公开(公告)号：US3328463A

公开(公告)日：1967-06-27

申请号：US37933964

申请日：1964-06-30

Applicant: STANDARD OIL CO

Inventor： LEE RICHARD J

IPC: C07F5/02 ,  C08F8/30 ,  C10L1/22 ,  C10L1/23 ,  C10M133/22

CPC classification number: C10M133/22 ,  C07C201/12 ,  C07F5/022 ,  C08F8/12 ,  C08F8/30 ,  C08F8/42 ,  C10L1/221 ,  C10L1/231 ,  C10M2207/282 ,  C10M2207/34 ,  C10M2209/103 ,  C10M2223/045 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2240/02 ,  C10N2250/10 ,  C07C205/45 ,  C08F110/08 ,  C08F8/32

公开(公告)号：US3876709A

公开(公告)日：1975-04-08

申请号：US30112572

申请日：1972-10-26

Applicant: STANDARD OIL CO

Inventor： LEE RICHARD J ,  KARLL ROBERT E

IPC: C07C37/11 ,  C08G81/02 ,  C07C39/12 ,  C07C37/00

CPC classification number: C08G81/021 ,  C07C37/11 ,  C07C39/15

Abstract: Derivatives of nuclear coupled alkylphenols, that is nuclear carbon-to-carbon coupling, have higher activity as lubricating oil addition agents than the same derivatives of the parent alkylphenols. For example, sulfonamides or products of the Mannich Reaction derived from coupled p-alkylphenolsulfonyl chloride and an amine or coupled alkylphenol, amine and formaldehyde have higher activity than the same derivatives from the parent p-alkylphenol. Two, three, four, five, six and up to seven molecules of alkylphenol can be coupled through nuclear carbon-to-carbon coupling in the presence of a lower alkanoic acid (e.g., acetic acid) solution of potassium dichromate and manganese acetate.

公开(公告)号：US3689561A

公开(公告)日：1972-09-05

申请号：US3689561D

申请日：1969-07-30

Applicant: STANDARD OIL CO

Inventor： LEE RICHARD J ,  KARLL ROBERT E

IPC: C09K8/32 ,  C10L1/23 ,  C07C85/00

CPC classification number: C10L1/231 ,  C09K8/32

Abstract: Nitration of an alkene with dinitrogen tetroxide under oxidizing conditions forms the corresponding vicinal nitro-, nitratosubstituted alkane. Reaction of about 1-4 mols of the nitronitrato alkane with 1 mol of an alkylamine or alkylene polyamine forms alkane nitro-amines containing vicinal nitro-, aminonitrogen groups. The alkane nitro-amines are useful as surfactants, rust or corrosion inhibitors, flotation agents and as additives in petroleum products.

Abstract translation: 在氧化条件下用四氧化二氮氮化硝化形成相应的邻位硝基 - 硝基取代的烷烃。 约1-4摩尔硝基 - 硝基烷烃与1摩尔烷基胺或亚烷基多胺的反应形成含有邻位硝基，氨基 - 氮基团的烷烃硝基胺。 烷烃硝基胺可用作石油产品中的表面活性剂，防锈剂或腐蚀抑制剂，浮选剂和添加剂。

公开(公告)号：US3235497A

公开(公告)日：1966-02-15

申请号：US21884662

申请日：1962-08-23

Applicant: STANDARD OIL CO

Inventor： LEE RICHARD J

IPC: C07F9/04 ,  C07F9/28 ,  C10M159/12

CPC classification number: C07F9/04 ,  C07F9/28 ,  C10M159/123 ,  C10M2207/123 ,  C10M2207/129 ,  C10M2207/22 ,  C10M2211/08 ,  C10M2215/04 ,  C10M2215/044 ,  C10M2215/06 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/086 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2223/045 ,  C10M2223/063 ,  C10M2223/065 ,  C10M2225/00 ,  C10M2225/02

公开(公告)号：US3873627A

公开(公告)日：1975-03-25

申请号：US30112272

申请日：1972-10-26

Applicant: STANDARD OIL CO

Inventor： LEE RICHARD J ,  KARLL ROBERT E

IPC: C07C37/11 ,  C07D295/26 ,  C08F8/00 ,  C07C37/14 ,  C07C39/12

CPC classification number: C07D295/26 ,  C07C37/11 ,  C08F8/00 ,  C08F110/00 ,  C07C39/15

Abstract: Derivatives of dimeric nuclear carbon-to-carbon coupled palkylphenol have higher activity as lubricating oil addition agents than the same derivative of present p-alkylphenol. For example, sulfonamide or methylene-imine (i.e., product of Mannich Reaction) derivatives of dimeric coupled p-alkylphenol sulfonylchloride or dimeric coupled alkylphenol are more active dispersants than the same sulfonamide or methyleneamine derivative of the parent alkylphenolsulfonyl chloride or palkylphenol. Such dimeric p-alkylphenols can be prepared by oxidative coupling in aqueous alkaline medium in presence of potassium ferricyanide.

Abstract translation: 二聚核碳 - 碳偶联的对 - 烷基酚的衍生物与现有的对烷基酚相同的衍生物具有较高的作为润滑油添加剂的活性。 例如，二聚偶联的对烷基苯酚磺酰氯或二聚偶联的烷基酚的磺酰胺或亚甲基亚胺（即曼尼希反应的产物）比母体烷基苯酚磺酰氯或对烷基酚的相同磺酰胺或亚甲基胺衍生物更具活性的分散剂。 这种二聚对烷基酚可以通过在碱性水溶液中在铁氰化钾存在下进行氧化偶联来制备。

公开(公告)号：US3703536A

公开(公告)日：1972-11-21

申请号：US3703536D

申请日：1967-11-24

Applicant: STANDARD OIL CO

Inventor： PIASEK EDMUND J ,  KARLL ROBERT E ,  LEE RICHARD J

IPC: C10M159/12 ,  C07C275/14 ,  C07D207/40 ,  C07F5/02 ,  C08F8/30 ,  C08G61/12 ,  C08G79/08 ,  C10M133/56 ,  C10M135/16 ,  C10M139/00 ,  C10N30/04 ,  C10N40/25 ,  C07F5/04

CPC classification number: C10M1/08 ,  C07C275/14 ,  C07F5/022 ,  C10M133/56 ,  C10M135/16 ,  C10M2215/04 ,  C10M2215/086 ,  C10M2215/10 ,  C10M2215/102 ,  C10M2215/26 ,  C10M2215/28 ,  C10M2217/046 ,  C10M2217/06 ,  C10M2219/044 ,  C10M2219/064 ,  C10M2223/045 ,  C10M2227/06 ,  C10M2227/061 ,  C10N2210/02 ,  C10N2210/03

Abstract: COMPLEX SUBSTITUTED ALKYLENE POLYAMINES SUCH AS DI (ALKENYLSUCCINIMIDE) OF N1,N3 SYMMETRICAL BIS(AMINOPOLYAZALKYLENE) UREAS AND OIL-SOLUBLE PRODUCTS DERIVED BY THE REACTION OF P-ALKYLPHENOLS, FORMALDEHYDE AND ALKYLENE POLYAMINES THAT REACT WITH BORIC ACID IN OIL SOLUTION EITHER WITH LOW BORIC ACID UTILIZATION EFFICIENCY OR REACT TO FORM A HAZY PRODUCT WHOSE HAZE CANNOT BE REMOVED BY FILTRATION ARE READILY CONVERTED TO THE DESIRED OIL SOLUTION OF BORON AND NITROGEN CONTAINING PRODUCTS BY FIRST PREPARING AN OIL SOLUTION OF SUPER BORON CONTAINING PRODUCT OF THE COMPLEX SUBSTITUTED ALKYLENE POLYAMINE, COMBINING THE OIL SOLUTION OF SUPER BORON CONTAINING PRODUCT WITH OIL SOLUTION OF THE COMPLEX SUBSTITUTED ALKYLENE POLYAMINE AND EQUILIBRATING THE RESULTING MIXTURE TO A UNIFORM BORON TO NITROGEN CONTENT THROUGHOUT.

Abstract translation: 复合取代的亚烷基多胺如N1，N3对称双（氨基多亚氮烷基）脲的二（烯基 - 琥珀酰亚胺）对称双（氨基多亚氮烷基）脲，其与硼酸在油溶液中反应，具有低硼酸利用效率或反应，形成其雾度不能通过 通过首先制备复合取代的亚烷基多胺的含超级含硼产物的油溶液，将含超硼含量产物的油溶液与络合物取代的亚烷基的油溶液结合，过滤容易地转化为所需的含硼和氮的产物油溶液 并将所得混合物平衡至一致的硼至氮含量。