising the steps of transforming plant material with a polynucleotide which encodes at least one enzyme which reacts with a non-phytotoxic substance to produce a phytotoxic one, and regenerating the thus transformed material into a plant, wherein the said non-phytotoxic substance is applied to the plant up to the time of male or female gamete formation and/or maturation, so that the non-phytotoxic substance provides for the production of a phytotoxic one which selectively prevents the formation of or otherwise renders the said gametes non-functional, wherein the enzyme is expressed preferentially in either male or female reproductive structures, characterised in that (i) the non-phytotoxic substance is selected from the group consisting of ester derivatives of non-phosphonate herbicides which herbicides are directly phytotoxic to non-green tissue, D-alpha amino acids, peptide derivatives of non-protein D-alpha amino acids, S-enantiomers of aryloxyphenoxypropionates and S-enantiomers of ester derivatives of aryloxyphenoxypropionates and (ii) the enzyme is selected from the group consisting of carboxylesterases, D-amino acid oxidases, D-amino acid dehydrogenases, D-amino acid racemases, 2-arylpropionyl-CoA epimerases, alpha-methylacyl-CoA racemases, thioesterases and acyl-CoA synthetases.
摘要翻译: 一种产生雄性或雌性不育植物的方法,包括以编码与非植物毒性物质反应产生植物毒性物质的至少一种酶的多核苷酸转化植物材料并将由此转化的材料再生成植物的步骤,其中 所述非植物毒性物质直到雄性或雌性配子形成和/或成熟时被施用于植物,使得非植物毒性物质提供了用于选择性地防止形成或以其它方式形成的植物毒性物质 所述配子是非功能性的,其中所述酶优先在雄性或雌性生殖结构中表达,其特征在于(i)非植物毒性物质选自除草剂直接的非膦酸酯除草剂的酯衍生物 对非绿色组织的植物毒性,D-α氨基酸,非蛋白D-α氨基酸的肽衍生物,S-enant 芳氧基苯氧基丙酸酯的酯衍生物的芳氧基苯氧基丙酸酯和S-对映体的异单体和(ii)该酶选自羧酸酯酶,D-氨基酸氧化酶,D-氨基酸脱氢酶,D-氨基酸消旋酶,2-芳基丙酰辅酶A 差向异构酶,α-甲基酰基-CoA消旋酶,硫酯酶和酰基辅酶A合成酶。
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公开(公告)号:US6022976A
公开(公告)日:2000-02-08
申请号:US117489
申请日:1998-07-28
IPC分类号: C07D263/18 , C07D277/14 , C07D263/04 , C07D231/04
CPC分类号: C07D277/14 , C07D263/18
摘要: A process for the production of hydroxy-substituted oxazolidinones, particularly 5-hydroxyoxazolidinones, which are useful as intermediates in the synthesis of herbicidally active compounds, comprising treating a hydroxythiazolidinone with an oxidizing agent.
摘要翻译: PCT No.PCT / GB97 / 00130 Sec。 371日期:1998年7月28日 102(e)日期1998年7月28日PCT 1997年1月17日PCT PCT。 公开号WO97 / 28138 日期1997年8月7日制备羟基取代的恶唑烷酮,特别是5-羟基恶唑烷酮的方法,其可用作合成除草活性化合物的中间体,包括用氧化剂处理羟基噻唑烷酮。
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公开(公告)号:US5688962A
公开(公告)日:1997-11-18
申请号:US649843
申请日:1996-05-16
申请人: John Michael Cox , David Philip John Pearson , Anthony Marian Kozakiewicz , Richard Butler Moore , Glynn Mitchell , David William Langton , Russell Ellis
发明人: John Michael Cox , David Philip John Pearson , Anthony Marian Kozakiewicz , Richard Butler Moore , Glynn Mitchell , David William Langton , Russell Ellis
IPC分类号: C07D263/20 , C07D263/18 , C07D263/28 , C07D263/04 , C07D263/16 , C07D263/46
CPC分类号: C07D263/18 , C07D263/28
摘要: A process for the synthesis of a compound of general formula II: ##STR1## wherein: R.sup.2 and R.sup.3 are each independently hydrogen or C.sub.1 -C.sub.4 alkyl; A is an aromatic or heteroaromatic ring system optionally substituted with one or more substituents as defined herein; and in which any ring nitrogen atom may be quaternised or oxidised; alternatively, any two substituents of the group A may combine to form a fused 5- or 6-membered saturated or partially saturated carbocyclic or heterocyclic ring in which any carbon or quaternised nitrogen atom may be substituted with any of the groups defined herein for A or in which a ring carbon atom may be oxidised; the process comprising cyclising a compound of general formula VII: ##STR2## wherein A, R.sup.2 and R.sup.3 are as defined for general formula II, R.sup.20 is hydrogen, benzyl or benzyl substituted with up to five substituents selected from halo, C.sub.1 -C.sub.6 alkyl, O(C.sub.1 -C.sub.6 alkyl) or nitro and R.sub.21 is C.sub.1 -C.sub.8 alkyl, benzyl or benzyl substituted with up to five of the substituents mentioned above for R.sup.20.
摘要翻译: 合成通式II化合物的方法:其中:R 2和R 3各自独立地为氢或C 1 -C 4烷基; A是任选被一个或多个如本文定义的取代基取代的芳族或杂芳族环系统; 并且其中任何环氮原子可被季铵化或氧化; 可选地,基团A的任何两个取代基可以结合形成稠合的5-或6-元饱和或部分饱和的碳环或杂环,其中任何碳或季铵化的氮原子可以被本文定义的任何A或 其中环碳原子可被氧化; 该方法包括环化通式VII的化合物:其中A,R 2和R 3如通式II所定义,R 20是氢,被至多5个选自卤素,C 1 -C 6烷基的取代基取代的苄基或苄基 ,O(C 1 -C 6烷基)或硝基,R 21是C 1 -C 8烷基,被至多5个上述R 20取代基取代的苄基或苄基。
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